Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors

Balbharti Maharashtra State Board 11th Physics Important Questions Chapter 11 Electric Current Through Conductors Important Questions and Answers.

Maharashtra State Board 11th Physics Important Questions Chapter 11 Electric Current Through Conductors

Question 1.
Define current. State its formula and SI unit.
Answer:

  1. Current is defined as the rate of flow of electric charge.
  2. Formula: I = \(\frac {q}{t}\)
  3. SI unit: ampere (A)

Question 2.
Derive an expression for a current generated due to the flow of charged particles
Answer:
i. Consider an imaginary gas of both negatively and positively charged particles moving randomly in various directions across a plane P.
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 1

ii. In a time interval t, let the amount of positive charge flowing in the forward direction be q+ and the amount of negative charge flowing in the forward direction be q. Thus, the net charge flowing in the forward direction is q = q+ – q

Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors

iii. Let I be the current varying with time. Let ∆q be the amount of net charge flowing across the plane P from time t to t + At, i.e. during the time interval ∆t.

iv. Then the current is given by
I(t) = \(\lim _{\Delta t \rightarrow 0} \frac{\Delta \mathrm{q}}{\Delta \mathrm{t}}\)
Flere, the current is expressed as the limit of the ratio (∆q/∆t) as ∆t tends to zero.

Question 3.
Match the amount of current generated A given in column – II with the sources given in column -I.

Column IColumn II
1. Lighteninga. Few amperes
2. House hold circuitsb. 10000 A
c. Order of µA

Answer:

Column IColumn II
1. Lighteningb. 10000 A
2. House hold circuitsa. Few amperes

Question 4.
Which are the most common units of current used in semiconductor devices?
Answer:

  1. milliampere (mA)
  2. microampere (µA)
  3. nanoampere (nA)

Question 5.
Six ampere current flows through a bulb. Find the number of electrons that should flow through the bulb in a time of 4 hrs.
Answer:
Given: I = 6 A, t = 4 hrs = 4 × 60 × 60 s
To find: Number of electrons (N)
Formula: I = \(\frac {q}{t}\) = \(\frac {Ne}{t}\)
Calculation: As we know, e = 1.6 × 10-19 C
From formula,
N = \(\frac {It}{e}\) = \(\frac {6×4×60×60}{1.6×10^{-19}}\) 6x4x60x60 = 5.4 × 1023

Question 6.
Explain flow of current in different conductor.
Answer:

  1. A current can be generated by positively or negatively charged particles.
  2. In an electrolyte, both positively and negatively charged particles take part in the conduction.
  3.  In a metal, the free electrons are responsible for conduction. These electrons flow and generate a net current under the action of an applied electric field.
  4. As long as a steady field exists, the electrons continue to flow in the form of a steady current.
  5. Such steady electric fields are generated by cells and batteries.

Question 7.
State the sign convention used to show the flow of electric current in a circuit.
Answer:
The direction of the current in a circuit is drawn in the direction in which positively charged particles would move, even if the current is constituted by the negatively charged particles, (electrons), which move in the direction opposite to that the electric field.

Question 8.
Explain the concept of drift velocity with neat diagrams.
Answer:
i. When no current flows through a copper rod, the free electrons move in random motion. Therefore, there is no net motion of these electrons in any direction.
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 2

ii. If an electric field is applied along the length of the copper rod, a current is set up in the rod. The electrons inside rod still move randomly, but tend to ‘drift’ in a particular direction.

iii. Their direction is opposite to that of the applied electric field.

iv. The electrons under the action of the applied electric field drift with a drift speed vd.
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 3

Question 9.
What is current density? State its SI unit.
Answer:
i. Current density at a point in a conductor is the amount of current flowing per unit area of the conductor.
Current density, J = \(\frac {I}{A}\)
where, I = Current
A = Area of cross-section

ii. SI unit: A/m²

Question 10.
A metallic wire of diameter 0.02 m contains 10 free electrons per cubic metre. Find the drift velocity for free electrons, having an electric current of 100 amperes flowing through the wire.
(Given: charge on electron = 1.6 × 10-19C)
Answer:
Given: e = 1.6 × 10-19 C, n = 1028 electrons/m³,
D = 0.02 m, r = D/2 = 0.01 m,
I = 100 A
To find: Drift velocity (vd)
Formula: vd = \(\frac {I}{nAe}\)
Calculation: From formula,
vd = \(\frac {I}{nπr^2e}\)
∴ vd = \(\frac {100}{10^{28}×3.142×10^{-4}×1.6×10^{-19}}\)
= \(\frac {10^{-3}}{3.142×1.6}\)
= 1.989 × 10-4 m/s

Question 11.
A copper wire of radius 0.6 mm carries a current of 1 A. Assuming the current to be uniformly distributed over a cross sectional area, find the magnitude of current density. Answer:
Given: r = 0.6 mm = 0.6 × 10-3 m, I = 1 A
To find: Current density (J)
Formula: J = \(\frac {I}{A}\)
Calculation: From formula,
J = \(\frac {1}{3.142×(0.6)^2×10^{-6}}\)
= 0.884 × 106 A/m²

Question 12.
A metal wire of radius 0.4 mm carries a current of 2 A. Find the magnitude of current density if the current is assumed to be uniformly distributed over a cross sectional area.
Answer:
Given: r = 0.4 mm = 0.4 × 10-3 m, I = 2 A
To find: Current density (J)
Formula: J = \(\frac {I}{A}\)
Calculation: From formula,
J = \(\frac {2}{3.142×(0.4)^2×10^{-6}}\)
= 3.978 × 106 A/m²

Question 13.
State and explain ohm’s law.
Answer:
Statement: The current I through a conductor is directly proportional to the potential difference V applied across its two ends provided the physical state of the conductor is unchanged.
Explanation:
According to ohm’s law,
I ∝ V
∴ V = IR or R = \(\frac {V}{I}\)
where, R is proportionality constant and is called the resistance of the conductor.

Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors

Question 14.
Draw a graph showing the I-V curve for a good conductor and ideal conductor.
Answer:
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 4

Question 15.
Define one ohm.
Answer:
If potential difference of 1 volt across a conductor produces a current of 1 ampere through it, then the resistance of the conductor is one ohm.

Question 16.
Define conductance. State its SI unit.
Answer:

  1. Reciprocal of resistance is called conductance.
    C = \(\frac {I}{R}\)
  2. S.I unit statement or Ω-1

Question 17.
Explain the concept of electrical conduction in a conductor.
Answer:

  1. Electrical conduction in a conductor is due to mobile charge carriers (electrons).
  2. These conduction electrons are free to move inside the volume of the conductor.
  3. During their random motion, electrons collide with the ion cores within the conductor. Assuming that electrons do not collide with each other these random motions average out to zero.
  4. On application of an electric field E, the motion of the electron is a combination of the random motion of electrons due to collisions and that due to the electric field \(\vec{E}\).
  5. The electrons drift under the action of the field \(\vec{E}\) and move in a direction opposite to the direction of the field \(\vec{E}\). In this way electrons in a conductor conduct electricity.

Question 18.
Derive expression for electric field when an electron of mass m is subjected to an electric field (E).
Answer:
i. Consider an electron of mass m subjected to an electric field E. The force experienced by the electron will be \(\vec{F}\) = e\(\vec{E}\).

ii. The acceleration experienced by the electron will then be
\(\vec{a}\) = \(\frac {e\vec{E}}{m}\) …………. (1)

iii. The drift velocities attained by electrons before and after collisions are not related to each other.

iv. After the collision, the electron will move in random direction, but will still drift in the direction opposite to \(\vec{E}\).

v. Let τ be the average time between two successive collisions.

vi. Thus, at any given instant of time, the average drift speed of the electron will be,
vd = a τ = \(\frac {eEτ}{m}\) ………………(From 1)
vd = \(\frac {eEτ}{m}\) = \(\frac {J}{ne}\) ……………(2) [∵ vd = \(\frac {J}{ne}\)]

vii. Electric field is given by,
E = (\(\frac {m}{e^2nτ}\))J ………… (from 2)
= ρJ = [∵ ρ = \(\frac {m}{ne^2τ}\)]
where, ρ is resistivity of the material.

Question 19.
A Flashlight uses two 1.5 V batteries to provide a steady current of 0.5 A in the filament. Determine the resistance of the glowing filament.
Answer:
Given: For each battery, V1 = V2 = 1.5 volt,
I = 0.5 A
To find: Resistance (R)
Formula: V = IR
Calculation: Total voltage, V = V1 + V2 = 3 volt
From formula,
R = \(\frac {V}{I}\) = \(\frac {3}{0.5}\) = 6.0 Ω

Question 20.
State an expression for resistance of non-ohmic devices and draw I-V curve for such devices.
Answer:
i. Resistance (R) of a non-ohmic device at a particular value of the potential difference V is given by,
R = \(\lim _{\Delta I \rightarrow 0} \frac{\Delta V}{\Delta I}=\frac{d V}{d I}\)
where, ∆V = potential difference between the
two values of potential V – \(\frac {∆V}{2}\) to V + \(\frac {∆V}{2}\),
and ∆I = corresponding change in the current.
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 5

Question 21.
Derive an expression for decrease in potential energy when a charge flows through an external resistance in a circuit.
Answer:
i. Consider a resistor AB connected to a cell in a circuit with current flowing from A to B.
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 6

ii. The cell maintains a potential difference V between the two terminals of the resistor, higher potential at A and lower at B.

iii. Let Q be the charge flowing in time ∆t through the resistor from A to B.

iv. The potential difference V between the two points A and B, is equal to the amount of work (W) done to carry a unit positive charge from A to B.
∴ V = \(\frac {W}{Q}\)

v. The cell provides this energy through the charge Q, to the resistor AB where the work is performed.

vi. When the charge Q flows from the higher potential point A to the lower potential point B, there is decrease in its potential energy by an amount
∆U = QV = I∆tV
where I is current due to the charge Q flowing in time ∆t.

Question 22.
Prove that power dissipated across a resistor is responsible for heating up the resistor. Give an example for it.
OR
Derive an expression for the power dissipated across a resistor in terms of its resistance R.
Answer:
i. When a charge Q flows from the higher potential point to the lower potential point, its potential energy decreases by an amount,
∆U = QV = I∆tV
where I is current due to the charge Q flowing in time ∆t.

ii. By the principle of conservation of energy, this energy is converted into some other form of energy.

iii. In the limit as ∆t → 0, \(\frac {dU}{dt}\) = IV
Here, \(\frac {dU}{dt}\) is power, the rate of transfer of energy ans is given by p = \(\frac {dU}{dt}\) = IV
Hence, power is transferred by the cell to the resistor or any other device in place of the resistor, such as a motor, a rechargeable battery etc.

iv. Due to the presence of an electric field, the free electrons move across a resistor and their kinetic energy increases as they move.

v. When these electrons collide with the ion cores, the energy gained by them is shared among the ion cores. Consequently, vibrations of the ions increase, resulting in heating up of the resistor.

vi. Thus, some amount of energy is dissipated in the form of heat in a resistor.

vii. The energy dissipated per unit time is actually the power dissipated which is given by,
P = \(\frac {V^2}{R}\) = I²R
Hence, it is the power dissipation across a resistor which is responsible for heating it up.

viii. For example, the filament of an electric bulb heats upto incandescence, radiating out heat and light.

Question 23.
Calculate the current flowing through a heater rated at 2 kW when connected to a 300 V d. c. supply.
Answer:
Given: P = 2 kW = 2000 W, V = 300 V
To find: Current (I)
Formula: P = IV
Calculation: From formula,
I = \(\frac {P}{V}\) = \(\frac {2000}{300}\) = 6.67 A

Question 24.
An electric heater takes 6 A current from a 230 V supply line, calculate the power of the heater and electric energy consumed by it in 5 hours.
Answer:
Given: I = 6 A, V = 230 V, t = 5 hours
To find: Power (P), Energy consumed
Formulae: i. P = IV
ii. Energy consumed = power × time
Calculation: From formula (i),
P = 6 × 230
= 1380 W = 1.38 kW
From formula (ii),
Energy consumed = 1.38 × 5 = 6.9 kWh
= 6.9 units

Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors

Question 25.
When supplied a voltage of 220 V, an electric heater takes 6 A current. Calculate the power of heater and electric energy consumed by its in 2 hours?
Answer:
Given: I = 6 A, V = 220 volt, t = 2 hour
To find: i. Power of heater (P)
ii. Electric energy consumed (E)
Formulae: i. P = IV
ii. Electric energy consumed
= Power × time
Calculation: From formula (i),
P = 6 × 220 = 1320 W = 1.32 kW
From formula (ii),
Electric energy consumed
= 1.32 × 2 = 2.64 kWh = 2.64 units

Question 26.
Explain the colour code system for resistors with an example.
Answer:
i. In colour code system, resistors has 4 bands on it.
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 7

ii. In the four band resistor, the colour code of the first two bands indicate two numbers and third band often called decimal multiplier.

iii. The fourth band separated by a space from the three value bands, indicates tolerance of the resistor.

iv. Following table represents the colour code of carbon resistor.
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 8

v. Example:
Let the colours of the rings of a resistor starting from one end be brown, red and orange and gold at the other end. To determine resistance of resistor we have,
x = 1, y = 2, z = 3 (From colour code table)
∴ Resistance = xy × 10z Ω ± tolerance
= 12 × 10³ Ω ± 5%
= 12 kΩ ± 5%
[Note: To remember the colours in order learn the Mnemonics: B.B. ROY of Great Britain had Very Good Wife]

Question 27.
Explain the concept of rheostat.
Answer:

  1. A rheostat is an adjustable resistor used in applications that require adjustment of current or resistance in an electric circuit.
  2. The rheostat can be used to adjust potential difference between two points in a circuit, change the intensity of lights and control the speed of motors, etc.
  3. Its resistive element can be a metal wire or a ribbon, carbon films or a conducting liquid, depending upon the application.
  4. In hi-fi equipment, rheostats are used for volume control.

Question 28.
Explain series combination of resistors.
Answer:
i. In series combination, resistors are connected in single electrical path. Hence, the same electric current flows through each resistor in a series combination.

ii. Whereas, in series combination, the supply voltage between two resistors R1 and R2 is divided into V1 and V2 respectively.
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 9

iii. According to Ohm’s law,
R1 = \(\frac {V_1}{I}\), R2 = \(\frac {v_2}{I}\)
Total Voltage, V = V1 + V2
= I(R1 + R2)
∴ V = I Rs
Thus, the equivalent resistance of the series circuit is, Rs = R1 + R2

iv. When a number of resistors are connected in series, the equivalent resistance is equal to the sum of individual resistances.
For ‘n’ number of resistors,
Rs = R1 + R2 + R2 + ………….. + Rn = \(\sum_{i=1}^{i=n} R_{i}\)

Question 29.
Explain parallel combination of resistors.
Answer:
i. In parallel combination, the resistors are connected in such a way that the same voltage is applied across each resistor.

ii. A number of resistors are said to be connected in parallel if all of them are connected between the same two electrical points each having individual path.

iii. In parallel combination, the total current I is divided into I, and I2 as shown in the circuit diagram.
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 10

iv. Since voltage V across them remains the same,
I = I1 + I2
where I1 is current flowing through R1 and I2 is current flowing through R2.

v. When Ohm’s law is applied to R1,
V = I1R1
i.e. I1 = \(\frac {V}{R_1}\) ………(1)
When Ohm’s law applied to R2,
V = I2R2
i.e., I2 = \(\frac {V}{R_2}\) …………(2)

vi. Total current is given by,
I = I1 + I2
∴ I = \(\frac {V}{R_1}\) + \(\frac {V}{R_2}\) ………[From (1) and (2)]
Since, I = \(\frac {V}{R_p}\)
∴ \(\frac {V}{R_p}\) = \(\frac {V}{R_1}\) + \(\frac {V}{R_2}\)
∴ \(\frac {1}{R_p}\) = \(\frac {1}{R_1}\) + \(\frac {1}{R_2}\)
Where, Rp is the equivalent resistance in parallel combination.

vii. If ‘n’ number of resistors R1, R2, R3, ………….. Rn are connected in parallel, the equivalent resistance of the combination is given by
\(\frac {1}{R_p}\) = \(\frac {1}{R_1}\) + \(\frac {1}{R_2}\) + \(\frac {1}{R_3}\) ……….. + \(\frac {1}{R_n}\) = \(\sum_{i=1}^{\mathrm{i}=\mathrm{n}} \frac{1}{\mathrm{R}}\)
Thus, when a number of resistors are connected in parallel, the reciprocal of the equivalent resistance is equal to the sum of the reciprocals of individual resistances.

Question 30.
Colour code of resistor is Yellow-Violet- Orange-Gold. Find its value.
Answer:

Yellow (x)Violet (y)Orange (z)Gold (T%)
Value473± 5

Value of resistance: xy × 10z Ω ± tolerance
∴ Value of resistance = 47 × 10³ Ω ± 5%
= 47 kΩ ± 5%

Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors

Question 31.
From the given value of resistor, find the colour bands of this resistor.
Value of resistor: 330 Ω
Answer:
Value = 330 Ω = 33 × 101 Ω = xy × 10z Ω

Value331
ColourOrange (x)Orange (y)Broen(z)

ii. Given: Green – Blue – Red – Gold

Question 32.
Evaluate resistance for the following colour-coded resistors:
i. Yellow – Violet – Black – Silver
ii. Green – Blue – Red – Gold
ill. Brown – Black – Orange – Gold
Answer:
i. Given: Yellow – Violet – Black – Silver
To find: Value of resistance
Formula: Value of resistance
= (xy × 10z ± T%)Ω

ColourYellow (x)Violet (y)Black (z)Sliver (T%)
Code470±10

Hence x = 4, y = 7, z = 0, T = 10%
Value of resistance = (xy ×10z ± T%) Ω
= (47 × 10° ± 10%) Ω
Value of resistance = 47 Ω ± 10%

To find: Value of resistance
Formula: Value of resistance
= (xy × 10z ± T%) Ω
Calculation:

ColourGreen (x)Blue (y)Red (z)Gold (T%)
Code562±5

Hence x = 5, y = 6, z = 2, T = 5%
Value of resistance = (xy × 10z ± T%) Q
= 56 × 102 Ω ± 5%
= 5.6 k Ω ± 5%

iii. Given: Brown – Black – Orange – Gold
To find: Value of the resistance
Formula: Value of the resistance
= (xy × 10z ± T%) Ω
Calculation:

ColourBrown (x)Black (y)Orange (z)Gold (T%)
Code103±5

Hence x = 1, y = 0, z = 3, T = 5%
Value of resistance = (xy × 10z ± T%) Ω
= 10 × 10³ Ω ± 5%
= 10 kΩ ± 5%

Question 33.
Calculate
i. total resistance and
ii. total current in the following circuit.
R1 = 3 Ω, R2 = 6 Ω, R3 = 5 Ω, V = 14 V
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 11
Answer:
i. R1 and R2 are connected in parallel. This combination (Rp) is connected in series with R3.
∴ Total resistance, RT = Rp + R3
Rp = \(\frac {R_1R_2}{R_1+R_2}\) = \(\frac {3×6}{3+6}\) = 2 Ω
∴ RT = 2+ 5 = 7 Ω

ii. Total current: I = \(\frac {V}{R_T}\) = \(\frac {14}{7}\) = 2 A

Question 34.
State the factors affecting resistance of a conductor.
Answer:
Factors affecting resistance of a conductor:

  1. Length of conductor
  2. Area of cross-section
  3. Nature of material

Question 35.
Derive expression for specific resistance of a material.
Answer:
At a particular temperature, the resistance (R) of a conductor of uniform cross section is
i. directly proportional to its length (l),
i.e., R ∝ l ……….. (1)

ii. inversely proportional to its area of cross section (A),
R ∝ \(\frac {1}{A}\) ……….. (1)
From equations (1) and (2),
R = ρ\(\frac {l}{A}\)
where ρ is a constant of proportionality and it is called specific resistance or resistivity of the material of the conductor at a given temperature.

iii. Thus, resistivity is given by,
ρ = \(\frac {RA}{l}\)

Question 36.
State SI unit of resistivity.
Answer:
SI unit of resistivity is ohm-metre (Ω m).

Question 37.
What is conductivity? State its SI unit.
Answer:
i. Reciprocal of resistivity is called as conductivity of a material.
Formula: σ = \(\frac {1}{ρ}\)
ii. SI unit: (\(\frac {1}{ohm m}\)) or siemens/metre

Question 38.
Explain the similarities between R = \(\frac {V}{I}\) and ρ = \(\frac {E}{J}\)
Answer:

  1. Resistivity (ρ) is a property of a material, while the resistance (R) refers to a particular object.
  2. The electric field \(\vec{E}\) at a point is specified in a material with the potential difference across the resistance and the current density \(\vec{J}\) in a material is specified instead of current I in the resistor.
  3. For an isotropic material, resistivity is given by ρ = \(\frac {E}{J}\)
    For a particular resistor, the resistance R given by, R = \(\frac {V}{I}\)

Question 39.
State expression for current density in terms of conductivity.
Answer:
Current density, \(\vec{J}\) = \(\frac {1}{ρ}\) \(\vec{E}\) = σ \(\vec{E}\)
where, ρ = resistivity of the material
E = electric field intensity
σ = conductivity of the material

Question 40.
Calculate the resistance per metre, at room temperature, of a constantan (alloy) wire of diameter 1.25 mm. The resistivity of constantan at room temperature is 5.0 × 10-7 Ωm.
Answer:
Given: ρ = 5.0 × 10-7 Ω m, d = 1.25 × 10-3 m,
∴ r = 0.625 × 10-3 m
To find: Resistance per metre (\(\frac {R}{l}\))
Formula: ρ = \(\frac {RA}{l}\)
Calculation:
From formula,
\(\frac{\mathrm{R}}{l}=\frac{\rho}{\mathrm{A}}=\frac{\rho}{\pi \mathrm{r}^{2}}\)
= \(\frac{5 \times 10^{-7}}{3.142 \times\left(0.625 \times 10^{-3}\right)^{2}}\)
= \(\frac{5}{3.142 \times 0.625^{2}} \times 10^{-1}\)
= { antilog [log 5 – log 3.142 -2 log 0.625]} × 10-1
= {antilog [ 0.6990 – 0.4972 -2(1.7959)]} × 10-1
= {antilog [0.2018- 1.5918]} × 10-1
= {antilog [0.6100]} × 10-1
= 4.074 × 10-1
∴ \(\frac {R}{l}\) ≈ 0.41 Ω m-1

Question 41.
A negligibly small current is passed through a wire of length 15 m and uniform cross-section 6 × 10-7 m², and its resistance is measured to be 5 Ω. What is the resistivity of the material at the temperature of the experiment?
Answer:
Given: l = 15 m, A = 6.0 × 10-7 m², R = 5 Ω
To find: Resistivity (ρ)
Formula: ρ = \(\frac {RA}{l}\)
Calculation: From formula,
ρ = \(\frac {5×6×10^{-7}}{15}\)
∴ ρ = 2 × 10-7 Ω m

Question 42.
A constantan wire of length 50 cm and 0.4 mm diameter is used in making a resistor. If the resistivity of constantan is 5 × 10-7m, calculate the value of the resistor.
Answer:
Given: l = 50 cm = 0.5 m,
d = 0.4 mm = 0.4 × 10-3 m,
r = 0.2 × 10-3 m, p = 5 × 10-7 Ωm
To Find: Value of resistor (R)
Formula: ρ = \(\frac {RA}{l}\)
Calculation: from formula,
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 12

Question 43.
The resistivity of nichrome is 10-6 Ωm. What length of a uniform wire of this material and of 0.2 mm diameter will have a resistance of 200 ohm?
Answer:
Given: ρ = 10-6 Ω m, d = 0.2 mm,
∴ r = 0.1 mm = 0.1 × 10-3 m, R = 200 Ω
To find: Length (l)
Formula: R = \(\frac {ρl}{A}\) = \(\frac {ρl}{πr^2}\)
Calculation: From formula,
l = \(\frac {πr^2}{ρ}\)
∴ l = \(\frac{200 \times 3.142 \times\left(0.1 \times 10^{-3}\right)^{2}}{10^{-6}}\) = 6 284 m

Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors

Question 44.
A wire of circular cross-section and 30 ohm resistance is uniformly stretched until its new length is three times its original length. Find its resistance.
Answer:
Given: R1 = 30 ohm,
l1 = original length, A1 = original area,
l2 = new length, A2 = new area
l2= 3l1
To find: Resistance (R2)
Formula: R= ρ\(\frac {l}{A}\)
Calculation: From formula,
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 13
The volume of wire remains the same in two cases, we have
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 14

Question 45.
Define temperature coefficient of resistivity. State its SI unit.
Answer:
i. The temperature coefficient of resistivity is defined as the increase in resistance per unit original resistance at the chosen reference temperature, per degree rise in temperature.
α = \(\frac{\rho-\rho_{0}}{\rho_{0}\left(T-T_{0}\right)}\)
= \(\frac{\mathrm{R}-\mathrm{R}_{0}}{\mathrm{R}_{0}\left(\mathrm{~T}-\mathrm{T}_{0}\right)}\)
For small difference in temperatures,
α = \(\frac {1}{R_0}\) \(\frac {dR}{dT}\)

ii. SI unit: °C-1 (per degree Celsius) or K-1 (per kelvin).

Question 46.
Give expressions for variation of resistivity and resistance with temperature. Represent graphically the temperature dependence of resistivity of copper.
Answer:
i. Resistivity is given by,
ρ = ρ0 [1 + α (T – T0)] where,
T0 = chosen reference temperature
ρ0 = resistivity at the chosen temperature
α = temperature coefficient of resistivity
T = final temperature

ii. Resistance is given by,
R = R0 [1+ α (T – T0)]
Where,
T0 = chosen reference temperature
R0 = resistance at the chosen temperature
α = temperature coefficient of resistance
T = final temperature

iii. For example, for copper, the temperature dependence of resistivity can be plotted as shown:
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 15

Question 47.
What is super conductivity?
Answer:

  1. The resistivity of a metal decreases as the temperature decreases.
  2. In case of some metals and metal alloys, the resistivity suddenly drops to zero at a particular temperature (Tc), this temperature is called critical temperature.
  3. Super conductivity is the phenomenon where resistivity of a material becomes zero at particular temperature.
  4. For example, mercury loses its resistance completely to zero at 4.2 K.

Question 48.
A piece of platinum wire has resistance of 2.5 Ω at 0 °C. If its temperature coefficient of resistance is 4 × 10-3/°C. Find the resistance of the wire at 80 °C.
Answer:
Given: R0 = 2.5 Ω
α = 4 × 10-3/°C = 0.004/°C
T = 80 °C
To find: Resistance at 80 °C (RT)
Formula: RT = R0(l + α T)
Calculation: From formula,
RT = 2.5 [1+ (0.004 × 80)]
= 2.5(1 + 0.32)
RT = 2.5 × 1.32
RT = 3.3 Ω

Question 49.
The resistance of a tungsten filament at 150 °C is 133 ohm. What will be its resistance at 500 °C? The temperature coefficient of resistance of tungsten is 0.0045 per °C.
Answer:
Given: Let resistance at 150 °C be R1 and resistance at 500 °C be R2
Thus,
R1= 133 Ω, α = 0.0045 °C-1
To find: Resistance (R2)
Formula: RT = R0 (1 + α∆T)
Calculation:
From formula,
R1 = R0 (1 + α × 150)
∴ 133 = R0(1 + 0.0045 × 150) ……….(i)
R2 = R0 (1 + α × 500)
∴ R2 = R0(1 + 0.0045 × 500) ………(ii)
Dividing equation (ii) by (i), we get
\(\frac{\mathrm{R}_{2}}{133}=\frac{1+(0.0045 \times 500)}{1+(0.0045 \times 150)}=\frac{3.25}{1.675}\)
∴ R2 = \(\frac {3.25}{1.675}\) × 133 = 258 Ω

Question 50.
A silver wire has resistance of 2.1 Ω at 27.5 °C. If temperature coefficient of silver is 3.94 × 10-3/°C, find the silver wire resistance at 100 °C.
Answer:
Given: R1 = 2.1 Ω, T1 = 27.5 °C,
α = 3.94 × 10-3/°C, T2 = 100 °C
To find: Resistance (R2)
Formula: RT = Ro (1 + αT)
Calculation:
From the formula,
R1 = R0(1 + α × 27.5) ……….. (i)
R2 = R0(l + α × 100) ………….. (ii)
Dividing equation (i) by (ii), we get,
\(\frac{\mathrm{R}_{1}}{\mathrm{R}_{2}}=\frac{1+\left(3.94 \times 10^{-3} \times 27.5\right)}{1+\left(3.94 \times 10^{-3} \times 100\right)}\)
\(\frac{\mathrm{R}_{1}}{\mathrm{R}_{2}}=\frac{1.10835}{1.394}\) = 0.795
∴ R2 = \(\frac{\mathrm{R}_{1}}{0.795}=\frac{2.1}{0.795}\) = 2.641 Ω

Question 51.
At what temperature would the resistance of a copper conductor be double its resistance at 0 °C?
(a for copper = 3.9 × 10-3/°C)
Answer:
Given: Let the resistance of the conductor at 0°C be R0
R1 = R0 at T1 = 0°C
R2 = 2R0 at T2 = T
To find: Final temperature (T)
Formula: α = \(\frac {R_2-R_1}{R_1(T_2-T_1)}\)
Calculation: From formula,
α = \(\frac {2R_0-R_0}{R_1(T_2-T_1)}\) = \(\frac {1}{T}\)
∴ T = \(\frac {1}{α}\) = \(\frac {1}{3.9×10^{-3}}\) ≈ 256 °C

Question 52.
A conductor has resistance of 15 Ω at 10 °C and 18 Ω at 400 °C. Find the temperature coefficient of resistance of the material.
Answer:
Given: R1 = 15 Ω, T1 = 10 °C, R2 = 18 Ω,
T2 = 400 °C
To find: Temperature coefficient of resistance (α)
Formula: RT = R0 (1 + αT)
Calculation:
From formula,
R1 = R0 (1 + α × 10) ……..(i)
R2 = R0 (1 + α × 400) …….(ii)
Dividing equation (i) by (ii), we get,
\(\frac{\mathrm{R}_{1}}{\mathrm{R}_{2}}=\frac{1+(\alpha \times 10)}{1+(\alpha \times 400)}\)
∴ \(\frac{15}{18}=\frac{1+10 \alpha}{1+400 \alpha}\)
∴ 18 + 180 α = 15 + 6000 α
∴ 5820 α = 3
∴ α = \(\frac {3}{5820}\) = 5.155 × 10-4/°C

Question 53.
Write short note on e.m.f. devices.
Answer:

  1. When charges flow through a conductor, a potential difference get established between the two ends of the conductor.
  2. For a steady flow of charges, this potential difference is required to be maintained across the two ends of the conductor.
  3. There is a device that does so by doing work on the charges, thereby maintaining the potential difference. Such a device is called an emf device and it provides the emf E.
  4. The charges move in the conductor due to the energy provided by the emf device. This energy is supplied by the e.m.f. device on account of its work done.
  5. Power cells, batteries, Solar cells, fuel cells, and even generators, are some examples of emf devices.

Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors

Question 54.
Explain working of a circuit when connected to emf device.
Answer:
i. A circuit is formed with connecting an emf device and a resistor R. Flere, the emf device keeps the positive terminal (+) at a higher electric potential than the negative terminal (-)
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 16
ii. The emf is represented by an arrow from the negative terminal to the positive terminal.

iii. When the circuit is open, there is no net flow of charge carriers within the device.

iv. When connected in a circuit, the positive charge carriers move towards the positive terminal which acts as cathode inside the emf device.

v. Thus, the positive charge carriers move from the region of lower potential energy, to the region of higher potential energy.

vi. Consider a charge dq flowing through the cross section of the circuit in time dt.

vii. Since, same amount of charge dq flows throughout the circuit, including the emf device. Hence, the device must do work dW on the charge dq, so that the charge enters the negative terminal (low potential terminal) and leaves the positive terminal (higher potential terminal).

viii. Therefore, e.m.f. of the emf device is,
E = \(\frac {dW}{dq}\)
The SI unit of emf is joule/coulomb (J/C).

Question 55.
What is an ideal e.m.f. device?
Answer:

  1. In an ideal e.m.f. device, there is no internal resistance to the motion of charge carriers.
  2. The emf of the device is then equal to the potential difference across the two terminals of the device.

Question 56.
What is a real e.m.f. device?
Answer:

  1. In a real emf device, there is an internal resistance to the motion of charge carriers.
  2. If such a device is not connected in a circuit, there is no current through it.

Question 57.
Derive an expression for current flowing through a circuit when an external resistance is connected to a real e.m.f. device.
Answer:
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 17
i. If a current (I) flows through an emf device, there is an internal resistance (r) and the emf (E) differs from the potential difference across its two terminals (V).
V = E – Ir ……… (1)

ii. The negative sign is due to the fact that the current I flows through the emf device from the negative terminal to the positive terminal.

iii. By the application of Ohm’s law,
V = IR …….(2)
From equations (1) and (2),
IR = E – Ir
∴ \(\frac {E}{R+r}\)

Question 58.
Explain the conditions for maximum current.
Answer:

  1. Current in a circuit is given by, I = \(\frac {E}{R+r}\)
  2. Maximum current can be drawn from the emf device, only when R = 0, i.e.
    Imax = \(\frac {E}{R}\)
  3. Imax is the maximum allowed current from an emf device (or a cell) which decides the maximum current rating of a cell or a battery.

Question 59.
A network of resistors is connected to a 14 V battery with internal resistance 1 Q as shown in the circuit diagram.
i. Calculate the equivalent resistance,
ii. Current in each resistor,
iii. Voltage drops VAB, VBC and VDC.
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 18
Answer:
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 19
For equivalent resistance (Req):
RAB is given as,
\(\frac{1}{\mathrm{R}_{\mathrm{AB}}}=\frac{1}{\mathrm{R}_{1}}+\frac{1}{\mathrm{R}_{2}}=\frac{1}{4}+\frac{1}{4}=\frac{2}{4}\)
∴ RAB = 2 Ω
RBC = R3 = 1 Ω
Also, RCD is given as,
\(\frac{1}{\mathrm{R}_{\mathrm{CD}}}=\frac{1}{\mathrm{R}_{4}}+\frac{1}{\mathrm{R}_{5}}=\frac{1}{6}+\frac{1}{6}=\frac{2}{6}\)
∴ RCD = 3 Ω
∴ Req = RAB + RBC + RCD
= 2 + 1 + 3 = 6Ω

ii. Current through each resistor:
Total current, I = \(\frac{\mathrm{E}}{\mathrm{R}_{\mathrm{eq}}+\mathrm{r}}\) = \(\frac {14}{6+1}\) = 2 A
Across AB, as, R1 = R2
V1 = V2
∴I1 × 4 = I2 × 4
∴ I1 = I2
But, I1 + I2 = I
∴ 2I1 = I
∴ I1 = I2 =1 A ….(∵I = 2 A)
Similarly, as R4 = R5
I3 = I4 = 1 A
Current through resistor BC is same as I.
∴ IBC = 2 A

iii. Voltage drops across AB, BC and CD:
VAB = IRAB = 2 × 2 = 4 V
VBC = IRBC = 2 × 1 = 2 V
VCD = IRCD = 2 × 3 = 6 V

Question 60.
i. Three resistors 2 Ω, 4 Ω and 5 Ω are combined in parallel. What is the total resistance of the combination?
ii. If the combination is connected to a battery of e.m.f. 20 V and negligible internal resistance, determine the current through each resistor and the total current drawn from the battery.
Answer:
Given: R1 = 2Ω, R2 = 4 Ω, R3 = 5 Ω,
V = 20 V
To Find: i. Total resistance (R)
ii. Current through each resistor (I1, I2, I3 respectively)
iii. Total current (I)
Formulae:
i. \(\frac{1}{\mathrm{R}}=\frac{1}{\mathrm{R}_{1}}+\frac{1}{\mathrm{R}_{2}}+\frac{1}{\mathrm{R}_{3}}\)
ii. V = IR
iii. Total current, I = I1 +I2 + I3
Calculation
From formula (i):
\(\frac{1}{R}=\frac{1}{2}+\frac{1}{4}+\frac{1}{5}=\frac{19}{20}\)
∴ R = \(\frac {20}{19}\) Ω
From formula (ii):
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 20
From formula (iii):
I = 10 + 5 + 4
∴ I = 19 A

Question 61.
i. Three resistors 1 Ω, 2 Ω and 3 Ω are combined in series. What is the total resistance of the combination?
ii. If the combination is connected to a battery of e.m.f. 12 V and negligible internal resistance, obtain the potential drop across each resistor.
Answer:
Given: R1 = 1Ω, R2 = 2 Ω, R3 = 3 Ω,
V = 12 V
To Find: i. Total resistance (R)
ii. P.D Across R1, R2, R3 (V1, V2, V3 respectively)
Formulae:
i. Rs = R1 + R2 + R3
ii. V = IR
Calculation
From formula (i):
Rs = l + 2 + 3 = 6 Ω
From formula (ii),
1 = \(\frac {V}{R}\) = \(\frac {12}{6}\) = 2A
∴ V1 = IR1 = 2 × 1 = 2 V
∴ V2 = IR2 = 2 × 2 = 4 V
∴ V3 = IR3 = 2 × 3 = 6 V

Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors

Question 62.
A voltmeter is connected across a battery of emf 12 V and internal resistance of 10 Ω. If the voltmeter resistance is 230 Ω, what reading will be shown by the voltmeter? Answer:
Given: E = 12 volt, r = 10 Ω, R = 230 Ω
To find: Reading shown by voltmeter (V)
Formula: i. I = \(\frac {E}{R+r}\)
ii. V = E – Ir
Calculation
From formula (i),
I = \(\frac{12}{230+10}=\frac{12}{240}=\frac{1}{20} \mathrm{~A}\)
From formula (ii),
V= 12 – \(\frac {1}{20}\) × 10 = 12 – 0.5
= 11.5 volt

Question 63.
A battery of e.m.f. 10 V and internal resistance 3 Ω is connected to a resistor. If the current in the circuit is 0.5 A, what is the resistance of the resistor? What is the terminal voltage of the battery when the circuit is closed?
Answer:
Given: E = 10 V, r = 3 Ω, I = 0.5 A
To find: i. Resistance of resistor (R)
ii. Terminal voltage of battery (V)
Formula: I = \(\frac {E}{R+r}\)
Calculation: From formula, R = \(\frac {E}{I}\) – r
∴ R = \(\frac {10}{0.5}\)– 3 = 17 Ω
∴ V = IR = 0.5 × 17 = 8.5 volt

Question 64.
How many cells each of 1.5 V/500 mA rating would be required in series-parallel combination to provide 1500 mA at 3 V?
Answer:
21 = ………… = 1.5 V (given)
I1 = I2 = …………… = 500 mA (given)
1500 mA at 3 V is required.
To determine required number of cells:
For series V = V1 + V2 + ………….., and current remains same.
For parallel I = I1 + I2 + ………, and voltage remains same.
To achieve battery output of 3V, the cells should be connected in series.
If n are the number of cells connected in series, then
V = V1 + V2 + …………. + Vn
∴ V = nV1
∴ 3 = n × 1.5
∴ n = 2 cells in series
The series combination of two cells in series will give a current 500 mA.
To achieve output of 1500 mA, the number of batteries (n) connected in parallel, each one having output 3V is,
I = I1 + I2 + ………. + In
∴ I = nI1
∴ 1500 = n × 500
∴ n = 3 batteries each of two cells
∴ No of cells required are 2 × 3 = 6 .
∴ Number of cells = 6
The six cells must be connected as shown
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 21

Question 65.
Explain the concept of series combination of cells.
Answer:
i. In a series combination, cells are connected in single electrical path, such that the positive terminal of one cell is connected to the negative terminal of the next cell, and so on.

ii. The terminal voltage of batteiy/cell is equal to the sum of voltages of individual cells in series. Example: Given figure shows two 1.5 V cells connected in series. This combination provides total voltage,
V = 1.5 V + 1.5 V = 3 V.
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 22

iii. The equivalent emf of n number of cells in series combination is the algebraic sum of their individual emf.
\(\sum_{i} \mathrm{E}_{\mathrm{i}}\) = E1 + E2 + E2+ …….. + En

iv. The equivalent internal resistance of n cells in a series combination is the sum of their individual internal resistance.
\(\sum_{i} \mathrm{r}_{\mathrm{i}}\) = r1 + r2 + r3 + ……… + rn

Question 66.
State advantages of cells in series.
Answer:

  1. The cells connected in series produce a larger resultant voltage.
  2. Cells which are damaged can be easily identified, hence can be easily replaced.

Question 67.
Explain combination of cells in parallel. Ans:
Answer:
i. Consider two cells which are connected in parallel. Here, positive terminals of all the cells are connected together and the negative terminals of all the cells are connected together.

ii. In parallel connection, the current is divided among the branches i.e. I1 and I2 as shown in figure.
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 23

iii. Consider points A and B having potentials VA and VB, respectively.

iv. For the first cell the potential difference across its terminals is, V = VA – VB = E1 – I1 r1
∴ I1 = \(\frac {E_1V}{r_1}\) ………. (1)

v. Point A and B are connected exactly similarly to the second cell.
Hence, considering the second cell,
V = VA – VB = E2 – I2r2
∴ I2 = \(\frac {E_2V}{r_2}\) ………. (2)

vi. Since, I = I1 + I2 ………….. (3)
Combining equations (1), (2) and (3),
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 24

viii. If we replace the cells by a single cell connected between points A and B with the emf Eeq and the internal resistance req then,
V = Eeq– Ireq
From equations (4) and (5),
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 25

ix. For n number of cells connected in parallel with emf E1, E2, E3, ………….., En and internal resistance r1, r2, r3, …………, rn
\(\frac{1}{\mathrm{r}_{\mathrm{rq}}}=\frac{1}{\mathrm{r}_{1}}+\frac{1}{\mathrm{r}_{2}}+\frac{1}{\mathrm{r}_{3}}+\ldots \ldots \ldots+\frac{1}{\mathrm{r}_{\mathrm{n}}}\)
and \(\frac{\mathrm{E}_{\mathrm{eq}}}{\mathrm{r}_{\mathrm{rq}}}=\frac{\mathrm{E}_{1}}{\mathrm{r}_{1}}+\frac{\mathrm{E}_{2}}{\mathrm{r}_{2}}+\ldots \ldots \ldots+\frac{\mathrm{E}_{\mathrm{n}}}{\mathrm{r}_{\mathrm{n}}}\)

Question 68.
State advantages and disadvantages of cells in parallel.
Answer:
Advantages:
For cells connected in parallel in a circuit, the circuit will not break open even if a cell gets damaged or open.

Disadvantages:
The voltage developed by the cells in parallel connection cannot be increased by increasing number of cells present in circuit.

Question 69.
State the basic categories of electrical cells.
Answer:
Electrical cells can be divided into several categories like primary cell, secondary cell, fuel cell, etc.

Question 70.
Write short note on primary cell.
Answer:

  1. A primary cell cannot be charged again. It can be used only once.
  2. Dry cells, alkaline cells are different examples of primary cells.
  3. Primary cells are low cost and can be used easily. But these are not suitable for heavy loads.

Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors

Question 71.
Write short note on secondary cell.
Answer:

  1. The secondary cells are rechargeable and can be reused.
  2. The chemical reaction in a secondary cell is reversible.
  3. Lead acid cell and fuel cell are some examples of secondary cells.
  4. Lead acid battery is used widely in vehicles and other applications which require high load currents.
  5. Solar cells are secondary cells that convert solar energy into electrical energy.

Question 72.
Write short note on fuel cells vehicles.
Answer:

  1. Fuel cells vehicles (FCVs) are electric vehicles that use fuel cells instead of lead acid batteries to power the vehicles.
  2. Hydrogen is used as a fuel in fuel cells. The by product after its burning is water.
  3. This is important in terms of reducing emission of greenhouse gases produced by traditional gasoline fuelled vehicles.
  4. The hydrogen fuel cell vehicles are thus more environment friendly.

Question 73.
What can be concluded from the following observations on a resistor made up of certain material? Calculate the power drawn in each case.

CaseCurrent (A)Voltage (V)
A0.21.6
B0.43.2
C0.64.8
d0.86.4

Answer:
i. As the ratio of voltage and current different readings are same, hence ohm’s is valid i.e., V = IR.

ii. Electric power is given by, P = IV
∴ (a) P1 = 0.2 × 1.6 = 0.32 watt
(b) P2 = 0.4 × 3.2 = 1.28 watt
(c) P3 = 0.6 × 4.8 = 2.88 watt
(d) P4 = 0.8 × 6.4 = 5.12 watt

Question 74.
Answer the following questions from the circuit given below. [S1, S2, S3, S4, S5 ⇒ Switches]. Calculate the current (I) flowing in the following cases:
i. S1, S4 → open; S2, S3, S5 → closed.
ii. S2, S5 → open; S1, S3, S4 → closed.
iii. S3 → open; S1, S2, S4, S5 → closed.
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 26
Answer:
i. Here, the circuit can be represented as,
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 27

ii. Here, the circuit can be represented as,
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 28

iii. Here, the circuit can be represented as,
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 29
∴ As switch S3 is open, no current will flow in the circuit.

Question 75.
An electric circuit with a carton resistor and an electric bulb (60 watt, 300 Ω) are connected in series with a 230 V source.
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 30
i. Calculate the current flowing through the circuit.
ii. If the electric bulb of 60 watt is replaced by an electric bulb (80 watt, 300 Ω), will it glow? Justify your answer.
Answer:
Resistance of carbon resistor (R1)
= 16 × 10 Ω = 160 Ω ….(using colour code)
Resistance of bulb (R2) = 300 Ω
∴ Current through the circuit = \(\frac{V}{R_{1}+R_{2}}\)
∴ I = \(\frac{230}{(160+300)}=\frac{230}{460}\) = 0.5 A

ii. Power drawn through electric bulb
= I²R2 = (0.5)² × 300 = 75 watt
Hence, if the bulb is replaced by 80 watt bulb, it will not glow.

Question 76.
From the graph given below, which of the two temperatures is higher for a metallic wire? Justify your answer.
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 31
Answer:
As R = \(\frac {V}{I}\)
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 32
For constant V,
I2 > I1
∴ R1 > R2
Now, for metallic wire,
R ∝ T
∴ T1 > T2
T1 is greater than T2.

Question 77.
If n identical cells, each of emf E and internal resistance r, are connected in series, write an expression for the terminal p.d. of the combination and hence show that this is nearly n times that of a single cell.
Answer:
i. Let n identical cells, each of emf E and internal resistance r, be connected in series. Let the current supplied by this combination to an external resistance R be I.

ii. The equivalent emf of the combination,
Eeq = E + E + …….. (n times) = nE

iii. The equivalent internal resistance of the combination,
req= r + r + … (n times)
= nr

iv. The terminal p.d. of the combination is
V = Eeq – Ireq = nE – Inr = n (E – Ir)
∴ V = n × terminal p.d. of a single cell
Thus, the terminal p.d. of the series combination is n times that of a single cell.

Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors

Question 78.
If n identical cells, each of emf E and internal resistance r, are connected in parallel, derive an expression for the current supplied by this combination to external resistance R. Prove that the combination supplies current almost n times the current supplied by a single cell, when the external resistance R is much smaller than the internal resistance of the parallel combination of the cells.
Answer:
i. Consider n identical cells, each of emf E and internal resistance r, connected in parallel.

ii. Let the current supplied by the combination to the external resistance R be I.
In this case, the equivalent emf of the combination is E.

iii. The equivalent internal resistance r’ of the combination is,
\(\frac{1}{\mathrm{r}^{\prime}}=\frac{1}{\mathrm{r}}+\frac{1}{\mathrm{r}}\) + …………. (n terms)
∴ \(\frac{1}{\mathrm{r}^{\prime}}=\frac{\mathrm{n}}{\mathrm{r}} \Rightarrow \mathrm{r}^{\prime} \frac{\mathrm{n}}{\mathrm{r}}\)

iv. But V = IR is the terminal p.d. across each cell.

v. Hence, the current supplied by each cell,
I = \(\frac {E-V}{r}\)

vi. This gives the current supplied by the combination to the external resistance as
I = \(\frac {E-V}{r}\) + \(\frac {E-V}{r}\) + …….. (n terms) = n(\(\frac {E-V}{r}\))
Thus, current I = n × current supplied by a single cell
This proves that, the current supplied by the combination is n times the current supplied by a single cell.

Multiple Choice Questions

Question 1.
The drift velocity of the free electrons in a conductor is independent of
(A) length of the conductor.
(B) cross-sectional area of conductor.
(C) current.
(D) electric charge.
Answer:
(A) length of the conductor.

Question 2.
The direction of drift velocity in a conductor is
(A) opposite to that of applied electric field.
(B) opposite to the flow of positive charge.
(C) in the direction of the flow of electrons,
(D) all of these.
Answer:
(D) all of these.

Question 3.
The drift velocity of free electrons in a conductor is vd, when the current is flowing in it. If both the radius and current are doubled, the drift velocity will be
(A) \(\frac {v_d}{8}\)
(B) \(\frac {v_d}{4}\)
(C) \(\frac {v_d}{2}\)
(D) vd
Answer:
(C) \(\frac {v_d}{2}\)

Question 4.
The drift velocity vd of electrons varies with electric field strength E as
(A) vd ∝ E
(B) vd ∝ \(\frac {1}{E}\)
(C) vd ∝ E1/2
(D) vd × E\(\frac {1}{1/2}\)
Answer:
(A) vd ∝ E

Question 5.
When a current I is set up in a wire of radius r, the drift speed is vd. If the same current is set up through a wire of radius 2r, then the drift speed will be
(A) vd/4
(B) vd/2
(C) 2vd
(D) 4vd
Answer:
(A) vd/4

Question 6.
When potential difference is applied across an electrolyte, then Ohm’s law is obeyed at
(A) zero potential
(B) very low potential
(C) negative potential
(D) high potential.
Answer:
(D) high potential.

Question 7.
A current of 1.6 A is passed through an electric lamp for half a minute. If the charge on the electron is 1.6 × 10-19 C, the number of electrons passing through it is
(A) 1 × 1019
(B) 1.5 × 1020
(C) 3 × 1019
(D) 3 × 1020
Answer:
(D) 3 × 1020

Question 8.
The SI unit of the emf of a cell is
(A) V/m
(B) V/C
(C) J/C
(D) C/J
Answer:
(C) J/C

Question 9.
The unit of specific resistance is
(A) Ω m-1
(B) Ω-1 m-1
(C) Ω m
(D) Ω m-2
Answer:
(C) Ω m

Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors

Question 10.
If the length of a conductor is halved, then its conductivity will be
(A) doubled
(B) halved
(C) quadrupled
(D) unchanged
Answer:
(D) unchanged

Question 11.
The resistance of a metal conductor increases with temperature due to
(A) change in current carriers.
(B) change in the dimensions of the conductor.
(C) increase in the number of collisions among the current carriers.
(D) increase in the rate of collisions between the current carriers and the vibrating atoms of the conductor.
Answer:
(D) increase in the rate of collisions between the current carriers and the vibrating atoms of the conductor.

Question 12.
The resistivity of Nichrome is 10-6 Ω-m. The wire of this material has radius of 0.1 mm with resistance 100 Ω, then the length will be
(A) 3.142 m
(B) 0.3142 m
(C) 3.142 cm
(D) 31.42 m
Answer:
(A) 3.142 m

Question 13.
Given a current carrying wire of non-uniform cross-section. Which of the following is constant throughout the length of the wire?
(A) Current, electric field and drift speed
(B) Drift speed only
(C) Current and drift speed
(D) Current only
Answer:
(D) Current only

Question 14.
A cell of emf E and internal resistance r is connected across an external resistance R (R >> r). The p.d. across R is A 1
(A) \(\frac {E}{R+r}\)
(B) E(I – \(\frac {r}{R}\))
(C) E(I + \(\frac {r}{R}\))
(D) E (R + r)
Answer:
(B) E(I – \(\frac {r}{R}\))

Question 15.
The e.m.f. of a cell of negligible internal resistance is 2 V. It is connected to the series combination of 2 Ω, 3 Ω and 5 Ω resistances. The potential difference across 3 Ω resistance will be
(A) 0.6 V
(B) 10 V
(C) 3 V
(D) 6 V
Answer:
(A) 0.6 V

Question 16.
A P.D. of 20 V is applied across a conductance of 8 mho. The current in the conductor is
(A) 2.5 A
(B) 28 A
(C) 160 A
(D) 45 A
Answer:
(C) 160 A

Question 17.
If an increase in length of copper wire is 0.5% due to stretching, the percentage increase in its resistance will be
(A) 0.1%
(B) 0.2%
(C) 1 %
(D) 2 %
Answer:
(C) 1 %

Question 18.
If a certain piece of copper is to be shaped into a conductor of minimum resistance, its length (L) and cross-sectional area A shall be respectively
(A) L/3 and 4 A
(B) L/2 and 2 A
(C) 2L and A2
(D) L and A
Answer:
(A) L/3 and 4 A

Question 19.
A given resistor has the following colour scheme of the various strips on it: Brown, black, green and silver. Its value in ohm is
(A) 1.0 × 104 ± 10%
(B) 1.0 × 105 ± 10%
(C) 1.0 × 106 + 10%
(D) 1.0 × 107 ± 10%
Answer:
(C) 1.0 × 106 + 10%

Question 20.
A given carbon resistor has the following colour code of the various strips: Orange, red, yellow and gold. The value of resistance in ohm is
(A) 32 × 104 ± 5%
(B) 32 × 104 ± 10%
(C) 23 × 105 ± 5%
(D) 23 × 105 ± 10%
Answer:
(A) 32 × 104 ± 5%

Question 21.
A typical thermistor can easily measure a change in temperature of the order of
(A) 10-3 °C
(B) 10-2 °C
(C) 10² °C
(D) 10³ °C
Answer:
(A) 10-3 °C

Question 22.
Thermistors are usually prepared from
(A) non-metals
(B) metals
(C) oxides of non-metals
(D) oxides of metals
Answer:
(D) oxides of metals

Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors

Question 23.
On increasing the temperature of a conductor, its resistance increases because
(A) relaxation time decreases.
(B) mass of the electron increases.
(C) electron density decreases.
(D) all of the above.
Answer:
(A) relaxation time decreases.

Question 24.
Which of the following is used for the formation of thermistor?
(A) copper oxide
(B) nickel oxide
(C) iron oxide
(D) all of the above
Answer:
(D) all of the above

Question 25.
Emf of a cell is 2.2 volt. When resistance R = 5 Ω is connected in series, potential drop across the cell becomes 1.8 volt. Value of internal resistance of the cell is
(A) 10/9 Ω
(B) 7/12 Ω
(C) 9/10 Ω
(D) 12/7 Ω
Answer:
(A) 10/9 Ω

Question 26.
A strip of copper, another of germanium are cooled from room temperature to 80 K. The resistance of
(A) copper strip decreases germanium decreases. and that of
(B) copper strip decreases germanium increases. and that of
(C) Both the strip increases.
(D) copper strip increases germanium decreases. and that of
Answer:
(B) copper strip decreases germanium increases. and that of

Question 27.
The terminal voltage of a cell of emf E on short circuiting will be
(A) E
(B) \(\frac {E}{2}\)
(C) 2E
(D) zero
Answer:
(D) zero

Question 28.
If a battery of emf 2 V with internal resistance one ohm is connected to an external circuit of resistance R across it, then the terminal p.d. becomes 1.5 V. The value of R is
(A) 1 Ω
(B) 1.5 Ω
(C) 2 Ω
(D) 3 Ω
Answer:
(D) 3 Ω

Question 29.
A hall is used 5 hours a day for 25 days in a month. It has 6 lamps of 100 W each and 4 fans of 150 W. The total energy consumed for the month is
(A) 1500 kWh
(B) 150 kWh
(C) 15 kWh
(D) 1.5 kWh
Answer:
(B) 150 kWh

Question 30.
The internal resistance of a cell of emf 2 V is 0.1 Ω. It is connected to a resistance of 3.9 Ω. The voltage across the cell will be
(A) 0.5 V
(B) 1.5 V
(C) 1.95 V
(D) 2 V
Answer:
(C) 1.95 V

Question 31.
The emf of a cell is 12 V. When it sends a current of 1 A through an external resistance, the p.d. across the terminals reduces to 10 V. The internal resistance of the cell is
(A) 0.1 Ω
(B) 0.5 Ω
(C) 1 Ω
(D) 2 Ω
Answer:
(D) 2 Ω

Question 32.
Three resistors, 8 Ω, 4 Ω and 10 Ω connected in parallel as shown in figure, the equivalent resistance is
Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors 33
(A) \(\frac {19}{40}\) Ω
(B) \(\frac {40}{19}\) Ω
(C) \(\frac {80}{19}\) Ω
(D) \(\frac {34}{23}\) Ω
Answer:
(B) \(\frac {40}{19}\) Ω

Question 33.
A potential difference of 20 V is applied across the ends of a coil. The amount of heat generated in it is 800 cal/s. The value of resistance of the coil will be
(A) 12 Ω
(B) 1.2 Ω
(C) 0.12 Ω
(D) 0.012 Ω
Answer:
(C) 0.12 Ω

Question 34.
In a series combination of cells, the effective internal resistance will
(A) remain the same.
(B) decrease.
(C) increase.
(D) be half that of the 1st cell.
Answer:
(C) increase.

Maharashtra Board Class 11 Physics Important Questions Chapter 11 Electric Current Through Conductors

Question 35.
The terminal voltage across a cell is more than its e.m.f., if another cell of
(A) higher e.m.f. is connected parallel to it.
(B) less e.m.f. is connected parallel to it.
(C) less e.m.f. is connected in series with it.
(D) higher e.m.f. is connected in series with it.
Answer:
(A) higher e.m.f. is connected parallel to it.

Question 36.
A 100 W, 200 V bulb is connected to a 160 volt supply. The actual power consumption would be
(A) 64 W
(B) 125 W
(C) 100 W
(D) 80 W
Answer:
(A) 64 W

Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics

Balbharti Maharashtra State Board 11th Physics Important Questions Chapter 10 Electrostatics Important Questions and Answers.

Maharashtra State Board 11th Physics Important Questions Chapter 10 Electrostatics

Question 1.
Explain: Atoms are electrically neutral.
Answer:

  1. The matter is made up of atoms which in turn consists of elementary particles proton, neutron, and electron.
  2. A proton is considered to be positively charged and an electron to be negatively charged.
  3. Neutron is electrically neutral i.e., it has no charge.
  4. An atomic nucleus is made up of protons and neutrons and hence is positively charged.
  5. Negatively charged electrons surround the nucleus so as to make an atom electrically neutral.

Question 2.
What do the below diagrams show?
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 1
Answer:

  1. Figure (a) shows insulated conductor.
  2. Figure (b) shows that positive charge is neutralized by electron from Earth.
  3. Figure (c) shows that earthing is removed, negative charge still stays in conductor due to positive charged rod.
  4. Figure (d) shows that when rod is removed, negative charge is distributed over the surface of the conductor.

Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics

Question 3.
Explain concept of charging by conduction.
Answer:

  1. When certain dissimilar substances, like fur and amber or comb and dry hair, are rubbed against each other, electrons get transferred to the other substance making them charged.
  2. The substance receiving electrons develops a negative charge while the other is left with an equal amount of positive charge.
  3. This can be called charging by conduction as charges are transferred from one body to another.

Question 4.
Explain concept of charging by induction.
Answer:

  1. If an uncharged conductor is brought near a charged body, (not in physical contact) the nearer side of the conductor develops opposite charge to that on the charged body and the far side of the conductor develops charge similar to that on the charged body. This is called induction.
  2. This happens because the electrons in a conductor are free and can move easily in presence of charged body.
  3. A charged body attracts or repels electrons in a conductor depending on whether the charge on the body is positive or negative respectively.
  4. Positive and negative charges are redistributed and are accumulated at the ends of the conductor near and away from the charged body.
  5. In induction, there is no transfer of charges between the charged body and the conductor. So when the charged body is moved away from the conductor, the charges in the conductor are free again.

Question 5.
Explain the concept of additive nature of charge.
Answer:

  1. Electric charge is additive, similar to mass. The total electric charge on an object is equal to the algebraic sum of all the electric charges distributed on different parts of the object.
  2. It may be pointed out that while taking the algebraic sum, the sign (positive or negative) of the electric charges must be taken into account.
  3. Thus, if two bodies have equal and opposite charges, the net charge on the system of the two bodies is zero.
  4. This is similar to that in case of atoms where the nucleus is positively charged and this charge is equal to the negative charge of the electrons making the atoms electrically neutral.

Question 6.
State the analogy between the additive property of charge with that of mass.
Answer:

  1. The masses of the particles constituting an object are always positive, whereas the charges distributed on different parts of the object may be positive or negative.
  2. The total mass of an object is always positive whereas, the total charge on the object may be positive, zero or negative.

Question 7.
What is quantization of charge?
Answer:

  1. Protons (+ve) and electrons (-ve) are the charged particles constituting matter, hence the charge on an object must be an integral multiple of ± e i.e., q = ± ne, where n is an integer.
  2. Charge on an object can be increased or decreased in multiples of e.
  3. It is because, during the charging process an integral number of electrons can be transferred from one body to the other body. This is known as quantization of charge or discrete nature of charge.

Question 8.
Explain with an example why quantization of charge is not observed practically.
Answer:
i. The magnitude of the elementary electric charge (e), is extremely small. Due to this, the number of elementary charges involved in charging an object becomes extremely large.

ii. For example, when a glass rod is rubbed with silk, a charge of the order of one µC (10-6 C) appears on the glass rod or silk. Since elementary charge e = 1.6 × 10-19 C. the number of elementary charges on the glass rod (or silk) is given by
n = \(\frac {10^{-6}C}{1.6×10^{-19}C}\) = 6.25 × 1012
Since, it is tremendously large number, the quantization of charge is not observed and one usually observes a continuous variation of charge.

Question 9.
The total charge of an isolated system is always conserved. Explain with an example.
Answer:

  1. When a glass rod is rubbed with silk, it becomes positively charged and silk becomes negatively charged.
  2. The amount of positive charge on glass rod is found to be exactly the same as negative charge on silk.
  3. Thus, the systems of glass rod and silk together possesses zero net charge after rubbing.
    Hence, the total charge of an isolated system is always conserved.

Question 10.
Explain the conclusion when charges are brought close to each other.
Answer:

  1. Unlike charges attract each other.
  2. Like charges repel each other.

Question 11.
How much positive and negative charge is present in 1 g of water? How many electrons are present in it?
(Given: molecular mass of water is 18.0 g)
Answer:
Molecular mass of water is 18 gram, that means the number of molecules in 18 gram of water is 6.02 × 1023
∴ Number of molecules in lgm of water = \(\frac {6.02×10^{23}}{18}\)
One molecule of water (H2O) contains two hydrogen atoms and one oxygen atom. Thus, the number of electrons in ILO is sum of the number of electrons in H2 and oxygen. There are 2 electrons in H2 and 8 electrons in oxygen.
∴ Number of electrons in H2O = 2 + 8 = 10
Total number of protons / electrons in one gram of water
= \(\frac {6.02×10^{23}}{18}\) × 10 = 3.344 × 1023
Total positive charge
= 3.344 × 1023 × charge on a proton
= 3.344 × 1023 × 1.6 × 10-19C
= 5.35 × 104 C
This positive charge is balanced by equal amount of negative charge so that the water molecule is electrically neutral.
∴ Total negative charge = 5.35 × 104C

Question 12.
Define point charge. Which law explains the interaction between charges at rest?
Answer:

  1. A point charge is a charge whose dimensions are negligibly small compared to its distance from another bodies.
  2. Coulomb’s law explains the interaction between charges at rest.

Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics

Question 13.
State and explain Coulomb’s law of electric charge in scalar form.
Answer:
Coulomb’s law:
The force of attraction or repulsion between two point charges at rest is directly proportional to the product of the magnitude of the charges and inversely proportional to the square of the distance between them. This force acts along the line joining the two charges.
Explanation:
i. Let q1 and q2 be the two point charges at rest with each other and separated by a distance r. F is the magnitude of electrostatic force of attraction or repulsion between them.

ii. According to Coulomb’s law.
F ∝ \(\frac {q_1q_2}{r^2}\)
∴ F = K\(\frac {q_1q_2}{r^2}\)
where, K is the constant of proportionality which depends upon the units of F, q1, q2, r and medium in which charges are placed.

Question 14.
State conditions for electrostatic force to be attractive or repulsive.
Answer:

  1. The force between the two charges will be attractive, if the charges are unlike (one positive and one negative).
  2. The force between the two charges will be repulsive, if the charges are similar (both positive or both negative).

Question 15.
Prove that relative permittivity is the ratio of the force between two point charges placed a certain distance apart in free space or vacuum to the force between the same two point charges when placed at the same distance in the given medium.
Answer:
i. The force between the two charges placed in a medium is given by,
Fmed = \(\frac {1}{4πε}\) (\(\frac {q_1q_2}{r^2}\)) …………. (1)
where, ε is called the absolute permittivity of the medium.

ii. The force between the same two charges placed in free space or vacuum at distance r is given by,
Fvac = \(\frac {1}{4πε_0}\) (\(\frac {q_1q_2}{r^2}\)) …………. (1)
Dividing equation (2) by equation (1),
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 2
Hence, relative permittivity is the ratio of the force between two point charges placed a certain distance apart in free space or vacuum to the force between the same two point charges when placed at the same distance in the given medium.

Question 16.
If relative permittivity of water is 80 then derive the relation between Fwater and Fvacuum. What can be concluded from it?
Answer:
i. The force between two point charges q1 and q2 placed at a distance r in a medium of relative permittivity εr, is given by
Fmed = \(\frac{1}{4 \pi \varepsilon_{0} \varepsilon_{r}} \frac{\mathrm{q}_{1} \mathrm{q}_{2}}{\mathrm{r}^{2}}\) …………. (1)
If the medium is vacuum,
Fvac = \(\frac{1}{4 \pi \varepsilon_{0}} \frac{\mathrm{q}_{1} \mathrm{q}_{2}}{\mathrm{r}^{2}}\) …………. (2)

ii. Dividing equation (2) by equation (1),
\(\frac{\mathrm{F}_{\mathrm{vac}}}{\mathrm{F}_{\text {med }}}\) = εr
For water, εr = 80 ……….. (given)
∴ Fwater = \(\frac {F_{vac}}{80}\)

iii. This means that when two point charges are placed some distance apart in water, the force between them is reduced to (\(\frac {1}{80}\))th of the force between the same two charges placed at the same distance in vacuum.

iv. Thus, it is concluded that a material medium reduces the force between charges by a factor of er, its relative permittivity.

Question 17.
Give conversions of micro-coulomb, nano-coulomb and pico-coulomb to coulomb.
Answer:
1 microcoulomb (µC) = 10-6 C
1 nanocoulomb (nC) = 10-9 C
1 picocoulomb (pC) = 10-12 C

Question 18.
Explain Coulomb’s law in vector form.
Answer:
i. Let q1 and q2 be the two similar point charges situated at points A and B and let \(\vec{r}\)12 be the distance of separation between them.

ii. The force \(\vec{F}\)21 exerted on q2 by q1 is given by,
\(\overrightarrow{\mathrm{F}}_{21}=\frac{1}{4 \pi \varepsilon_{0}} \frac{\mathrm{q}_{1} \mathrm{q}_{2}}{\left|\mathrm{r}_{12}\right|^{2}} \times \hat{\mathrm{r}}_{12}\)
where, \(\hat{r}\)12 is the unit vector from A to B.
\(\vec{F}\)21 acts on q2 at B and is directed along BA, away from B.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 3

iii. Similarly, the force \(\vec{F}\)12 exerted on q1 by q2 is given by, \(\vec{F}\)12 = \(\frac{1}{4 \pi \varepsilon_{0}} \frac{\mathrm{q}_{1} \mathrm{q}_{2}}{\left|\mathrm{r}_{12}\right|^{2}} \times \hat{\mathrm{r}_{21}}\)
where, \(\hat{r}\)21 is the unit vector from B to A. \(\vec{F}\)12 acts on q1 at A and is directed along BA, away from A.

iv. The unit vectors \(\hat{r}\)12 and \(\hat{r}\)21 are oppositely directed i.e., \(\hat{r}\)12 = –\(\hat{r}\)21
Hence, \(\vec{F}\)21 = –\(\vec{F}\)12
Thus, the two charges experience force of equal magnitude and opposite in direction.

v. These two forces form an action-reaction pair.

vi. As \(\vec{F}\)21 and \(\vec{F}\)12 act along the line joining the two charges, the electrostatic force is a central force.

Question 19.
State similarities and differences of gravitational and electrostatic forces.
Answer:
i. Similarities:
a. Both forces obey inverse square law:
F ∝ \(\frac{1}{r^2}\)
b. Both are central forces and they act along the line joining the two objects.

ii. Differences:
a. Gravitational force between two objects is always attractive while electrostatic force between two charges can be either attractive or repulsive depending on the nature of charges.
b. Gravitational force is about 36 orders of magnitude weaker than the electrostatic force.

Question 20.
Charge on an electron is 1.6 × 10-19 C. How many electrons are required to accumulate a charge of one coulomb?
Answer:
1 electron = 1.6 × 10-19 C
∴ 1 C = \(\frac{1}{1.6 \times 10^{-19}}\) electrons
= 0.625 × 1019 electrons
……. (Taking reciprocal from log table)
= 6.25 × 1018 electrons
Hence, 6.25 × 1018 electrons are required to accumulate a charge of one coulomb.

Question 21.
What is the force between two small charge spheres having charges of 2 × 10-7 C and 3 × 10-7 C placed 30 cm apart in air?
Answer:
Given: q1 = 2 × 10-7 C, q2 = 3 × 10-7 C
r = 30 cm = \(\frac {30}{100}\) m = 0.3 m
To find: Force (F)
Formula: F = \(\frac {1}{4πε_0}\) \(\frac {q_1q_2}{r^2}\)
Calculation: From formula,
F = \(\frac{9 \times 10^{9} \times 2 \times 10^{-7} \times 3 \times 10^{-7}}{(0.3)^{2}}\)
∴ F = 6 × 10-3 N

Question 22.
The electrostatic force on a small sphere of charge 0.4 µC due to another small sphere of charge -0.8 µC in air is 0.2 N. (i) What is the distance between the two spheres? (ii) What is the force on the second sphere due to the first?
Answer:
i. Given: q1 = 0.4 µC = 0.4 × 10-6 C,
q2 = -0.8 µC = -0.8 × 10-6 C, F = 0.2 N
To find: i. Distance (r)
ii. Force on second sphere (F)
Formula: F = \(\frac {1}{4πε_0}\) \(\frac {q_1q_2}{r^2}\)
Calculation:
i. From formula,
r² = \(\frac {1}{4πε_0}\) \(\frac {q_1q_2}{F}\)
r² = \(\frac{9 \times 10^{9} \times 0.4 \times 10^{-6} \times 0.8 \times 10^{-6}}{0.2}\)
= 0.0144
∴ r = \(\sqrt{0.0144}\) = 0.12 m
∴ r = 12 cm

ii. The force on the second sphere due to the first is also 0.2 N and is attractive in nature.

Question 23.
i. Two insulated charged copper spheres A and B have their centres separated by a distance of 50 cm. What is the mutual force of electrostatic repulsion, if the charge on each is 6.5 × 10-7 C? The radii of A and B are negligible compared to the distance of separation,
ii. What is the force of repulsion if each sphere is charged double the above amount and the distance between them is halved?
Answer:
Given: q1 = 6.5 × 10-7 C q2 = 6.5 × 10-7 C
r = 50 cm = 0.50 m
To find: Force of repulsion (F)
Formula: F = \(\frac {1}{4πε_0}\) \(\frac {q_1q_2}{r^2}\)
Calculation:
From formula,
F = \(\frac{9 \times 10^{9} \times 6.5 \times 10^{-7} \times 6.5 \times 10^{-7}}{(0.50)^{2}}\)
F = 1.52 × 10-2 N

ii. When each charge is doubled and the distance between them is reduced to half, then
F = \(\frac{1}{4 \pi \varepsilon_{0}} \frac{\left(2 q_{1}\right)\left(2 q_{2}\right)}{(r / 2)^{2}}\)
= 16 × \(\frac {1}{4πε_0}\) \(\frac {q_1q_2}{r^2}\) = 16 × 1.52 × 10-2
∴ F = 0.24 N

Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics

Question 24.
Calculate and compare the electrostatic and gravitational forces between two protons which are 10-15 m apart. Value of G = 6.674 × 10-11 m³ kg-1 s-2 and mass of the porton is 1.67 × 10-27 kg.
Answer:
Given: G = 6.674 × 10-11 m³ kg-1 s-2
mp = 1.67 × 10-27 kg.
qp = 1.67 × 10-19 C, r = 10-15
To find:
i. Electrostatic Force (FE)
ii. Gravitational Force (FG)
Formula: i. FE = \(\frac {1}{4πε_0}\) \(\frac {q_1q_2}{r^2}\)
ii. FE = \(\frac {Gm_1m_2}{r^2}\)
Calculation:
From formula (i),
\(\mathrm{F}_{\mathrm{E}}=9 \times 10^{9} \times \frac{1.6 \times 10^{-19} \times 1.6 \times 10^{-19}}{\left(10^{-15}\right)^{2}}\)
= 9 × 1.6 × 1.6 × 10
= 90 × 1.6 × 1.6
= antilog [log 90 + log 1.6 + log 1.6]
= antilog [1.9542 + 0.2041 + 0.2041]
= antilog [2.3624]
= 2.303 × 10² N
From formula (ii),
\(\mathrm{F}_{\mathrm{G}}=6.674 \times 10^{-11} \times \frac{1.67 \times 10^{-27} \times 1.67 \times 10^{-27}}{\left(10^{-15}\right)^{2}}\)
= 6.674 × 1.67 × 1.67 × 10-35
= {antilog [log 6.674 + log 1.67 + log 1.67]} × 10-35
= {antilog [0.8244 + 0.2227 + 0.2227]} × 10-35
= {antilog [1.2698]} × 10-35
= 1.861 × 101 × 10-35
= 1.861 × 10-34 N
Now,
\(\frac{\mathrm{F}_{\mathrm{E}}}{\mathrm{F}_{\mathrm{G}}}=\frac{2.303 \times 10^{2}}{1.861 \times 10^{-34}}\)
= {antilog [log 2.303 – log 1.861]} × 1036
= {antilog [0.3623 – 0.2697]} × 1036
= {antilog [0.0926]}
= 1.238 × 1036
∴ FE ≈ 1036 × FG

Question 25.
State and explain principle of superposition.
Answer:
Statement: When a number of charges are interacting, the resultant force on a particular charge is given by the vector sum of the forces exerted by individual charges.
Explanation:
i. Consider a number of point charges q1, q2, q3 ……………… kept at points A1, A2, A3 ………….. as shown in figure.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 4

ii. The force exerted on the charge q1 by q2 is \(\vec{F}\)12 The value of \(\vec{F}\)12 is calculated by ignoring the presence of other charges. Similarly, force \(\vec{F}\)13, \(\vec{F}\)14 can be found, using the Coulomb’s law.

iii. Total force \(\vec{F}\)1 on charge qi is the vector sum of all such forces.
\(\vec{F}\)1 = \(\vec{F}\)12 + \(\vec{F}\)13 + \(\vec{F}\)14 + …………..
\( =\frac{1}{4 \pi \varepsilon_{0}}\left[\frac{\mathrm{q}_{1} \mathrm{q}_{2}}{\left|\mathrm{r}_{21}\right|^{2}} \times \hat{\mathrm{r}}_{21}+\frac{\mathrm{q}_{1} \mathrm{q}_{3}}{\left|\mathrm{r}_{31}\right|^{2}} \times \hat{\mathrm{r}}_{31}+\ldots .\right]\)

where \(\hat{r}\)21, \(\hat{r}\)31 are unit vectors directed to q1 from q2, q3 respectively and r21, r31, r41 are the distances from q1 to q2, q3 respectively.

iv. If q1, q2, q3 ……., qn are the point charges then the force \(\vec{F}\) exerted by these charges on a test charge q0 is given by,
\(\vec{F}\)test = \(\vec{F}\)1 = \(\vec{F}\)2 + \(\vec{F}\)3 + …. + \(\vec{F}\)n
= \(\sum_{\mathrm{n}=1}^{\mathrm{n}} \mathrm{F}_{\mathrm{n}}=\frac{1}{4 \pi \varepsilon_{0}} \sum_{\mathrm{n}=1}^{\mathrm{n}} \frac{\mathrm{q}_{0} \mathrm{q}_{\mathrm{n}}}{\mathrm{r}_{\mathrm{n}}^{2}} \hat{\mathrm{r}}_{\mathrm{n}}\)
Where, \(\hat{r}\)n, is a unit vector directed from the nth charge to the test charge q0 and r2 is the
separation between them, \(\vec{r}\)n = rn \(\hat{r}\)n

Question 26.
Three charges of 2 µC, 3 µC and 4 µC are placed at points A, B and C respectively, as shown in the figure. Determine the force on A due to other charges.
(Given: AB = 4 cm, BC = 3 cm)
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 5
Answer:
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 6
Using pythagoras theorem
AC = \(\sqrt {AB^2+BC^2}\)
= \(\sqrt {4^2+3^2}\)
AC = 5 cm
Magnitude of force \(\vec{F}\)AB on A due to B is,
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 7
In ∆ABC 4
cos θ = \(\frac {4}{5}\)
θ = cos-1 (\(\frac {4}{5}\)) = 36.87°
Forces acting points A are
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 8
= 59.36 N
Direction of resultant force is 36.87° (north of west)
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 9
[Note: The question given above is modified considering minimum requirement of data needed to solve the problem.]

Question 27.
There are three charges of magnitude 3 pC, 2 pC and 3 pC located at three corners A, B and C of a square ABCD of each side measuring 2 m. Determine the net force on 2 pC charge.
Answer:
Given: q1 = 3 µC, q2 = 2 µC, q3 = 3 µC, r = 2 m
To find: Net force on q2 (R)
Formula: F = \(\frac {1}{4πε_0}\) \(\frac {q_1q_2}{r^2}\)
Calculation:
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 10
From the formula,
Force on q2 because of q1
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 11
Net force on q2 is the resultant force of \(\vec{F}\)21 and \(\vec{F}\)23 which is given by,
R = \(\sqrt{\mathrm{F}_{21}^{2}+\mathrm{F}_{23}^{2}}\)
= \(\sqrt{\left(1.35 \times 10^{-2}\right)^{2}+\left(1.35 \times 10^{-2}\right)^{2}}\)
∴ R = 1.91 × 10-2 N

Question 28.
Explain the concept of electric field.
Answer:

  1. The space around a charge gets modified when a test charge is brought in that region, it experiences a coulomb force. The region around a charged object in which coulomb force is experienced by another charge is called electric field.
  2. Mathematically, electric field is defined as the force experienced per unit charge.
  3. The coulomb force acts across an empty space (vacuum) and does not need any intervening medium for its transmission.
  4. The electric field exists around a charge irrespective of the presence of other charges.
  5. Since the coulomb force is a vector, the electric field of a charge is also a vector and is directed along the direction of the coulomb force, experienced by a test charge.

Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics

Question 29.
Define electric field. State its SI unit and dimensions.
Answer:

  1. Electric field is the force experienced by a test charge in presence of the given charge at the given distance from it.
    \(\vec{E}\) = \(\lim _{q \rightarrow 0} \frac{\vec{F}}{q}\)
  2. SI unit: newton per coulomb (N/C) or volt per metre (V/m).
  3. Dimensions: [L M T-3 A-1]

Question 30.
Establish relation between electric field intensity and electrostatic force.
Answer:
i. Let Q and q be two charges separated by a distance r.
The coulomb force between them is given by \(\vec{F}\) = \(\frac {1}{4πε_0}\) \(\frac {Qq}{r^2}\) \(\hat{r}\)
where, \(\hat{r}\) is the unit vector along the line joining Q to q.

ii. Therefore, electric field due to charge Q is given \(\vec{F}\) = \(\frac{\vec{F}}{\mathrm{q}}=\frac{1}{4 \pi \varepsilon_{0}} \frac{\mathrm{Q}}{\mathrm{r}^{2}} \hat{\mathrm{r}}\)

iii. Electric field at a point is useful to estimate the force experienced by a charge at that point.

Question 31.
State an expression for electric field on the surface of the sphere due to a positive point charge placed at its centre.
Answer:
The magnitude of electric field at a distance r from a point charge Q is same at all points on the surface of a sphere of radius r as shown in figure.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 12
ii. Magnitude of electric field is given by,
E = \(\frac {1}{4πε_0}\) \(\frac {Q}{r^2}\)
iii. Its direction is along the radius of the sphere, pointing away from its centre if the charge is positive.

Question 32.
Derive expression for electric field intensity due to a point charge in a material medium.
Answer:
i. Consider a point charge q placed at point O in a medium of dielectric constant K as shown in figure.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 13

ii. Consider the point P in the electric field of point charge at distance r from q. A test charge q0 placed at the point P will experience a force which is given by the Coulomb’s law,
\(\vec{F}\) = \(\frac{1}{4 \pi \varepsilon_{0} \mathrm{~K}} \frac{\mathrm{qq}_{0}}{\mathrm{r}^{2}} \hat{\mathrm{r}}\)
where \(\hat{r}\) is the unit vector in the direction of force i.e., along OP.

iii. By the definition of electric field intensity,
\(\vec{F}\) = \(\frac{\vec{F}}{\mathrm{q}_{0}}=\frac{1}{4 \pi \varepsilon_{0} \mathrm{~K}} \frac{\mathrm{q}}{\mathrm{r}^{2}} \hat{\mathrm{r}}\)
The direction of \(\vec{E}\) will be along OP when q is positive and along PO when q is negative.

iv. The magnitude of electric field intensity in a medium is given by, E = \(\frac{1}{4 \pi \varepsilon_{0} \mathrm{~K}} \frac{\mathrm{q}}{\mathrm{r}^{2}}\)

v. For air or vacuum, K = 1 then
E = \(\frac{1}{4 \pi \varepsilon_{0}} \frac{\mathrm{q}}{\mathrm{r}^{2}}\)

Question 33.
Show graphical representation of variation of coulomb force and electric field due to point charge with distance.
Answer:
Electrostatic force: F = \(\frac{1}{4 \pi \varepsilon_{0}} \frac{\mathrm{q}_{1} \mathrm{q}_{2}}{\mathrm{r}^{2}}\)
Electric field: E : \(\frac{1}{4 \pi \varepsilon_{0}} \frac{\mathrm{q}}{\mathrm{r}^{2}}\)
The coulomb force (F) between two charges and electric field (E) due to a charge both follow the inverse square law.
(F ∝ 1/r², E ∝ 1/r²)
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 14

Question 34.
What is non-uniform electric field?
Answer:
A field whose magnitude and direction is not the same at all points.
For example, field due to a point charge. In this case, the magnitude of field is same at distance r from the point charge in any direction but the direction of the field is not same.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 15

Question 35.
Derive relation between electric field (E) and electric potential (V).
Answer:
i. A pair of parallel plates is connected as shown in the figure. The electric field between them is uniform
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 16

ii. A potential difference V is applied between two parallel plates separated by a distance ‘d’.

iii. The electric field between them is directed from plate A to plate B.

iv. A charge +q placed between the plates experiences a force F due to the electric field.

v. If the charge is moved against the direction of field, i.e., towards the positive plate, some amount of work is done on it.

vi. If the charge is moved +q from the negative plate B to the positive plate A, then the work done against the field is W = Fd; where ‘d’ is the separation between the plates.

vii. The potential difference V between the two plates is given by W = Vq,
but W = Fd
∴ Vq = Fd
∴ \(\frac {F}{q}\) = \(\frac {V}{d}\) = E
∴ Electric field can be defined as E = V/d.

Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics

Question 36.
What are electric lines of force?
Answer:
i. An electric line of force is an imaginary curve drawn in such a way that the tangent at any given point on this curve gives the direction of the electric field at that point.

ii. If a test charge is placed in an electric field it would be acted upon by a force at every point in the field and will move along a path.

iii. The path along which the unit positive charge moves is called a line of force.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 17

iv. A line of force is defined as a curve such that the tangent at any point to this curve gives the direction of the electric field at that point.

v. The density of field lines indicates the strength of electric fields at the given point in space.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 18

Question 37.
State the characteristics of electric lines of force.
Answer:

  1. The lines of force originate from a positively charged object and end on a negatively charged object.
  2. The lines of force neither intersect nor meet each other, as it will mean that electric field has two directions at a single point.
  3. The lines of force leave or terminate on a conductor normally.
  4. The lines of force do not pass through conductor i.e., electric field inside a conductor is always zero, but they pass through insulators.
  5. Magnitude of the electric field intensity is proportional to the number of lines of force per unit area of the surface held perpendicular to the field.
  6. Electric lines of force are crowded in a region where electric intensity is large.
  7. Electric lines of force are widely separated from each other in a region where electric intensity is small
  8. The lines of force of an uniform electric field are parallel to each other and are equally spaced.

Question 38.
Find the distance from a charge of 4 µC placed in air which produces electric field of intensity 9 × 10³ N/C.
Answer:
Given: K = 1, E = 9 × 10³ N/C
q = 4 µC = 4 × 10-6
To Find: Distance (r)
Formula: E = \(\frac{1}{4 \pi \varepsilon_{0} K} \frac{q}{r^{2}}\)
Calculation from formula
9 × 10³ = \(\frac{1}{4 \pi \varepsilon_{0}} \frac{4 \times 10^{-6}}{r^{2}}\)
∴ 9 × 10³ = 9 × 109 \(\frac{4 \times 10^{-6}}{\mathrm{r}^{2}}\)
∴ r² = 4
∴ r = 2 m

Question 39.
What is the magnitude of a point charge chosen so that the electric field 50 cm away has magnitude 2.0 N/C?
Answer:
Given: r = 50 cm – 0.5 m, E = 2 N/C,
To find: Magnitude of charge (q)
Formula: E = \(\frac{1}{4 \pi \varepsilon_{0}} \frac{q}{r^{2}}\)
Calculation from formula
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 19

Question 40.
Three point charges are placed at the vertices of a right angled isosceles triangle as shown in the given figure. What is the magnitude and direction of the resultant electric field at point P which is the mid point of its hypotenuse?
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 20
Answer:
Electric field at P due to the charges at A, B and C are shown in the figure.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 21
Let \(\vec{E}\)A be the field at P due to charge at A and \(\vec{E}\)c be the field at P due to charge at C.
Since P is the midpoint of AC and the fields at A and C are equal in magnitudes and are opposite in direction, EA = – EC .
i.e., \(\vec{E}\)A + \(\vec{E}\)C = 0.
Thus, the field at P is only to the charge at B and is given by,
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 22

Question 41.
A simplified model of hydrogen atom consists of an electron revolving about a proton at a distance of 5.3 × 10-11 m. The charge on a proton is +1.6 × 10-19 C. Calculate the intensity of the electric field due to proton at this distance. Also find the force between electron and proton.
Answer:
Given: r = 5.3 × 10-11 m
q = 1.6 × 10-19 C
To Find: i. Intensity of electric field (E)
ii. Force (F)
Formula: i. E = \(\frac{1}{4 \pi \varepsilon_{0}} \times \frac{\mathrm{q}}{\mathrm{r}^{2}}\)
ii. E = \(\frac {F}{q}\)
Calculation from formula (i)
E = 9 × 109 × \(\frac{1.6 \times 10^{-19}}{\left(5.3 \times 10^{-11}\right)^{2}}\)
= 5.126 × 1011 N/C
Force between electron and proton,
Force between electron and proton,
F = E × qe ….[From formula (ii)]
= 5.126 × 10-11 × -1.6 × 10-19
= -8.201 × 108 N

Question 42.
The force exerted by an electric field on a charge of +10 µC at a point is 16 × 10-4 N. What is the intensity of the electric field at the point?
Answer:
Given: q = 10 µC= 10 × 10-6 C, F = 16 × 10-4 N
To find: Electric field intensity (E)
Formula: E = \(\frac {F}{q}\)
Calculation: From formula,
E = \(\frac {16×10^{-4}}{10×10^{-6}}\) = 160 N/C

Question 43.
What is the force experienced by a test charge of 0.20 µC placed in an electric field of 3.2 × 106 N/C?
Answer:
Given: q0 = 0.20 µC = 0.2 × 106 C,
E = 3.2 × 106 N/C
To find: Force (F)
Formula: E = \(\frac {F}{q_0}\)
Calculation: From formula,
F = Eq0
∴ F = 3.2 × 106 × 0.2 × 10-6 = 0.64 N

Question 44.
Gap between two electrodes of the spark-plug used in an automobile engine is 1.25 mm. If the potential of 20 V is applied across the gap, what will be the magnitude of electric field between the electrodes?
Answer:
Given: V = 20 V
d = 1.25 mm = 1.25 × 10-3 m
To Find: Magnitude of electric field (E)
Formula: E = \(\frac {V}{d}\)
Calculation: From formula,
E = \(\frac {20}{1.25×10^{-3}}\)
= 1.6 × 104 V/m

Question 45.
If 100 joules of work must be done to move electric charge equal to 4 C from a place, where potential is -10 volt to another place where potential is V volt, find the value of V.
Answer:
Given: q0 = 4 C,
VA = -10 volt,
VB = V volt,
WAB = 100 J
To Find: Potential (V)
Formula: VB – VA = \(\frac {W_{AB}}{q_0}\)
Calculation: From formula,
V – (-10) = \(\frac {100}{4}\) = 25
∴ V + 10 = 25
∴ V = 15 volt

Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics

Question 46.
Find the work done when a point charge of 2.0 pC is moved from a point at a potential of -10 V to a point at which the potential is zero.
Answer:
VA = -10V,
VB = 0,
q = 2 × 10-6 C
To Find: Work done (W)
Formula: VBA = \(\frac {W}{q}\)
Calculation: From formula,
W = VBA × q
= (VB – VA) × q
= (0 + 10) × 2 × 10-6
= 20 × 10-6 J
∴ W = 2 × 10-5 J

Question 47.
Explain the term: Electric flux
Answer:
i. The number of lines of force per unit area is the intensity of the electric field \(\vec{E}\).
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 23

ii. When the area is inclined at an angle θ with the direction of electric field, the electric flux can be calculated as follows.
Let the angle between electric field \(\vec{E}\), and area vector \(\vec{dS}\) be θ, then the electric flux passing through are dS is given by
dø = (component of dS along \(\vec{E}\)) × (area of \(\vec{dS}\))
dø = EdS cos θ
dø = \(\vec{E}\) .\(\vec{dS}\)
Total flux through the entire surface .
ø = ∫dø = \( \int_{S} \vec{E} \cdot d \vec{S}=\vec{E} \cdot \vec{S}\)

iii. The SI unit of electric flux can be calculated using,
ø = \(\vec{E}\). \(\vec{S}\) = (V/m) m² = V m
[Note: Area vector is a vector whose magnitude is equal to area and is directed normal to its surface]

Question 48.
The electric flux through a plane surface of area 200 cm² in a region of uniform electric field 20 N/C is 0.2 N m²/C. Find the angle between electric field and normal to the surface.
Answer:
Given: ds = 200 cm² = 2 × 10-2 m², E = 20 N/C,
ø = 0.2 N m²/C
To find: Angle between electric field and normal (θ)
Formula: ø = Eds cos θ
Calculation:
From formula,
cos θ = \(\frac {ø}{Eds}\) = \(\frac {0.2}{20×2×10^{-2}}\) = \(\frac {1}{2}\)
∴ θ = cos-1 (\(\frac {1}{2}\))
∴ θ = 60°

Question 49.
A charge of 5.0 C is kept at the centre of a sphere of radius 1 m. What is the flux passing through the sphere? How will this value change if the radius of the sphere is doubled?
Answer:
Given: q = 5C, r = 1 m
To find: Flux (ø)
Formulae: i. E = \(\frac{1}{4 \pi \varepsilon_{0}} \times \frac{\mathrm{q}}{\mathrm{r}^{2}}\)
ii. ø = E × A = E (4πr²)
Calculation: From formula (i),
E = 9 × 109 × \(\frac {5}{1^2}\)
= 4.5 × 1010 N/C
From formula (ii),
ø = E × 4 π r²
= 4.5 × 1010 × 4 × 3.14 × 1²
ø = 5.65 × 1011 Vm
This value of flux will not change if radius of sphere is doubled. Though radius of sphere will increase, increased distance will reduce the electric field intensity. As E ∝ \(\frac {1}{r^2}\) and A × r² net variation in total flux will not be observed.

Question 50.
State and prove Gauss’ law of electrostatics.
Answer:
Statement:
The flux of the net electric field through a closed surface equals the net charge enclosed by the surface divided by Eo.
\(\int \vec{E} \cdot \overrightarrow{\mathrm{dS}}=\frac{\mathrm{Q}}{\varepsilon_{0}}\)
where Q is the total charge within the surface.

Proof:
i. Consider a closed surface of any shape which encloses number of positive electric charges.

ii. Imagine a small charge +q present at a point O inside closed surface. Imagine an infinitesimal area dS of the given irregular closed surface.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 24

iii. The magnitude of electric field intensity at point P on dS due to charge +q at point O is, E = \(\frac{1}{4 \pi \varepsilon_{0}}\left(\frac{\mathrm{q}}{\mathrm{r}^{2}}\right)\) ………… (1)

iv. The direction of E is away from point O. Let θ be the angle subtended by normal drawn to area dS and the direction of E

v. Electric flux passing through area (dø)
= Ecosθ dS
= \(\frac{\mathrm{q}}{4 \pi \varepsilon_{0} \mathrm{r}^{2}}\) cosθ dS ………….. (from 1)
= \(\left(\frac{\mathrm{q}}{4 \pi \varepsilon_{0}}\right)\left(\frac{\mathrm{d} \mathrm{S} \cos \theta}{\mathrm{r}^{2}}\right)\)
But, dω = \(\frac {dS cos θ}{r^2}\)
where, dco is the solid angle subtended by area dS at a point O.
∴ dø = \(\left(\frac{\mathrm{q}}{4 \pi \varepsilon_{0}}\right)\) dω …………. (2)

vi. Total electric flux crossing the given closed surface can be obtained by integrating equation (2) over the total area.
\(\phi_{\mathrm{E}}=\int_{\mathrm{s}} \mathrm{d} \phi=\int_{\mathrm{s}} \overrightarrow{\mathrm{E}} \cdot \overrightarrow{\mathrm{dS}}=\int \frac{\mathrm{q}}{4 \pi \varepsilon_{0}} \mathrm{~d} \omega=\frac{\mathrm{q}}{4 \pi \varepsilon_{0}} \int \mathrm{d} \omega\)

vii. But ∫dω = 4π = solid angle subtended by entire closed surface at point O.
Total Flux = \(\frac {q}{4πε_0}\) (4π)
∴ øE = \(\int_{\mathrm{s}} \overrightarrow{\mathrm{E}} \cdot \overrightarrow{\mathrm{dS}}=\frac{+\mathrm{q}}{\varepsilon_{0}}\)

viii. This is true for every electric charge enclosed by a given closed surface.
Total flux due to charge q1, over the given closed surface = + \(\frac {q_1}{ε_0}\)
Total flux due to charge q2, over the given closed surface = + \(\frac {q_2}{ε_0}\)
Total flux due to charge qn, over the given closed surface = +\(\frac {q_n}{ε_0}\)

ix. According to the superposition principle, the total flux c|> due to all charges enclosed within the given closed surface is
\(\phi_{\mathrm{E}}=\frac{\mathrm{q}_{1}}{\varepsilon_{0}}+\frac{\mathrm{q}_{2}}{\varepsilon_{0}}+\frac{\mathrm{q}_{3}}{\varepsilon_{0}}+\ldots+\frac{\mathrm{q}_{\mathrm{n}}}{\varepsilon_{0}}=\sum_{\mathrm{i}=1}^{\mathrm{i}=\mathrm{n}} \frac{\mathrm{q}_{\mathrm{i}}}{\varepsilon_{0}}=\frac{\mathrm{Q}}{\varepsilon_{0}}\)

Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics

Question 51.
With a help of diagram, state the direction of flux due to positive charge, negative charge and charge outside a closed surface.
Answer:
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 25
Positive sign indicates that the flux is directed outwards, away from the charge.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 26
If the charge is negative, the flux will be is directed inwards.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 27
If a charge is outside the closed surface, the net flux through it will be zero.

Question 52.
Explain: Electric flux is independent of shape and size of closed surface.
Answer:
i. The net flux crossing an enclosed surface is equal to \(\frac {q}{ε_0}\) where q is the net charge inside the closed surface.

ii. Consider a charge +q at the centre of concentric circles as shown in figure below.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 28
As the charge inside the sphere is unchanged, the flux passing through a sphere of any radius is the same.

iii. Thus, if the radius of the sphere is increased by a factor of 2, the flux passing through is surface remains unchanged.

iv. As shown in figure same number of lines of force cross both the surfaces.
Hence, total flux is independent of shape of the closed surface radius of the sphere and size of closed surface.

Question 53.
Define the following terms with the help of a diagram.
i. Electric dipole
ii. Dipole axis
iii. Axial line
iv. Equatorial line
Answer:
i. Electric dipole: A pair of equal and opposite charges separated by a finite distance is called an electric dipole.

ii. Dipole axis: Line joining the two charges is called the dipole axis.

iii. Axial line: A line passing through the dipole axis is called axial line.

iv. Equatorial line: A line passing through the centre of the dipole and perpendicular to the axial line is called the equatorial line.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 29
AB : Electric dipole Line joining
AB: Dipole axis
X-Y : Axial line
P-Q : Equatorial line

Question 54.
What are polar molecules? Explain with examples.
Answer:

  1. Polar molecules are the molecules in which the centre of positive charge and the negative charge is naturally separated.
  2. Molecules of water, ammonia, sulphur dioxide, sodium chloride etc. have an inherent separation of centres of positive and negative charges. Such molecules are called polar molecules.

Question 55.
What are non-polar molecules? Explain with examples.
Answer:
i. Non-polar molecules are the molecules in which the centre of positive charge and the negative charge is one and the same. They do not have a permanent electric dipole. When an external electric field is applied to such molecules, the centre of positive and negative charge are displaced and a dipole is induced.

ii. Molecules such as H2, CI2, CO2, CH4, etc., have their positive and negative charges effectively centred at the same point and are called non-polar molecules.

Question 56.
Derive expression for couple acting on an electric dipole in a uniform electric field.
Answer:
i. Consider an electric dipole placed in a uniform electric field E. The axis of electric dipole makes an angle θ with the direction of electric field.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 30

ii. The force acting on charge – q at A is \(\vec{F}\)A = -q\(\vec{E}\) in the direction of\(\vec{E}\) and the force acting on charge +q at B is \(\vec{F}\)B = + q \(\vec{E}\) in the direction opposite to \(\vec{E}\).

iii. Since \(\vec{F}\)A = –\(\vec{F}\)B, the two equal and opposite forces separated by a distance form a couple.

iv. Moment of the couple is called torque and is defined by \(\vec{τ}\) = \(\vec{d}\) × \(\vec{F}\) where, d is the perpendicular distance between the two equal and opposite forces.

v. Magnitude of Torque = Magnitude of force × Perpendicular distance
∴ Torque on the dipole (\(\vec{τ}\)) = \(\vec{BA}\) × q\(\vec{E}\)
= 2lqE sin θ
but p = q2l
∴ τ = pEsin θ
∴ In vector form \(\vec{τ}\) = \(\vec{d}\) × \(\vec{E}\)

vi. If θ = 90° sin θ = 1, then τ = pE
When the axis of electric dipole is perpendicular to uniform electric field, torque of the couple acting on the electric dipole is maximum, i.e., τ = pE.

vii. If θ = 0 then τ = 0, this is the minimum torque on the dipole. Torque tends to align its axis along the direction of electric field.

Question 57.
Derive expression for electric intensity at a point on the axis of an electric dipole.
Answer:
i. Consider an electric dipole consisting of two charges -q and +q separated by a distance 2l.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 31

ii. Let P be a point at a distance r from the centre C of the dipole.

iii. The electric intensity \(\vec{E}\)a at P due to the dipole is the vector sum of the field due to the charge -q at A and +q at B.

iv. Electric field intensity at P due to the charge -q at A = \(\vec{E}\)A = \(\frac{1}{4 \pi \varepsilon_{0}} \frac{(-q)}{(r+l)^{2}} \hat{\mathrm{u}}_{\mathrm{pD}}\),
where, \(\hat{u}\)PD is unit vector directed along \(\vec{PD}\)

v. Electric intensity at P due to charge +q at B
\(\vec{E}\)B = \(\frac{1}{4 \pi \varepsilon_{0}} \frac{\mathrm{q}}{(\mathrm{r}-l)^{2}} \hat{\mathrm{u}}_{\mathrm{PQ}}\)
where, \(\hat{u}\)PQ is a unit vector directed along \(\vec{PQ}\)
The magnitude of \(\vec{E}\)B is greater than that of \(\vec{E}\)A since BP < AP

vi. Resultant field \(\vec{E}\)a at P on the axis, due to the dipole is
\(\vec{E}\)a = \(\vec{E}\)B + E\(\vec{E}\)A

vii. The magnitude of \(\vec{E}\)a is given by
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 32

ix. |\(\vec{E}\)a| is directed along PQ, which is the direction of the dipole moment \(\vec{p}\) i.e., from the negative to the positive charge, parallel to the axis.

x. If r >> l, l² can be neglected compared to r²,
|\(\vec{E}\)a| = \(\frac{1}{4 \pi \varepsilon_{0}} \frac{2 p}{r^{3}}\)

The field will be along the direction of the dipole moment \(\vec{p}\).

Question 58.
Drive expression for electric intensity at a point on the equator of an electric dipole.
Answer:
i. Electric field at point P due to charge -q at A is \(\vec{E}\)A = \(\frac{1}{4 \pi \varepsilon_{0}} \frac{(-\mathrm{q})}{(\mathrm{AP})^{2}} \hat{\mathrm{u}}_{\mathrm{PA}}\)
where, \(\hat{u}\)PA is a unit vector directed along \(\vec{PA}\)
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 33

ii. Similarly, electric field at P due to charge +q at B is
\(\vec{E}\)A = \(\frac{1}{4 \pi \varepsilon_{0}} \frac{\mathrm{q}}{(\mathrm{BP})^{2}} \hat{\mathrm{u}}_{\mathrm{BP}}\)
where \(\hat{u}\)BP is a unit vector directed along \(\vec{BP}\)

iii. Electric field at P is the sum of EA and EB
∴ \(\vec{E}\)eq = \(\vec{E}\)A + \(\vec{E}\)B

iv. Consider ∆ACP
(AP)² = (PC)² + (AC)² = r² + l² = (BP)²
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 34

v. The resultant of fields \(\vec{E}\)A and \(\vec{E}\)B acting at point P can be calculated by resolving these vectors E\(\vec{E}\)A and E\(\vec{E}\)B along the equatorial line and along a direction perpendicular to it.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 35

vi. Let the Y-axis coincide with the equator of the dipole X-axis will be parallel to dipole axis and the origin is at point P as shown.

vii. The Y-components of EA and EB are EAsin θ and EB sin θ respectively. They are equal in magnitude but opposite in direction and cancel each other. There is no contribution from them towards the resultant.

viii. The X-components of EA and EB are EAcos θ and EBcos θ respectively. They are of equal magnitude and are in the same direction.
∴ |\(\vec{E}\)eq| = EA cos θ + EB cos θ From equation (3),
|\(\vec{E}\)eq| = 2EA cos θ
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 36

x. The direction of this field is along –\(\vec{P}\) (anti-parallel to \(\vec{P}\)).
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 37

Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics

Question 59.
An electric dipole of length 2.0 cm is placed with its axis making an angle of 30° with a uniform electric field of 105 N/C as shown in figure. If it experiences a torque of 10√3 N m, calculate the magnitude of charge on dipole.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 38
Answer:
Given: 2l = 2 cm = 2 × 102 m
E = 105 N/C, τ = 10√3 Nm, θ = 30°
To find: Charge (q)
Formula: τ = q E 2 l sin θ
Calculation: From Formula.
q = \(\frac{τ}{\mathrm{E} \times 2 l \times \sin \theta}\)
= \(\frac{10 \sqrt{3}}{10^{5} \times 2 \times 10^{-2} \times \sin 30^{\circ}}\)
= 1.732 × 10-2 C

Question 60.
Explain the concept of continuous charge distribution.
Answer:
i. A system of charges can be considered as a continuous charge distribution, if the charges are located very close together, compared to their distances from the point where the intensity of electric field is to be found out.

ii. Thus, the charge distribution is said to be continuous for a system of closely spaced charges. It is treated equivalent to a total charge which is continuously distributed along a line or a surface or a volume.

Question 61.
Explain linear charge density.
Answer:
Consider charge q uniformly distributed along a linear conductor of length l, then the linear charge density (λ) is given as,
λ = \(\frac {q}{l}\)
For example, charge distributed uniformly on a straight thin rod or a thin nylon thread. If the charge is not distributed uniformly over the length of thin conductor then charge dq on small element of length dl can be written as dq = λ dl.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 39

Question 62.
Explain surface charge density.
Answer:
i. Consider a charge q uniformly distributed over a surface of area A then the surface charge density c is given as
σ = \(\frac {q}{A}\)
For example, charge distributed uniformly on a thin disc or a synthetic cloth. If the charge is not distributed uniformly over the surface of a conductor, then charge dq on small area element dA can be written as dq = σ dA.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 40

ii. SI unit of σ is (C / m²)

Question 63.
Explain volume charge density.
Answer:
i. Consider a charge q uniformly distributed throughout a volume V, then the volume charge density ρ is given as
ρ = \(\frac {q}{V}\)
For example, charge on a plastic sphere or a plastic cube. If the charge is not distributed uniformly over the volume of a material, then charge dq over small volume element dV can be written as dq = ρ dV.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 41

ii. S.I. unit of p is (C/m³)
[Note: Electric field due to a continuous charge distribution can be calculated by adding electric fields due to all these small charges.]

Question 64.
Explain the concept of static charge.
Answer:

  1. Static charges can be created whenever there is a friction between an insulator and other object.
  2. For example, when an insulator like rubber or ebonite is rubbed against a cloth, the friction between them causes electrons to be transferred from one to the other.
  3. This property of insulators is used in many applications such as photocopier, inkjet printer, painting metal panels, electrostatic precipitation/separators etc.

Question 65.
Explain the disadvantage of static charge.
Answer:

  1. When charge transferred from one body to other is very large, sparking can take place. For example, lightning in sky.
  2. Sparking can be dangerous while refuelling your vehicle.
  3. One can get static shock, if charge transferred is large.
  4. Dust or dirt particles gathered on computer or TV screens can catch static charges and can be troublesome.

Question 66.
State the precautions against static charge.
Answer:

  1. Home appliances should be grounded.
  2. Avoid using rubber soled footwear.
  3. Keep your surroundings humid (dry air can retain static charges).

Question 67.
Two charged particles having charge 3 × 10-8 C each are joined by an insulating string of length 2 m. Find the tension in the string when the system is kept on a smooth horizontal table.
Answer:
Tension (T) in the string is the force of repulsion (F) between the two charges.
According to Coulomb’s law,
F = \(\frac{\mathrm{q}_{1} \mathrm{q}_{2}}{4 \pi \varepsilon_{0} \mathrm{r}^{2}}\)
= \(\frac{9 \times 10^{9} \times 3 \times 10^{-8} \times 3 \times 10^{-8}}{2^{2}}\)
F = 2.025 × 10-6 N
Hence, tension in the string is 2.025 × 10-6 N.

Question 68.
A free pith ball of mass 5 gram carries a positive charge of 0.6 × 10-7 C. What is the nature and magnitude of charge that should be given to second ball fixed 6 cm vertically below the former pith ball so that the upper pith bath is stationary?
Answer:
Let +q2 be the charge on lower pith ball.
Now, the upper pith ball become stationary only when its weight acting downward is balanced by the upward force of repulsion between two pith balls,
i.e., FE = mg
∴ \(\frac{1}{4 \pi \varepsilon_{0}} \frac{\mathrm{q}_{1} \mathrm{q}_{2}}{\mathrm{r}^{2}}\) = mg
∴ \(\frac{9 \times 10^{9} \times 0.6 \times 10^{-7} \times \mathrm{q}_{2}}{\left(6 \times 10^{-2}\right)^{2}}\) = 5 × 10-3 × 9.8
∴ q2 = 3.27 × 10-7C
Hence, the second pith ball carries a positive charge of 3.27 × 10-7C.

Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics

Question 69.
A water drop of mass 11.0 mg and having a charge of 1.6 × 10-6 C stays suspended in a room. What will be the magnitude and direction of electric Held in the room?
Answer:
As the drop is suspended,
Force (F) due to electric field balances the weight of the drop.
∴ F = mg ………….. (1)
Here, m = 11.0 mg
= 11 × 10-6 kg,
q = 1.6 × 10-6 C
Electric field is given by,
E = \(\frac {F}{q}\)
= \(\frac {mg}{q}\)
= \(\frac {11×10^{-6}×9.8}{1.6×10^{-6}}\)
E = 67.4 N/C
As upward force balances the weight, hence direction of electric field must be vertically upwards.

Question 70.
A charged metallic sphere A is suspended by a nylon thread. Another charged metallic sphere B held by an insulating handle is brought close to A such that the distance between their centres is 10 cm, as shown in figure (a). The resulting repulsion of A is noted (for example, by shining a beam of light and measuring the deflection of its shadow on a screen.) Spheres A and B are touched by uncharged spheres C and D respectively, as shown in figure (b). C and D are then removed and B is brought closer to A to a distance of 5.0 cm between their centres, as shown in figure (c). What is the expected repulsion of A on the basis of Coulomb’s law? Spheres A and C and spheres B and D have identical sizes. Ignore the sizes of A and B comparison to the separation between their centres.
Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics 42
Answer:
Let the original charge on sphere A be q and that on B be q’. At a distance r between their centres, the magnitude of the electrostatic force on each is given by
F = \(\frac{1}{4 \pi \varepsilon_{0}} \frac{\mathrm{qq}^{\prime}}{\mathrm{r}^{2}}\)

Neglecting the sizes of spheres, A and B in comparison to r. When an identical but uncharged sphere C touches A, the charges redistribute on A and C and, by symmetry, each sphere carries a charge q/2. Similarly, after D touches B, the redistributed charge on each is q’/2. Now, if the separation between A and B is halved, the magnitude of the electrostatic force on each is
F’ = \(\frac{1}{4 \pi \varepsilon_{0}} \frac{(\mathrm{q} / 2)\left(\mathrm{q}^{\prime} / 2\right)}{(\mathrm{r} / 2)^{2}}=\frac{1}{4 \pi \varepsilon_{0}} \frac{\left(\mathrm{qq}^{\prime}\right)}{\mathrm{r}^{2}}\) = F

Thus, the electrostatic force on A, due to B, remains unaltered.

Multiple Choice Questions

Question 1.
Force between two charges separated by a certain distance in air is F. If each charge is doubled and the distance between them is also doubled, force would be
(A) F
(B) 2 F
(O’ 4 F
(D) F/4
Answer:
(A) F

Question 2.
For what order of distance is Coulomb7 s law true?
(A) For all distances.
(B) Distances greater than 10-13 m.
(C) Distances less than 10-13 m.
(D) Distance equal to 10-13 m.
Answer:
(B) Distances greater than 10-13 m.

Question 3.
The permittivity of medium is 26.55 × 10-12 C²/Nm². The dielectric constant of the medium will be
(A) 2
(B) 3
(C) 4
(D) 5
Answer:
(B) 3

Question 4.
A glass rod when rubbed with a piece of fur acquires a charge of magnitude 3.2 µC. The number of electrons transferred is
(A) 2 × 10-13 from fur to glass
(B) 5 × 1012 from glass to fur
(C) 2 × 1013 from glass to fur
(D) 5 × 1012 from fur to glass
Answer:
(A) 2 × 10-13 from fur to glass

Question 5.
Choose the correct answer.
(A) Total charge present in the universe is constant.
(B) Total positive charge present in the universe is constant.
(C) Total negative charge present in the universe is constant.
(D) Total number of charged particles present in the universe is constant.
Answer:
(A) Total charge present in the universe is constant.

Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics

Question 6.
If a charge is moved against the Coulomb force of an electric field,
(A) work is done by the electric field
(B) energy is used from some outside source
(C) the strength of the field is decreased
(D) the energy of the system is decreased
Answer:
(B) energy is used from some outside source

Question 7.
Two point charges +4 µC and +2 µC repel each other with a force of 8 N. If a charge of -4 µC is added to each of these charges, the force would be
(A) zero
(B) 8 N
(C) 4 N
(D) 12 N
Answer:
(A) zero

Question 8.
The electric field intensity at a point 2 m from an isolated point charge is 500 N/C. The electric potential at the point is
(A) 0 V
(B) 2.5 V
(C) 250 V
(D) 1000 V
Answer:
(D) 1000 V

Question 9.
The dimensional formula of electric field intensity is
(A) [M1E1T-2A-1]
(B) [M1L1T-3A-1]
(C) [M-1L2T-3A-1]
(D) [M1L2T-3A-2]
Answer:
(B) [M1L1T-3A-1]

Question 10.
A force of 2.25 N acts on a charge of 15 × 10-4C. Calculate the intensity of electric field at that point.
(A) 1500 NC-1
(B) 150 NC-1
(C) 15000NC-1
(D) 2500 NC-1
Answer:
(A) 1500 NC-1

Question 11.
A point charge q produces an electric field of magnitude 2 N C-1 at a point distant 0.25 m from it. What is the value of charge?
(A) 1.39 × 10-11 C
(B) 1.39 × 1011 C
(C) 13.9 × 10-11 C
(D) 13.9 × 1011 C
Answer:
(A) 1.39 × 10-11 C

Question 12.
The electric intensity in air at a point 20 cm from a point charge Q coulombs is 4.5 × 105 N/ C. The magnitude of Q is
(A) 20 µC
(B) 200 µC
(C) 10 µC
(D) 2 µC
Answer:
(D) 2 µC

Question 13.
The charge on the electron is 1.6 × 10-19 C. The number of electrons need to be removed from a metal sphere of 0.05 m radius so as to acquire a charge of 4 × 10-15 C is
(A) 1.25 × 104
(B) 1.25 × 10³
(C) 2.5 × 10³
(D) 2.5 × 104
Answer:
(D) 2.5 × 104

Question 14.
Electric lines of force about a positive point charge and negative point charge are respectively .
(A) circular, clockwise
(B) radially outward, radially inward
(C) radially inward, radially outward
(D) circular, anticlockwise
Answer:
(B) radially outward, radially inward

Question 15.
Which of the following is NOT the property of equipotential surfaces?
(A) They do not intersect each other.
(B) They are concentric spheres for uniform electric field.
(C) Potential at all points on the surface has constant value.
(D) Separation of equipotential surfaces increases with decrease in electric field.
Answer:
(B) They are concentric spheres for uniform electric field.

Question 16.
In a uniform electric field, a charge of 3 C experiences a force of 3000 N. The potential difference between two points 1 cm apart along the electric lines of force will be
(A) 10 V
(B) 3 V
(C) 0.1 V
(D) 20 V
Answer:
(A) 10 V

Question 17.
Gauss’ law helps in
(A) determination of electric field due to symmetric charge distribution.
(B) determination of electric potential due to symmetric charge distribution.
(C) determination of electric flux.
(D) situations where Coulomb’s law fails.
Answer:
(A) determination of electric field due to symmetric charge distribution.

Question 18.
The electric flux over a sphere of radius 1.0 m is ø. If the radius of the sphere is doubled without changing the charge, the flux will be
(A) 4ø
(B) 2ø
(C) ø
(D) 8ø
Answer:
(C) ø

Question 19.
Gauss’ theorem states that total normal electric induction over a closed surface in an electric field is equal to
(A) \( \frac{1}{\varepsilon} \sum \mathrm{q}_{\mathrm{n}}\)
(B) εΣ qn
(C) Σ qn
(D) q1 × q2 × q3 × ……… qn
Answer:
(C) Σ qn

Maharashtra Board Class 11 Physics Important Questions Chapter 10 Electrostatics

Question 20.
Number of lines of induction starting from a conductor holding + q charge surrounded by a medium of permittivity ε is
(A) q and they leave the surface in normal direction.
(B) q and they leave the surface in any direction.
(C) q/ε and they leave the surface normally at every point.
(D) q/ε and they leave the surface in any direction.
Answer:
(C) q/ε and they leave the surface normally at every point.

Question 21.
An electric dipole of moment p is placed in the position of stable equilibrium in a uniform electric field of intensity E. The torque required to rotate, when the dipole makes an angle 0 with the initial position is
(A) pE cosθ
(B) pE sinθ
(C) pE tanθ
(D) pE cotθ
Answer:
(B) pE sinθ

Question 22.
Four coulomb charge is uniformly distributed on 2 km long wire. Its linear charge density is
(A) 2 C/m
(B) 4 C/m
(C) 4 × 10³ C/m
(D) 2 × 10-3 C/m
Answer:
(D) 2 × 10-3 C/m

Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1

Balbharti 12th Maharashtra State Board Maths Solutions Book Pdf Chapter 7 Probability Distributions Ex 7.1 Questions and Answers.

Maharashtra State Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1

Question 1.
Let X represent the difference between a number of heads and the number of tails when a coin is tossed 6 times. What are the possible values of X?
Solution:
When a coin is tossed 6 times, the number of heads can be 0, 1, 2, 3, 4, 5, 6.
The corresponding number of tails will be 6, 5, 4, 3, 2, 1, 0.
∴ X can take values 0 – 6, 1 – 5, 2 – 4, 3 – 3, 4 – 2, 5 – 1, 6 – 0
i.e. -6, -4, -2, 0, 2, 4, 6.
∴ X = {-6, -4, -2, 0, 2, 4, 6}.

Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1

Question 2.
An urn contains 5 red and 2 black balls. Two balls are drawn at random. X denotes the number of black balls drawn. What are the possible values of X?
Solution:
The urn contains 5 red and 2 black balls.
If two balls are drawn from the urn, it contains either 0 or 1 or 2 black balls.
X can take values 0, 1, 2.
∴ X = {0, 1, 2}.

Question 3.
State which of the following are not the probability mass function of a random variable. Give reasons for your answer.
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q3
Solution:
P.m.f. of random variable should satisfy the following conditions:
(a) 0 ≤ pi ≤ 1
(b) Σpi = 1.

(i)
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q3.1
(a) Here 0 ≤ pi ≤ 1
(b) Σpi = 0.4 + 0.4 + 0.2 = 1
Hence, P(X) can be regarded as p.m.f. of the random variable X.

(ii)
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q3.2
P(X = 3) = -0.1, i.e. Pi < 0 which does not satisfy 0 ≤ Pi ≤ 1
Hence, P(X) cannot be regarded as p.m.f. of the random variable X.

(iii)
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q3.3
(a) Here 0 ≤ pi ≤ 1
(b) ∑pi = 0.1 + 0.6 + 0.3 = 1
Hence, P(X) can be regarded as p.m.f. of the random variable X.

(iv)
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q3.4
Here ∑pi = 0.3 + 0.2 + 0.4 + 0 + 0.05 = 0.95 ≠ 1
Hence, P(Z) cannot be regarded as p.m.f. of the random variable Z.

Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1

(v)
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q3.5
Here ∑pi = 0.6 + 0.1 + 0.2 = 0.9 ≠ 1
Hence, P(Y) cannot be regarded as p.m.f. of the random variable Y.

(vi)
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q3.6
(a) Here 0 ≤ pi ≤ 1
(b) ∑pi = 0.3 + 0.4 + 0.3 = 1
Hence, P(X) can be regarded as p.m.f. of the random variable X.

Question 4.
Find the probability distribution of
(i) number of heads in two tosses of a coin.
(ii) number of tails in the simultaneous tosses of three coins.
(iii) number of heads in four tosses of a coin.
Solution:
(i) For two tosses of a coin the sample space is {HH, HT, TH, TT}
Let X denote the number of heads in two tosses of a coin.
Then X can take values 0, 1, 2.
∴ P[X = 0] = P(0) = \(\frac{1}{4}\)
P[X = 1] = P(1) = \(\frac{2}{4}\) = \(\frac{1}{2}\)
P[X = 2] = P(2) = \(\frac{1}{4}\)
∴ the required probability distribution is
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q4

(ii) When three coins are tossed simultaneously, then the sample space is
{HHH, HHT, HTH, THH, HTT, THT, TTH, TTT}
Let X denotes the number of tails.
Then X can take the value 0, 1, 2, 3.
∴ P[X = 0] = P(0) = \(\frac{1}{8}\)
P[X = 1] = P(1) = \(\frac{3}{8}\)
P[X = 2] = P(2) = \(\frac{3}{8}\)
P[X = 3] = P(3) = \(\frac{1}{8}\)
∴ the required probability distribution is
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q4.1

(iii) When a fair coin is tossed 4 times, then the sample space is
S = {HHHH, HHHT, HHTH, HTHH, THHH, HHTT, HTHT, HTTH, THHT, THTH, TTHH, HTTT, THTT, TTHT, TTTH, TTTT}
∴ n(S) = 16
Let X denotes the number of heads.
Then X can take the value 0, 1, 2, 3, 4
When X = 0, then X = {TTTT}
∴ n(X) = 1
∴ P(X = 0) = \(\frac{n(X)}{n(S)}=\frac{1}{16}\)
When X = 1, then
X = {HTTT, THTT, TTHT, TTTH}
∴ n(X) = 4
∴ P(X = 1) = \(\frac{n(X)}{n(S)}=\frac{4}{16}=\frac{1}{4}\)
When X = 2, then
X = {HHTT, HTHT, HTTH, THHT, THTH, TTHH}
∴ n(X) = 6
∴ P(X = 2) = \(\frac{n(X)}{n(S)}=\frac{6}{16}=\frac{3}{8}\)
When X = 3, then
X = {HHHT, HHTH, HTHH, THHH}
∴ n(X) = 4
∴ P(X = 3) = \(\frac{n(X)}{n(S)}=\frac{4}{16}=\frac{1}{4}\)
When X = 4, then X = {HHHH}
∴ n(X) = 1
∴ P(X = 4) = \(\frac{n(X)}{n(S)}=\frac{1}{16}\)
∴ the probability distribution of X is as follows:
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q4.2

Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1

Question 5.
Find the probability distribution of a number of successes in two tosses of a die, where success is defined as a number greater than 4 appearing on at least one die.
Solution:
When a die is tossed twice, the sample space s has 6 × 6 = 36 sample points.
∴ n(S) = 36
The trial will be a success if the number on at least one die is 5 or 6.
Let X denote the number of dice on which 5 or 6 appears.
Then X can take values 0, 1, 2.
When X = 0 i.e., 5 or 6 do not appear on any of the dice, then
X = {(1, 1), (1, 2), (1, 3), (1, 4), (2, 1), (2, 2), (2, 3), (2, 4), (3, 1), (3, 2), (3, 3), (3, 4), (4, 1), (4, 2), (4, 3), (4, 4)}
∴ n(X) = 16.
∴ P(X = 0) = \(\frac{n(X)}{n(S)}=\frac{16}{36}=\frac{4}{9}\)
When X = 1, i.e. 5 or 6 appear on exactly one of the dice, then
X = {(1, 5), (1, 6), (2, 5), (2, 6), (3, 5), (3, 6), (4, 5), (4, 6), (5, 1), (5, 2), (5, 3), (5, 4), (6, 1), (6, 2), (6, 3), (6, 4)}
∴ n(X) = 16
∴ P(X = 1) = \(\frac{n(X)}{n(S)}=\frac{16}{36}=\frac{4}{9}\)
When X = 2, i.e. 5 or 6 appear on both of the dice, then
X = {(5, 5), (5, 6), (6, 5), (6, 6)}
∴ n(X) = 4
∴ P(X = 2) = \(\frac{n(X)}{n(S)}=\frac{4}{36}=\frac{1}{9}\)
∴ the required probability distribution is
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q5

Question 6.
From a lot of 30 bulbs which include 6 defectives, a sample of 4 bulbs is drawn at random with replacement. Find the probability distribution of the number of defective bulbs.
Solution:
Here, the number of defective bulbs is the random variable.
Let the number of defective bulbs be denoted by X.
∴ X can take the value 0, 1, 2, 3, 4.
Since the draws are done with replacement, therefore the four draws are independent experiments.
Total number of bulbs is 30 which include 6 defectives.
∴ P(X = 0) = P(0) = P(all 4 non-defective bulbs)
= \(\frac{24}{30} \times \frac{24}{30} \times \frac{24}{30} \times \frac{24}{30}\)
= \(\frac{256}{625}\)
P(X = 1) = P (1) = P (1 defective and 3 non-defective bulbs)
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q6
P(X = 2) = P(2) = P(2 defective and 2 non-defective)
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q6.1
P(X = 3) = P(3) = P(3 defectives and 1 non-defective)
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q6.2
P(X = 4) = P(4) = P(all 4 defectives)
= \(\frac{6}{30} \times \frac{6}{30} \times \frac{6}{30} \times \frac{6}{30}\)
= \(\frac{1}{625}\)
∴ the required probability distribution is
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q6.3

Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1

Question 7.
A coin is biased so that the head is 3 times as likely to occur as the tail. If the coin is tossed twice. Find the probability distribution of a number of tails.
Solution:
Given a biased coin such that heads is 3 times as likely as tails.
∴ P(H) = \(\frac{3}{4}\) and P(T) = \(\frac{1}{4}\)
The coin is tossed twice.
Let X can be the random variable for the number of tails.
Then X can take the value 0, 1, 2.
∴ P(X = 0) = P(HH) = \(\frac{3}{4} \times \frac{3}{4}=\frac{9}{16}\)
P(X = 1) = P(HT, TH) = \(\frac{3}{4} \times \frac{1}{4}+\frac{1}{4} \times \frac{3}{4}=\frac{6}{16}=\frac{3}{8}\)
P(X = 2) = P(TT) = \(\frac{1}{4} \times \frac{1}{4}=\frac{1}{16}\)
∴ the required probability distribution is
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q7

Question 8.
A random variable X has the following probability distribution:
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q8
Determine:
(i) k
(ii) P(X < 3) (iii) P(X > 4)
Solution:
(i) Since P (x) is a probability distribution of x,
\(\sum_{x=0}^{7} P(x)=1\)
⇒ P(0) + P(1) + P(2) + P(3) + P(4) + P(5) + P(6) + P(7) = 1
⇒ 0 + k + 2k + 2k + 3k + k2 + 2k2 + 7k2 + k = 1
⇒ 10k2 + 9k – 1 = 0
⇒ 10k2 + 10k – k – 1 = 0
⇒ 10k(k + 1) – 1(k + 1) = 0
⇒ (k + 1)(10k – 1) = 0
⇒ 10k – 1 = 0 ……..[∵ k ≠ -1]
⇒ k = \(\frac{1}{10}\)

(ii) P(X< 3) = P(0) + P(1) + P(2)
= 0 + k + 2k
= 3k
= 3(\(\frac{1}{10}\))
= \(\frac{3}{10}\)

(iii) P(0 < X < 3) = P (1) + P (2)
= k + 2k
= 3k
= 3(\(\frac{1}{10}\))
= \(\frac{3}{10}\)

Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1

Question 9.
Find expected value and variance of X for the following p.m.f.:
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q9
Solution:
We construct the following table to calculate E(X) and V(X):
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q9.1
From the table,
Σxipi = -0.05 and \(\Sigma x_{i}^{2} \cdot p_{i}\) = 2.25
∴ E(X) = Σxipi = -0.05
and V(X) = \(\Sigma x_{i}^{2}+p_{i}-\left(\sum x_{i}+p_{i}\right)^{2}\)
= 2.25 – (-0.05)2
= 2.25 – 0.0025
= 2.2475
Hence, E(X) = -0.05 and V(X) = 2.2475.

Question 10.
Find expected value and variance of X, where X is the number obtained on the uppermost face when a fair die is thrown.
Solution:
If a die is tossed, then the sample space for the random variable X is
S = {1, 2, 3, 4, 5, 6}
∴ P(X) = \(\frac{1}{6}\); X = 1, 2, 3, 4, 5, 6.
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q10
Hence, E(X) = 3.5 and V(X) = 2.9167.

Question 11.
Find the mean number of heads in three tosses of a fair coin.
Solution:
When three coins are tossed the sample space is {HHH, HHT, THH, HTH, HTT, THT, TTH, TTT}
∴ n(S) = 8
Let X denote the number of heads when three coins are tossed.
Then X can take values 0, 1, 2, 3
P(X = 0) = P(0) = \(\frac{1}{8}\)
P(X = 1) = P(1) = \(\frac{3}{8}\)
P(X = 2) = P(2) = \(\frac{3}{8}\)
P(X = 3) = P(3) = \(\frac{1}{8}\)
∴ mean = E(X) = ΣxiP(xi)
= \(0 \times \frac{1}{8}+1 \times \frac{3}{8}+2 \times \frac{3}{8}+3 \times \frac{1}{8}\)
= \(0+\frac{3}{8}+\frac{6}{8}+\frac{3}{8}\)
= \(\frac{12}{8}\)
= 1.5

Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1

Question 12.
Two dice are thrown simultaneously. If X denotes the number of sixes, find the expectation of X.
Solution:
When two dice are thrown, the sample space S has 6 × 6 = 36 sample points.
∴ n(S) = 36
Let X denote the number of sixes when two dice are thrown.
Then X can take values 0, 1, 2
When X = 0, then
X = {(1, 1), (1, 2), (1, 3), (1, 4), (1, 5), (2, 1), (2, 2), (2, 3), (2, 4), (2, 5), (3, 1), (3, 2), (3, 3), (3, 4), (3, 5), (4, 1), (4, 2), (4, 3), (4, 4), (4, 5), (5, 1), (5, 2), (5, 3), (5, 4), (5, 5)}
∴ n(X) = 25
∴ P(X = 0) = \(\frac{n(X)}{n(S)}=\frac{25}{36}\)
When X = 1, then
X = {(1, 6), (2, 6), (3, 6), (4, 6), (5, 6), (6, 1), (6, 2), (6, 3), (6, 4), (6, 5)}
∴ n(X) = 10
∴ P(X = 1) = \(\frac{n(X)}{n(S)}=\frac{10}{36}\)
When X = 2, then X = {(6, 6)}
∴ n(X) = 1
∴ P(X = 2) = \(\frac{n(X)}{n(S)}=\frac{1}{36}\)
∴ E(X) = ΣxiP(xi)
= \(0 \times \frac{25}{36}+1 \times \frac{10}{36}+2 \times \frac{1}{36}\)
= \(0+\frac{10}{36}+\frac{2}{36}\)
= \(\frac{1}{3}\)

Question 13.
Two numbers are selected at random (without replacement) from the first six positive integers. Let X denote the larger of the two numbers. Find E(X).
Solution:
Two numbers are chosen from the first 6 positive integers.
∴ n(S) = \({ }^{6} C_{2}=\frac{6 \times 5}{1 \times 2}\) = 15
Let X denote the larger of the two numbers.
Then X can take values 2, 3, 4, 5, 6.
When X = 2, the other positive number which is less than 2 is 1.
∴ n(X) = 1
∴ P(X = 2) = P(2) = \(\frac{n(X)}{n(S)}=\frac{1}{15}\)
When X = 3, the other positive number less than 3 can be 1 or 2 and hence can be chosen in 2 ways.
∴ n(X) = 2
P(X = 3) = P(3) = \(\frac{n(X)}{n(S)}=\frac{2}{15}\)
Similarly, P(X = 4) = P(4) = \(\frac{3}{15}\)
P(X = 5) = P(5) = \(\frac{4}{15}\)
P(X = 6) = P(6) = \(\frac{5}{15}\)
∴ E(X) = ΣxiP(xi)
= \(2 \times \frac{1}{15}+3 \times \frac{2}{15}+4 \times \frac{3}{15}+5 \times \frac{4}{15}+6 \times \frac{5}{15}\)
= \(\frac{2+6+12+20+30}{15}\)
= \(\frac{70}{15}\)
= \(\frac{14}{3}\)

Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1

Question 14.
Let X denote the sum of numbers obtained when two fair dice are rolled. Find the standard deviation of X.
Solution:
If two fair dice are rolled then the sample space S of this experiment is
S = {(1, 1), (1, 2), (1, 3), (1, 4), (1, 5), (1, 6), (2, 1), (2, 2), (2, 3), (2, 4), (2, 5), (2, 6), (3, 1), (3, 2), (3, 3), (3, 4), (3, 5), (3, 6), (4, 1), (4, 2), (4, 3), (4, 4), (4, 5), (4, 6), (5, 1), (5, 2), (5, 3), (5, 4), (5, 5), (5, 6), (6, 1), (6, 2), (6, 3), (6, 4), (6, 5), (6, 6)}
∴ n(S) = 36
Let X denote the sum of the numbers on uppermost faces.
Then X can take the values 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q14
∴ the probability distribution of X is given by
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q14.1
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q14.2
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q14.3

Question 15.
A class has 15 students whose ages are 14, 17, 15, 14, 21, 17, 19, 20, 16, 18, 20, 17, 16, 19 and 20 years. One student is selected in such a manner that each has the same chance of being chosen and the age X of the student is recorded. What is the probability distribution of the random variable X? Find mean, variance, and standard deviation of X.
Solution:
Let X denote the age of the chosen student. Then X can take values 14, 15, 16, 17, 18, 19, 20, 21.
We make a frequency table to find the number of students with age X:
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q15
The chances of any student selected are equally likely.
If there are m students with age X, then P(X) = \(\frac{m}{15}\)
Using this, the following is the probability distribution of X:
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q15.1
Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1 Q15.2
Variance = V(X) = \(\Sigma x_{i}^{2}\) . P(xi) – [E(X)]2
= 312.2 – (17.53)2
= 312.2 – 307.3
= 4.9
Standard deviation = √V(X) = √4.9 = 2.21
Hence, mean = 17.53, variance = 4.9 and standard deviation = 2.21.

Maharashtra Board 12th Maths Solutions Chapter 7 Probability Distributions Ex 7.1

Question 16.
In a meeting, 70% of the member’s favour and 30% oppose a certain proposal. A member is selected at random and we take X = 0 if he opposed and X = 1 if he is in favour. Find E(X) and Var(X).
Solution:
X takes values 0 and 1.
It is given that
P(X = 0) = P(0) = 30% = \(\frac{30}{100}\) = 0.3
P(X = 1) = P(1) = 70% = \(\frac{70}{100}\) = 0.7
∴ E(X) = Σxi . P(xi) = 0 × 0.3 + 1 × 0.7 = 0.7
Also, \(\Sigma x_{i}^{2} \cdot P\left(x_{i}\right)\) = 0 × 0.3 + 1 × 0.7 = 0.7
∴ Variance = V(X) = \(\Sigma x_{i}^{2} \cdot P\left(x_{i}\right)-[E(X)]^{2}\)
= 0.7 – (0.7)2
= 0.7 – 0.49
= 0.21
Hence, E(X) = 0.7 and Var(X) = 0.21.

Maharashtra Board Class 11 Physics Solutions Chapter 14 Semiconductors

Balbharti Maharashtra State Board 11th Physics Textbook Solutions Chapter 14 Semiconductors Textbook Exercise Questions and Answers.

Maharashtra State Board 11th Physics Solutions Chapter 14 Semiconductors

1. Choose the correct option.

Question 1.
Electric conduction through a semiconductor is due to:
(A) Electrons
(B) holes
(C) none of these
(D) both electrons and holes
Answer:
(D) both electrons and holes

Maharashtra Board Class 11 Physics Solutions Chapter 14 Semiconductors

Question 2.
The energy levels of holes are:
(A) in the valence band
(B) in the conduction band
(C) in the band gap but close to valence band
(D) in the band gap but close to conduction band
Answer:
(C) in the band gap but close to valence band

Question 3.
Current through a reverse biased p-n junction, increases abruptly at:
(A) Breakdown voltage
(B) 0.0 V
(C) 0.3V
(D) 0.7V
Answer:
(A) Breakdown voltage

Question 4.
A reverse biased diode, is equivalent to:
(A) an off switch
(B) an on switch
(C) a low resistance
(D) none of the above
Answer:
(A) an off switch

Question 5.
The potential barrier in p-n diode is due to:
(A) depletion of positive charges near the junction
(B) accumulation of positive charges near the junction
(C) depletion of negative charges near the junction,
(D) accumulation of positive and negative charges near the junction
Answer:
(D) accumulation of positive and negative charges near the junction

2. Answer the following questions.

Question 1.
What is the importance of energy gap in a semiconductor?
Answer:

  1. The gap between the bottom of the conduction band and the top of the valence band is called the energy gap or the band gap.
  2. This band gap is present only in semiconductors and insulators.
  3. Magnitude of the band gap plays a very important role in the electronic properties of a solid.
  4. Band gap in semiconductors is of the order of 1 eV.
  5. If electrons in valence band of a semiconductor are provided with energy more than band gap energy (in the form of thermal energy or electrical energy), then the electrons get excited and occupy energy levels in conduction band. These electrons can easily take part in conduction.

Question 2.
Which element would you use as an impurity to make germanium an n-type semiconductor?
Answer:
Germanium can be made an n-type semiconductor by doping it with pentavalent impurity, like phosphorus (P), arsenic (As) or antimony (Sb).

Maharashtra Board Class 11 Physics Solutions Chapter 14 Semiconductors

Question 3.
What causes a larger current through a p-n junction diode when forward biased?
Answer:
In case of forward bias the width of the depletion region decreases and the p-n junction offers a low resistance path allowing a high current to flow across the junction.

Question 4.
On which factors does the electrical conductivity of a pure semiconductor depend at a given temperature?
Answer:
For pure semiconductor, the number density of free electrons and number density of holes is equal. Thus, at a given temperature, the conductivity of pure semiconductor depends on the number density of charge carriers in the semiconductor.

Question 5.
Why is the conductivity of a n-type semiconductor greater than that of p-type semiconductor even when both of these have same level of doping?
Answer:

  1. In a p-type semiconductor, holes are majority charge carriers.
  2. When a p-type semiconductor is connected to terminals of a battery, holes, which are not actual charges, behave like a positive charge and get attracted towards the negative terminal of the battery.
  3. During transportation of hole, there is an indirect movement of electrons.
  4. The drift speed of these electrons is less than that in the n-type semiconductors. Mobility of the holes is also less than that of the electrons.
  5. As, electrical conductivity depends on the mobility of charge carriers, the conductivity of a n-type semiconductor is greater than that of p-type semiconductor even when both of these have same level of doping.

3. Answer in detail.

Question 1.
Explain how solids are classified on the basis of band theory of solids.
Answer:
i. The solids can be classified into conductors, insulators and semiconductors depending on the distribution of electron energies in each atom.

ii. As an outcome of the small distances between atoms, the resulting interaction amongst electrons and the Pauli’s exclusion principle, energy bands are formed in the solids.

iii. In metals, conduction band and valence band overlap. However, in a semiconductor or an insulator, there is gap between the bottom of the conduction band and the top of the valence band. This is called the energy gap or the band gap.
Maharashtra Board Class 11 Physics Solutions Chapter 14 Semiconductors 1

iv. For metals, the valence band and the conduction band overlap and there is no band gap as shown in figure (b). Therefore, electrons can easily gain electrical energy when an external electric field is applied and are easily available for conduction.
Maharashtra Board Class 11 Physics Solutions Chapter 14 Semiconductors 2

v. In case of semiconductors, the band gap is fairly small, of the order of 1 eV or less as shown in figure (c). Hence, with application of external electric field, electrons get excited and occupy energy levels in conduction band. These can take part in conduction easily.
Maharashtra Board Class 11 Physics Solutions Chapter 14 Semiconductors 3

vi. Insulators, on the contrary, have a wide gap between valence band and conduction band of the order of 5 eV (for diamond) as shown in figure (d). Therefore, electrons find it very difficult to gain sufficient energy to occupy energy levels in conduction band.
Maharashtra Board Class 11 Physics Solutions Chapter 14 Semiconductors 4

vii. Thus, an energy band gap plays an important role in classifying solids into conductors, insulators and semiconductors based on band theory of solids.

Maharashtra Board Class 11 Physics Solutions Chapter 14 Semiconductors

Question 2.
Distinguish between intrinsic semiconductors and extrinsic semiconductors
Answer:

Intrinsic semiconductorsExtrinsic semiconductors
1. A pure semiconductor is known as intrinsic semiconductors.The semiconductor, resulting
2. Their conductivity is lowTheir conductivity is high even at room temperature.
3. Its electrical conductivity is a function of temperature alone.Its electrical conductivity depends upon the temperature as well as on the quantity of impurity atoms doped in the structure.
4. The number density of holes (nh) is same as the number density of free electron (ne) (nh = ne).The number density of free electrons and number density of holes are unequal.

Question 3.
Explain the importance of the depletion region in a p-n junction diode.
Answer:
i. The region across the p-n junction where there are no charges is called the depletion layer or the depletion region.

ii. During diffusion of charge carriers across the junction, electrons migrate from the n-side to the p-side of the junction. At the same time, holes are transported from p-side to n-side of the junction.

iii. As a result, in the p-type region near the junction there are negatively charged acceptor ions, and in the n-type region near the junction there are positively charged donor ions.

iv. The potential barrier thus developed, prevents continuous flow of charges across the junction. A state of electrostatic equilibrium is thus reached across the junction.

v. Free charge carriers cannot be present in a region where there is a potential barrier. This creates the depletion region.

vi. In absence of depletion region, all the majority charge carriers from n-region (i.e., electron) will get transferred to the p-region and will get combined with the holes present in that region. This will result in the decreased efficiency of p-n junction.

vii. Hence, formation of depletion layer across the junction is important to limit the number of majority carriers crossing the junction.

Question 4.
Explain the I-V characteristic of a forward biased junction diode.
Answer:
Maharashtra Board Class 11 Physics Solutions Chapter 14 Semiconductors 5

  1. Figure given below shows the I-V characteristic of a forward biased diode.
  2. When connected in forward bias mode, initially, the current through diode is very low and then there is a sudden rise in the current.
  3. The point at which current rises sharply is shown as the ‘knee’ point on the I-V characteristic curve.
  4. The corresponding voltage is called the knee voltage. It is about 0.7 V for silicon and 0.3 V for germanium.
  5. A diode effectively becomes a short circuit above this knee point and can conduct a very large current.
  6. To limit current flowing through the diode, resistors are used in series with the diode.
  7. If the current through a diode exceeds the specified value, the diode can heat up due to the Joule’s heating and this may result in its physical damage.

Maharashtra Board Class 11 Physics Solutions Chapter 14 Semiconductors

Question 5.
Discuss the effect of external voltage on the width of depletion region of a p-n junction.
Answer:

  1. A p-n junction can be connected to an external voltage supply in two possible ways.
  2. A p-n junction is said to be connected in a forward bias when the p-region connected to the positive terminal and the n-region is connected to the negative terminal of an external voltage source.
  3. In forward bias connection, the external voltage effectively opposes the built-in potential of the junction. The width of depletion region is thus reduced.
  4. The second possibility of connecting p-n junction is in reverse biased electric circuit.
  5. In reverse bias connection, the p-region is connected to the negative terminal and the n-region is connected to the positive terminal of the external voltage source. This external voltage effectively adds to the built-in potential of the junction. The width of potential barrier is thus increased

11th Physics Digest Chapter 14 Semiconductors Intext Questions and Answers

Internet my friend (Textbookpage no. 256)

i. https://www.electronics-tutorials.ws/diode
ii. https://www.hitachi-hightech.com
iii. https://nptel.ac.in/courses
iv. https://physics.info/semiconductors
v. http://hyperphysics.phy- astr.gsu.edu/hbase/Solids/semcn.html

[Students are expected to visit above mentioned links and collect more information regarding semiconductors.]

Maharashtra Board Class 11 Physics Solutions Chapter 13 Electromagnetic Waves and Communication System

Balbharti Maharashtra State Board 11th Physics Textbook Solutions Chapter 13 Electromagnetic Waves and Communication System Textbook Exercise Questions and Answers.

Maharashtra State Board 11th Physics Solutions Chapter 13 Electromagnetic Waves and Communication System

1. Choose the correct option.

Question 1.
The EM wave emitted by the Sun and responsible for heating the Earth’s atmosphere due to the greenhouse effect is
(A) Infra-red radiation
(B) X-ray
(C) Microwave
(D) Visible light
Answer:
(A) Infra-red radiation

Question 2.
Earth’s atmosphere is richest in
(A) UV
(B) IR
(C) X-ray
(D) Microwaves
Answer:
(B) IR

Maharashtra Board Class 11 Physics Solutions Chapter 13 Electromagnetic Waves and Communication System

Question 3.
How does the frequency of a beam of ultraviolet light change when it travels from air into glass?
(A) depends on the values of p and e
(B) increases
(C) decreases
(D) remains same
Answer:
(D) remains same

Question 4.
The direction of EM wave is given by
(A) \(\bar{E}\) × \(\bar{B}\)
(B) \(\bar{E}\).\(\bar{B}\)
(C) along \(\bar{E}\)
(D) along \(\bar{B}\)
Answer:
(A) \(\bar{E}\) × \(\bar{B}\)

Question 5.
The maximum distance upto which TV transmission from a TV tower of height h can be received is proportional to
(A) h½
(B) h
(C) h3/2
(D) h²
Answer:
(A) h½

Question 6.
The waves used by artificial satellites for communication purposes are
(A) Microwave
(B) AM radio waves
(C) FM radio waves
(D) X-rays
Answer:
(A) Microwave

Question 7.
If a TV telecast is to cover a radius of 640 km, what should be the height of transmitting antenna?
(A) 32000 m
(B) 53000 m
(C) 42000 m
(D) 55000 m
Answer:
(A) 32000 m

2. Answer briefly.

Question 1.
State two characteristics of an EM wave.
Answer:
i. The electric and magnetic fields, \(\vec{E}\) and \(\vec{B}\) are always perpendicular to each other and also to the direction of propagation of the EM wave. Thus, the EM waves are transverse waves.

ii. The cross product (\(\vec{E}\) × \(\vec{B}\)) gives the direction in which the EM wave travels. (\(\vec{E}\) × \(\vec{B}\)) also gives the energy carried by EM wave.

Question 2.
Why are microwaves used in radar?
Answer:
Microwaves are used in radar systems for identifying the location of distant objects like ships, aeroplanes etc.

Maharashtra Board Class 11 Physics Solutions Chapter 13 Electromagnetic Waves and Communication System

Question 3.
What are EM waves?
Answer:
Waves that are caused by the acceleration of charged particles and consist of electric and magnetic fields vibrating sinusoidally at right angles to each other and to the direction of propagation are called EM waves or EM radiation.

Question 4.
How are EM waves produced?
Answer:

  1. According to quantum theory, an electron, while orbiting around the nucleus in a stable orbit does not emit EM radiation even though it undergoes acceleration.
  2. It will emit an EM radiation only when it falls from an orbit of higher energy to one of lower energy.
  3. EM waves (such as X-rays) are produced when fast moving electrons hit a target of high atomic number (such as molybdenum, copper, etc.).
  4. An electric charge at rest has an electric field in the region around it but has no magnetic field.
  5. When the charge moves, it produces both electric and magnetic fields.
  6. If the charge moves with a constant velocity, the magnetic field will not change with time and hence, it cannot produce an EM wave.
  7. But if the charge is accelerated, both the magnetic and electric fields change with space and time and an EM wave is produced.
  8. Thus, an oscillating charge emits an EM wave which has the same frequency as that of the oscillation of the charge.

Question 5.
Can we produce a pure electric or magnetic wave in space? Why?
Answer:
No.
In vacuum, an electric field cannot directly induce another electric field so a “pure” electric field wave cannot exist and same can be said for a “pure” magnetic wave.

Question 6.
Does an ordinary electric lamp emit EM waves?
Answer:
Yes, ordinary electric lamp emits EM waves.

Question 7.
Why light waves travel in vacuum whereas sound wave cannot?
Answer:
Light waves are electromagnetic waves which can travel in vacuum whereas sound waves travel due to the vibration of particles of medium. Without any particles present (like in a vacuum) no vibrations can be produced. Hence, the sound wave cannot travel through the vacuum.

Question 8.
What are ultraviolet rays? Give two uses.
Answer:
Production:

  1. Ultraviolet rays can be produced by the mercury vapour lamp, electric spark and carbon arc lamp.
  2. They can also be obtained by striking electrical discharge in hydrogen and xenon gas tubes.
  3. The Sun is the most important natural source of ultraviolet rays, most of which are absorbed by the ozone layer in the Earth’s atmosphere.

Uses:

  1. Ultraviolet rays destroy germs and bacteria and hence they are used for sterilizing surgical instruments and for purification of water.
  2. Used in burglar alarms and security systems.
  3. Used to distinguish real and fake gems.

Maharashtra Board Class 11 Physics Solutions Chapter 13 Electromagnetic Waves and Communication System

Question 9.
What are radio waves? Give its two uses.
Answer:

  1. Radio waves are produced by accelerated motion of charges in a conducting wire. The frequency of waves produced by the circuit depends upon the magnitudes of the inductance and the capacitance.
  2. Thus, by choosing suitable values of the inductance and the capacitance, radio waves of desired frequency can be produced.

Uses:

  1. Radio waves are used for wireless communication purpose.
  2. They are used for radio broadcasting and transmission of TV signals.
  3. Cellular phones use radio waves to transmit voice communication in the ultra high frequency (UHF) band.

Question 10.
Name the most harmful radiation entering the Earth’s atmosphere from the outer space.
Answer:
Ultraviolet radiation.

Question 11.
Give reasons for the following:
i. Long distance radio broadcast uses short wave bands.
ii. Satellites are used for long distance TV transmission.
Answer:
i. Long distance radio broadcast uses short wave bands because electromagnetic waves only in the frequency range of short wave bands only are reflected by the ionosphere.

ii. a. It is necessary to use satellites for long distance TV transmissions because television signals are of high frequencies and high energies. Thus, these signals are not reflected by the ionosphere.
b. Hence, satellites are helpful in long distance TV transmission.

Question 12.
Name the three basic units of any communication system.
Answer:
Three basic (essential) elements of every communication system are transmitter, communication channel and receiver.

Question 13.
What is a carrier wave?
Answer:
The high frequency waves on which the signals to be transmitted are superimposed are called carrier waves.

Question 14.
Why high frequency carrier waves are used for transmission of audio signals?
Answer:
An audio signal has low frequency (<20 kHz) and low frequency signals cannot be transmitted over large distances. Because of this, a high frequency carrier waves are used for transmission.

Question 15.
What is modulation?
Answer:
The signals in communication system (e.g. music, speech etc.) are low frequency signals and cannot be transmitted over large distances. In order to transmit the signal to large distances, it is superimposed on a high frequency wave (called carrier wave). This process is called modulation.

Question 16.
What is meant by amplitude modulation?
Answer:
When the amplitude of carrier wave is varied in accordance with the modulating signal, the process is called amplitude modulation.

Question 17.
What is meant by noise?
Answer:

  1. A random unwanted signal is called noise.
  2. The source generating the noise may be located inside or outside the system.
  3. Efforts should be made to minimize the noise level in a communication system.

Question 18.
What is meant by bandwidth?
Answer:
The bandwidth of an electronic circuit is the range of frequencies over which it operates efficiently.

Maharashtra Board Class 11 Physics Solutions Chapter 13 Electromagnetic Waves and Communication System

Question 19.
What is demodulation?
Answer:
The process of regaining signal from a modulated wave is called demodulation. This is the reverse process of modulation.

Question 20.
What type of modulation is required for television broadcast?
Answer:
Amplitude modulation is required for television broadcast.

Question 21.
How does the effective power radiated by an antenna vary with wavelength?
Answer:

  1. To transmit a signal, an antenna or an aerial is needed.
  2. Power radiated from a linear antenna of length l is, P ∝ (\(\frac {l}{λ}\))²
    where, λ is the wavelength of the signal.

Question 22.
Why should broadcasting programs use different frequencies?
Answer:
If broadcasting programs run on same frequency, then the information carried by these waves will get mixed up with each other. Hence, different broadcasting programs should run on different frequencies.

Question 23.
Explain the necessity of a carrier wave in communication.
Answer:

  1. Without a carrier wave, the input signals could be carried by very low frequency electromagnetic waves but it will need quite a bit of amplification in order to transmit those very low frequencies.
  2. The input signals themselves do not have much power and need a fairly large antenna in order to transmit the information.
  3. Hence, it is necessary to impose the input signal on carrier wave as it requires less power in order to transmit the information.

Question 24.
Why does amplitude modulation give noisy reception?
Answer:
i. In amplitude modulation, carrier is varied in accordance with the message signal.

ii. The higher the amplitude, the greater is magnitude of the signal. So even if due to any reason, the magnitude of the signal changes, it will lead to variation in the amplitude of the signal. So its easy for noise to disturb the amplitude modulated signal.

Question 25.
Explain why is modulation needed.
Answer:
Modulation helps in avoiding mixing up of signals from different transmitters as different carrier wave frequencies can be allotted to different transmitters. Without the use of these waves, the audio signals, if transmitted directly by different transmitters, would get mixed up.

3. Solve the numerical problem.

Question 1.
Calculate the frequency in MHz of a radio wave of wavelength 250 m. Remember that the speed of all EM waves in vacuum is 3.0 × 108 m/s.
Answer:
Given: λ = 250 m, c = 3 × 108 m/s
To find: Frequency (v)
Formula: c = v8
Calculation: From formula,
v = \(\frac {c}{λ}\) = \(\frac {3×10^8}{250}\) = 1.2 × 106 Hz
= 1.2 MHz

Maharashtra Board Class 11 Physics Solutions Chapter 13 Electromagnetic Waves and Communication System

Question 2.
Calculate the wavelength in nm of an X-ray wave of frequency 2.0 × 1018 Hz.
Solution:
Given: c = 3 × 108, v = 2 × 1018 Hz
To find: Wavelength (λ)
Formula: c = vλ
Calculation. From formula,
λ = \(\frac {c}{v}\) = \(\frac {3×10^8}{2×10^{18}}\) = 1.5 × 10-10
= 0.15 nm

Question 3.
The speed of light is 3 × 108 m/s. Calculate the frequency of red light of wavelength of 6.5 × 10-7 m.
Answer:
Given: c = 3 × 108 m/s, λ = 6.5 × 10-7 m
To find: Frequency (v)
Formula: c = vλ
Calculation: From formula,
v = \(\frac {c}{λ}\) = \(\frac {3×10^8}{6.5×10^{-7}}\) = 4.6 × 1014 Hz

Question 4.
Calculate the wavelength of a microwave of frequency 8.0 GHz.
Answer:
Given: v = 8 GHz = 8 × 109 Hz,
c = 3 × 108 m/s
To find: Wavelength (λ)
Formula: c = vλ
Calculation: From formula,
λ = \(\frac {c}{λ}\) = \(\frac {3×10^8}{8×10^9}\) = 3.75 × 10-2
= 3.75 cm

Question 5.
In a EM wave the electric field oscillates sinusoidally at a frequency of 2 × 1010 What is the wavelength of the wave?
Answer:
Given: v = 2 × 1010 Hz, c = 3 × 108 m
To find: Wavelength (λ)
Formula: c = vλ
Calculation: From formula,
λ = \(\frac {c}{λ}\) = \(\frac {3×10^8}{2×10^{10}}\) = 1.5 × 10-2

Question 6.
The amplitude of the magnetic field part of a harmonic EM wave in vacuum is B0 = 5 X 10-7 T. What is the amplitude of the electric field part of the wave?
Answer:
Given: B0 = 5 × 10-7 T, c = 3 × 108
To find: Amplitude of electric field (E0)
Formula: c = \(\frac {E_0}{B_0}\)
Calculation /From formula,
E0 = c × B0
= 3 × 108 × 5 × 10-7
= 150 V/m

Question 7.
A TV tower has a height of 200 m. How much population is covered by TV transmission if the average population density around the tower is 1000/km²? (Radius of the Earth = 6.4 × 106 m)
Answer:
Given: h = 200 m,
Population density (n)
= 1000/km² = 1000 × 10-6/m² = 10-3/m²
R = 6.4 ×106 m
To find: Population covered
Formulae: i. A = πd² = π(\(\sqrt{2Rh}\))² = 2πRh
ii. Population covered = nA
Calculation /From formula (i),
A = 2πRh
= 2 × 3.142 × 6.4 × 106 × 200
≈ 8 × 109
From formula (ii),
Population covered = nA
= 10-3 × 8 × 109
= 8 × 106

Maharashtra Board Class 11 Physics Solutions Chapter 13 Electromagnetic Waves and Communication System

Question 8.
Height of a TV tower is 600 m at a given place. Calculate its coverage range if the radius of the Earth is 6400 km. What should be the height to get the double coverage area?
Answer:
Given: h = 600 m, R = 6.4 × 106 m
To find: Range (d)
Height to get the double coverage (h’)
Formula: d = \(\sqrt{2hR}\)
Calculation: From formula,
d = \(\sqrt{2×600×6.4×10^6}\) = 87.6 × 10³ = 87.6 km
Now, for A’ = 2A
π(d’)² = 2 (πd²)
∴ (d’)² = 2d²
From formula,
h’ = \(\frac{(d’)^2}{2R}\)
= \(\frac{2d^2}{2R}\)
= 2 × h ……….. (∵ h = \(\frac{d^2}{2R}\))
= 2 × 600
=1200 m

Question 9.
A transmitting antenna at the top of a tower has a height 32 m and that of the receiving antenna is 50 m. What is the maximum distance between them for satisfactory communication in line of sight mode? Given radius of Earth is 6.4 × 106 m.
Answer:
Given: ht = 32 m, hr = 50 m, R = 6.4 × 106 m
To find: Maximum distance or range (d)
Formula: d = \(\sqrt{2Rh}\)
Calculation: From formula,
dt = \(\sqrt{2Rh_t}\) = \(\sqrt{2×6.4×10^6×32}\)
= 20.238 × 10³ m
= 20.238 km
dr = \(\sqrt{2Rh_t}\)
= \(\sqrt{2×6.4×10^6×50}\)
= 25.298 × 10³ m
= 25.298 km
Now, d = dt + dr
= 20.238 + 25.298
= 45.536 km

11th Physics Digest Chapter 13 Electromagnetic Waves and Communication System Intext Questions and Answers

Can you recall? (Textbookpage no. 229)

Question 1.
i. What is a wave?
Answer:
Wave is an oscillatory disturbance which travels through a medium without change in its form.

ii. What is the difference between longitudinal and transverse waves?
Answer:
a. Transverse wave: A wave in which particles of the medium vibrate in a direction perpendicular to the direction of propagation of wave is called transverse wave.
b. Longitudinal wave: A wave in which particles of the medium vibrate in a direction parallel to the direction of propagation of wave is called longitudinal wave.

iii. What are electric and magnetic fields and what are their sources?
Answer:
a. Electric field is the force experienced by a test charge in presence of the given charge at the given distance from it.
b. A magnetic field is produced around a magnet or around a current carrying conductor.

iv. By which mechanism heat is lost by hot bodies?
Answer:
Hot bodies lose the heat in the form of radiation.

Maharashtra Board Class 11 Physics Solutions Chapter 13 Electromagnetic Waves and Communication System

Question 2.
What are Lenz’s law, Ampere’s law and Faraday’s law?
Answer:
Lenz’s law:
Whereas, Lenz’s law states that, the direction of the induced emf is such that the change is opposed.

Ampere’s law:
Ampere’s law describes the relation between the induced magnetic field associated with a loop and the current flowing through the loop.

Faraday’s law:
Faraday’s law states that, time varying magnetic field induces an electromotive force (emf) and an electric field.

Internet my friend. (Tpxtboakpage no. 240)

https//www.iiap.res.in/centers/iao
[Students are expected to visit the above mentioned website and collect more information about different EM wave propagations used by astronomical observatories.]

Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry

Balbharti Maharashtra State Board 11th Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry Important Questions and Answers.

Maharashtra State Board 11th Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry

Question 1.
Define chemistry.
Answer:
Chemistry is the study of matter, its physical and chemical properties, and the physical and chemical changes it undergoes under different conditions.

Question 2.
Why is chemistry called a central science?
Answer:

  1. Knowledge of chemistry is required in the studies of physics, biological sciences, applied sciences, and earth and space sciences.
  2. Chemistry is involved in every aspect of day-to-day life, i.e. the air we breathe, the food we eat, the fluids we drink, our clothing, transportation and fuel supplies, etc.

Hence, chemistry is called a central science.

Question 3.
Give reason: Although chemistry has ancient roots, it has developed as modern science.
Answer:
Technological development in sophisticated instruments has expanded knowledge of chemistry which, now, has been used in applied sciences such as medicine, dentistry, engineering, agriculture, and daily home use products. Hence, due to development and advancement in science and technology, chemistry has developed as modem science.

Question 4.
How is chemistry traditionally classified?
Answer:
Chemistry is traditionally classified into five branches:

  • Organic chemistry
  • Inorganic chemistry
  • Physical chemistry
  • Biochemistry
  • Analytical chemistry

Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry

Question 5.
Explain the following terms:
i. Organic chemistry
ii. Inorganic chemistry
iii. Physical chemistry
Answer:
i. Organic chemistry: It deals with properties and reactions of compounds of carbon.
ii. Inorganic chemistry: It deals with the study of all the compounds which are not organic.
iii. Physical chemistry: It deals with the study of properties of matter, the energy changes and the theories, laws and principles that explain the transformation of matter from one form to another. It also provides basic framework for all the other branches of chemistry.

Question 6.
Distinguish between
i. Mixtures and pure substances
ii. Mixtures and compounds
Answer:
i.

MixturesPure substances
a.Mixtures have no definite chemical composition.Pure substances have a definite chemical composition.
b.Mixtures have no definite properties.Pure substances always have the same properties regardless of their origin.
e.g.Paint (mixture of oils, pigment, additive), concrete (a mixture of sand, cement, water), etc.Pure metal, distilled water, etc.

ii.

MixturesCompounds
a.Mixtures have no definite chemical composition.Compounds are made up of two or more elements in fixed proportion.
b.The constituents of a mixture can be easily separated by physical method.The constituents of a compound cannot be easily separated by physical method.
e.g.Paint (mixture of oils, pigment, additive), concrete (a mixture of sand, cement, water), etc.Water, table salt, sugar, etc.

Question 7.
What is the difference between element and compound?
Answer:
Elements cannot be broken down into simpler substances while compounds can be broken down into simpler substances by chemical changes.

Question 8.
Explain: States of matter
Answer:
There are three different states of matter as follows:

  1. Solid: Particles are held tightly in perfect order. They have definite shape and volume.
  2. Liquid: Particles are close to each other but can move around within the liquid.
  3. Gas: Particles are far apart as compared to that of solid and liquid.

These three states of matter can be interconverted by changing the conditions of temperature and pressure.

Question 9.
Explain: Physical and chemical properties
Answer:
i. Physical properties: These are properties which can be measured or observed without changing the identity or the composition of the substance. e.g. Colour, odour, melting point, boiling point, density, etc.

ii. Chemical properties: These are properties in which substances undergo change in chemical composition. e.g. Coal bums in air to produce carbon dioxide, magnesium wire bums in air in the presence of oxygen to form magnesium oxide, etc.

Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry

Question 10.
How are properties of matter measured?
Answer:

  • Measurement involves comparing a property of matter with some fixed standard which is reproducible and unchanging.
  • Properties such as mass, length, area, volume, time, etc. are quantitative in nature and can be measured.
  • A quantitative measurement is represented by a number followed by units in which it is measured.
  • These units are arbitrarily chosen on the basis of universally accepted standards. e.g. Length of class room can be expressed as 10 m. Here, 10 is the number and ‘m’ is the unit ‘metre’ in which the length is measured.

Question 11.
Define: Units
Answer:
The arbitrarily decided and universally accepted standards are called units.
e.g. Metre (m), kilogram (kg).

Question 12.
What are the various systems in which units are expressed?
Answer:
Units are expressed in various systems like CGS (centimetre for length, gram for mass and second for time), FPS (foot, pound, second) and MKS (metre, kilogram, second) systems, etc.

Question 13.
What are SI units? Name the fundamental SI units.
Answer:
SI Units: In 1960, the general conference of weights and measures proposed revised metric system, called International system of Units i.e. SI system (abbreviated from its French name).
The seven fundamental SI units are as given below:

No.Base physical quantitySI unitSymbol
i.LengthMetrek
ii.MassKilogramkg
iii.TimeSeconds
iv.TemperatureKelvinK
v.Amount of substanceMolemol
vi.Electric currentAmpereA
vii.Luminous intensityCandelacd

[Note: Units for other quantities such as speed, volume, density, etc. can be derived from fundamental SI units.]

Question 14.
What is the basic unit of mass in the SI system?
Answer:
The basic unit of mass in the SI system is kilogram (kg).

Question 15.
Name the following:
i. Full form of CGS unit system
ii. Full form of FPS unit system
iii. The SI unit of length
iv. Symbol used for Candela unit
v. SI unit of electric current
vi. SI unit of electric current
Answer:
i. Centimetre Gram Second
ii. Foot Pound Second
iii. Metre (m)
iv. Cd
v. Kelvin (K)
vi. Ampere (A)

Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry

Question 16.
Give reason: The mass of a body is more fundamental property than its weight.
Answer:

  • Mass is an inherent property of matter and is the measure of the quantity of matter of a body.
  • The mass of a body does not vary with respect to its position.
  • On the other hand, the weight of a body is a result of the mass and gravitational attraction
  • Weight varies because the gravitational attraction of the earth for a body varies with the distance from the centre of the earth.

Hence, the mass of a body is more fundamental property than its weight.

Question 17.
How is gram related to the SI unit kilogram?
Answer:
The SI unit kilogram (kg) is related to gram (g) as 1 kg = 1000 g= 103 g.
[Note: ‘Gram’ is used for weighing small quantities of chemicals in the laboratories.
Other commonly used quantity is ‘milligram’. 1 kg = 1000 g = 106 mg]

Question 18.
Why are fractional units of the SI units of length often used? Give two examples of the fractional units of length. How are they related to the SI unit of length?
Answer:
i. Some properties such as the atomic radius, bond length, wavelength of electromagnetic radiation, etc. are very small and therefore, fractional units of the SI unit of length are often used to express these properties.
ii. Fractional units of length: Nanometre (nm), picometre (pm), etc.
iii. Nanometre (nm) and picometre (pm) are related to the SI unit of length (m) as follows:
1 nm = 10-9 m, 1 pm = 10-12 m

Question 19.
Define: Volume
Answer:
Volume is the amount of space occupied by a three-dimensional object. It does not depend on shape.

Question 20.
State the common unit used for the measurement of volume of liquids and gases.
Answer:
The common unit used for the measurement of volume of liquids and gases is litre (L).

Question 21.
How is the SI unit of volume expressed?
Answer:
The SI unit of volume is expressed as (metre)3 or m3.

Question 22.
Name some glassware that are used to measure the volume of liquids and solutions.
Answer:

  • Graduated cylinder
  • Burette
  • Pipette

Question 23.
What is a volumetric flask used for in laboratory?
Answer:
A volumetric flask is used to prepare a known volume of a solution in laboratory.

Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry

Question 24.
What is density of a substance? How is it measured?
Answer:
Density:

  • Density of a substance is its mass per unit volume. It is the characteristic property of any substance.
  • It is determined in the laboratory by measuring both the mass and the volume of a sample.
  • The density is calculated by dividing mass by volume.

Question 25.
How is the SI unit of density derived? State CGS unit of density.
Answer:
i. The SI unit of density is derived as follows:
Density = \(\frac{\text { SI unit mass }}{\text { SI unit volume }}\)
= \(\frac{\mathrm{kg}}{\mathrm{m}^{3}}\)
= kg m-3

ii. CGS unit of density: g cm-3
[Note: The CGS unit, g cm-3 is equivalent to \(\frac{\mathrm{g}}{\mathrm{mL}}\) or g mL-1.]

Question 26.
State three common scales of temperature measurement.
Answer:

  1. Degree Celsius (°C)
  2. Degree Fahrenheit (°F)
  3. Kelvin (K)

Question 27.
State the temperatures in Fahrenheit scale that corresponds to 0 °C and 100 °C.
Answer:
The temperature that corresponds to 0 °C is 32 °F and the temperature that corresponds to 100 °C is 212 °F.

Question 28.
Write the expression showing the relationship between:
i. Degree Fahrenheit and Degree Celsius
ii. Kelvin and Degree Celsius
Answer:
i. The relationship between degree Fahrenheit and degree Celsius is expressed as,
°F = \(\frac {9}{5}\) (°C) + 32
ii. The relationship between Kelvin and degree Celsius is expressed as,
K = °C + 273.15

Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry

Question 29.
Convert the following degree Fahrenheit temperature to degree Celsius.
i. 50 °F ii. 10 °F
Answer:
Given: Temperature in degree Fahrenheit = 50 °F
To find: Temperature in degree Celsius
Formula: °F = \(\frac {9}{5}\) (°C) + 32
Calculation: Substituting 50 °F in the formula,
°F = \(\frac {9}{5}\) (°C) + 32
50 = \(\frac {9}{5}\) (°C) + 32
°C = \(\frac{(50-32) \times 5}{9}\)
= 10 °C

ii. Given: Temperature in degree Fahrenheit = 10 °F
To find: Temperature in degree Celsius
Formula: °F = \(\frac {9}{5}\) (°C) + 32
Calculation: Substituting 10 °F in the formula,
°F = \(\frac {9}{5}\) (°C) + 32
10 = \(\frac {9}{5}\) (°C) + 32
°C = \(\frac{(10-32) \times 5}{9}\)
= -12.2 °C
Ans: i. The temperature 50 °F corresponds to 10 °C.
ii. The temperature 10 °F corresponds to -12.2 °C.

Question 30.
What is a chemical combination?
Answer:

  • The process in which the elements combine with each other to form compounds is called chemical combination.
  • The process of chemical combination is governed by five basic laws which were discovered before the knowledge of molecular formulae.

Question 31.
State and explain the law of definite proportions.
Answer:
Law of definite proportions:
i. The law states that “A given compound always contains exactly the same proportion of elements by weight”.
ii. French chemist, Joseph Proust worked with two samples of cupric carbonate; one of which was naturally occurring cupric carbonate and other was synthetic sample. He found the composition of elements present in both the samples was same as shown below:

Cupric carbonate% of copper% of carbon% of oxygen
Natural sample51.359.7438.91
Synthetic sample51.359.7438.91

iii. Thus, irrespective of the source, a given compound always contains same elements in the same proportion.

Question 32.
State and explain the law of multiple proportions.
Answer:
Law of multiple proportions:
i. John Dalton (British scientist) proposed the law of multiple proportions in 1803.
ii. It has been observed that two or more elements may combine to form more than one compound.
iii. The law states that, “ When two elements A and B form more than one compounds, the masses of element B that combine with a given mass of A are always in the ratio of small whole numbers”.
e.g. Hydrogen and oxygen combine to form two compounds, water and hydrogen peroxide.
Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry 1
Here, the two masses of oxygen (16 g and 32 g) which combine with the fixed mass of hydrogen (2 g) in these two compounds bear a simple ratio of small whole numbers, i.e. 16 : 32 or 1 : 2.

Question 33.
Show that NO and NO2 satisfy the law of multiple proportions.
Answer:
Nitrogen and oxygen combine to form two compounds, nitric oxide (NO) and nitrogen dioxide (NO2).
Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry 2
Here, the two masses of oxygen (16 g and 32 g) which combine with the fixed mass of nitrogen (14 g) in these two compounds bear a simple ratio of small whole numbers, i.e. 16 : 32 or 1 : 2.
This is in accordance with the law of multiple proportions.

Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry

Question 34.
Show that carbon monoxide and carbon dioxide satisfy the law of multiple proportions.
Answer:
Chemical reaction of carbon with oxygen gives two compounds, carbon monoxide (CO) and carbon dioxide (CO2).
Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry 3
Here, the two masses of oxygen (16 g and 32 g) which combine with the fixed mass of carbon (12 g) in these two compounds bear a simple ratio of small whole numbers, i.e. 16 : 32 or 1 : 2.
This is in accordance with the law of multiple proportions.

Question 35.
Show that SO2 and SO3 satisfy the law of multiple proportions.
Answer:
Chemical reaction of sulphur with oxygen gives two compounds, sulphur dioxide (SO2) and sulphur trioxide (SO3).
Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry 4
Here, the two masses of oxygen (32 g and 48 g) which combine with the fixed mass of sulphur (32 g) in these two compounds bear a simple ratio of small whole numbers, i.e. 32 : 48 or 2 : 3.
This is in accordance with the law of multiple proportions.

Question 36.
State and explain Gay Lussac’s law of gaseous volume with two examples.
Answer:
Gay Lussac’s law:
i. Gay Lussac proposed the law of gaseous volume in 1808.
ii. Gay Lussac’s law states that, “ When gases combine or are produced in a chemical reaction, they do so in a simple ratio by volume, provided all gases are at same temperature and pressure
e.g. a. Under identical conditions of temperature and pressure, 100 mL of hydrogen gas combine with 50 mL of oxygen gas to produce 100 mL of water vapour.
Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry 5
Thus, the simple ratio of volumes is 2 : 1 : 2.

b. Under identical conditions of temperature and pressure, 1 L of nitrogen gas combine with 3 L of hydrogen gas to produce 2 L of ammonia gas.
Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry 6
Thus, the simple ratio of volumes is 1 : 3 : 2.

Question 37.
Give two examples which support the Gay Lussac’s law of gaseous volume.
Answer:
i. Under identical conditions of temperature and pressure, 1 L of hydrogen gas reacts with 1 L of chlorine gas to produce 2 L of hydrogen chloride gas.
Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry 7
Thus, the ratio of volumes is 1 : 1 : 2
This is in accordance with Gay Lussac’s law.

ii. Under identical conditions of temperature and pressure, 200 mL sulphur dioxide combine with 100 mL oxygen to form 200 mL sulphur trioxide.
Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry 8
Thus, the ratio of volumes is 2 : 1 : 2.
This is in accordance with Gay Lussac’s law.

Question 38.
Match the following:

LawStatement
i.Law of definite proportionsa.When two elements A and B form more than one compounds, the masses of element B that combine with a given mass of A are always in the ratio of small whole numbers
ii.Gay Lussac’s lawb.Equal volumes of all gases at the same temperature and pressure contain equal number of molecules
iii.Law of multiple proportionsc.When gases combine or are produced in a chemical reaction they do so in a simple ratio by volume, provided all gases are at same temperature and pressure
iv.Avogadro’s lawd.A given compound always contains exactly the same proportion of elements by weight

Answer:
i – d,
ii – c,
iii – a,
iv – b

Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry

Question 39.
32 g of oxygen reacts with some carbon to make 56 grams of carbon monoxide. Find out how much mass must have been used.
Answer:
Given: Mass of oxygen (reactant) = 32 g, mass of carbon monoxide (product) = 56 g
To find: Mass of oxygen (reactant)
Calculation: 12 g of carbon combine with 16 g oxygen to form 28 g of carbon monoxide as follows:
Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry 9
Hence, (2 × 12 = 24 g) of carbon will combine with (2 × 16 = 32 g) of oxygen to give (2 × 28 = 56 g) carbon monoxide.
Ans: Mass of carbon used = 24 g

Question 40.
Calculate the mass of sulphur trioxide produced by burning 64 g of sulphur in excess of oxygen. (Average atomic mass: S = 32 u, O = 16 u).
Solution:
Given: Mass of sulphur (reactant) = 64 g
To find: Mass of sulphur dioxide (product)
Calculation: 32 g of sulphur combine with 48 g oxygen to form 80 g of sulphur trioxide as follows:
Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry 10
Hence, (2 × 32 = 64 g) of sulphur will combine with (2 × 48 = 96 g) of oxygen to give (2 × 80 = 160 g) sulphur trioxide.
Ans: Mass of sulphur trioxide produced = 160 g

Question 41.
Explain Dalton’s atomic theory.
Answer:
John Dalton published “A New System of chemical philosophy” in the year of 1808. He proposed the following features, which later became famous as Dalton’s atomic theory.

  • Matter consists of tiny, indivisible particles called atoms.
  • All the atoms of a given elements have identical properties including mass. Atoms of different elements differ in mass.
  • Compounds are formed when atoms of different elements combine in a fixed ratio.
  • Chemical reactions involve only the reorganization of atoms. Atoms are neither created nor destroyed in a chemical reaction.

Dalton’s atomic theory could explain all the laws of chemical combination.

Question 42.
Give reason: Dalton’s atomic theory explains the law of conservation of mass.
Answer:

  • The law of conservation of mass states that, “Mass can neither be created nor destroyed” during chemical combination of matter.
  • According to Dalton’s atomic theory, chemical reactions involve only the reorganization of atoms. Therefore, the total number of atoms in the reactants and products should be same and mass is conserved during a reaction.

Hence, Dalton’s atomic theory explains the law of conservation of mass.

Question 43.
Give reason: Dalton’s atomic theory explains the law of multiple proportion.
Answer:

  • The law of multiple proportion states that, “When two elements A and B form more than one compounds, the masses of element B that combine with a given mass of A are always in the ratio of small whole numbers
  • According to Dalton’s atomic theory, compounds are formed when atoms of different elements combine in fixed ratio.

Hence, Dalton’s atomic theory explains the law of multiple proportion.

Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry

Question 44.
Define: Atomic mass unit (amu).
Answer:
Atomic mass unit or amu is defined as a mass exactly equal to one twelth of the mass of one carbon-12 atom.

Question 45.
How is relative atomic mass of an atom measured?
Answer:

  • The mass of a single atom is extremely small, i.e. the mass of a hydrogen atom is 1.6736 × 10-24 g. Hence, it is not possible to weigh a single atom.
  • In the present system, mass of an atom is determined relative to the mass of an atom of carbon-12 as the standard. This was decided in 1961 by international agreement.
  • The atomic mass of carbon-12 is assigned as 12.00000 atomic mass unit (amu).
  • The masses of all other elements are determined relative to the mass of an atom of carbon-12 (C-12).
  • The atomic masses are expressed in amu which is exactly equal to one twelth of the mass of one carbon-12 atom.
  • The value of 1 amu is equal to 1.6605 × 10-24 g.

Question 46.
What is meant by Unified Mass unit?
Answer:

  • Presently, instead of amu, Unified Mass has now been accepted as the unit of atomic mass.
  • It is called Dalton and its symbol is ‘u’ or ‘Da’.

Question 47.
What is average atomic mass?
Answer:
The atomic mass of an element which exists as mixture of two or more isotopes is the average of atomic masses of its isotopes. This is called average atomic mass.

Question 48.
Define: Molecular mass
Answer:
Molecular mass of a substance is the sum of average atomic masses of the atoms of the elements which constitute the molecule.
OR
Molecular mass of a substance is the mass of one molecule of that substance relative to the mass of one carbon-12 atom.

Question 49.
How is molecular mass of a substance calculated? Give example.
Answer:
Molecular mass is calculated by multiplying average atomic mass of each element by the number of its atoms and adding them together.
e.g. Molecular mass of carbon dioxide (CO2) is calculated as follows:
Molecular mass of CO2 = (1 × average atomic mass of C) + (2 × average atomic mass of O)
= (1 × 12.0 u) + (2 × 16.0 u)
= 44.0 u

Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry

Question 50.
Mass of an atom of hydrogen in gram is 1.6736 × 10-24 g. What is the atomic mass of hydrogen in u?
Solution:
Given: Mass of an atom of hydrogen in gram is 1.6736 × 10-24 g.
To find: Atomic mass of hydrogen in u
Calculation: 1.66056 × 10-24 g = 1 u
∴ 1.6736 × 10-24 g = x
x = \(\frac{1.6736 \times 10^{-24} \mathrm{~g}}{1.66056 \times 10^{-24} \mathrm{~g} / \mathrm{u}}\) = 1.008u
Ans: The atomic mass of hydrogen in u = 1.008 u

Question 51.
The mass of an atom of one carbon atom is 12.011 u. What is the mass of 20 atoms of the same isotope?
Solution:
Mass of l atom of carbon = 12.011 u
∴ Mass of 20 atoms of same carbon isotope = 20 × 12.011 u = 240.220 u
Ans: The mass of 20 atoms of same carbon isotope = 240.220 u

Question 52.
Calculate the average atomic mass of neon using the following data:

IsotopeAtomic massNatural Abundance
20Ne19.9924 u90.92%
21Ne20.9940 u0.26 %
22Ne21.9914 u8.82 %

Solution:
Average atomic mass of Neon (Ne)
Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry 11
Ans: Average atomic mass of neon = 20.1707 u

Question 53.
Calculate the average atomic mass of argon from the following data:

IsotopeIsotopic mass (g mol-1)Abundance
36Ar35.967550.337%
38Ar37.962720.063%
40Ar39.962499.600%

Solution:
Average atomic mass of argon (Ar)
Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry 12
Ans: Average atomic mass of argon = 39.974 g mol-1

Question 54.
Calculate the molecular mass of the following in u:
i. H2O ii. C6H5Cl iii. H2SO4
Solution:
i. Molecular mass of H2O = (2 × Average atomic mass of H) + (1 × Average atomic mass of O)
= (2 × 1.0u) + (1 × 16.0 u)
= 18 u

ii. Molecular mass of C6H5Cl = (6 × Average atomic mass of C) + (5 × Average atomic mass of H) + (1 × Average atomic mass of Cl)
= (6 × 12.0 u) + (5 × 1.0 u) + (1 × 35.5 u)
= 112.5 u

iii. Molecular mass of H2SO4 = (2 × Average atomic mass of H) + (1 × Average atomic mass of S) + (4 × Average atomic mass of O)
= (2 × 1.0 u) + (1 × 32.0 u) + (1 × 16.0 u)
= 98 u
Ans: i. The molecular mass of H2O = 18 u
ii. The molecular mass of C6H5Cl = 112.5 u
iii. The molecular mass of H2SO4 = 98 u

Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry

Question 55.
Find the mass of 1 molecule of oxygen (O2) in amu (u) and in grams.
Solution:
Molecular mass of O2 = 2 × 16 u
∴ Mass of 1 molecule = 32 u
∴ Mass of 1 molecule of O2= 32 × 1.66056 × 10-24 g = 53.1379 × 10-24 g
Ans: Mass of 1 molecule in amu = 32 u
Mass of 1 molecule in grams = 53.1379 × 10-24 g

Question 56.
Find the formula mass of
i. NaCl ii. Cu(NO3)2
Solution:
i. Formula mass of NaCl
= Average atomic mass of Na + Average atomic mass of Cl
= 23.0 u + 35.5 u = 58.5 u

ii. Formula mass of Cu(NO3)2
= Average atomic mass of Cu + 2 × (Average atomic mass of N + Average atomic mass of three O)
= 63.5 + 2 × [14 + (3 × 16)] = 187.5 u
Ans: i. Formula mass of NaCl = 58.5 u
ii. Formula mass of Cu(NO3)2 = 187.5 u

Question 57.
Find the formula mass of
i. KCl
ii. AgCl
Atomic mass of K = 39 u, Ag =108 u and Cl = 35.5 u.
Solution:
i. Formula mass of KCl
= Average atomic mass of K + Average atomic mass of Cl
= 39 u + 35.5 u = 74.5 u

ii. Formula mass of AgCl
= Average atomic mass of Ag + Average atomic mass of Cl
= 108 + 35.5 = 143.5 u
Ans: i. Formula mass of KCl = 74.5 u
ii. Formula mass of AgCl = 143.5 u

Question 58.
Calculate the number of moles and molecules of urea present in 5.6 g of urea.
Solution:
Given: Mass of urea = 5.6 g
To find: The number of moles and molecules of urea
Formulae: i. Number of moles = \(\frac{\text { Mass of a substance }}{\text { Molar mass of a substance }}\)
ii. Number of molecules = Number of moles × Avogadro’s constant
Mass of urea = 5.6 g
Molecular mass of urea, NH2CONH2
= (2 × Average atomic mass of N) + (4 × Average atomic mass of H) + (1 × Average atomic mass of C) + (1 × average atomic mass of O)
= (2 × 14 u) + (4 × 1 u) + (1 × 12 u) + (1 × 16 u) = 60 u
∴ Molar mass of urea = 60 g mol-1
∴ Number of moles = \(\frac{\text { Mass of a substance }}{\text { Molar mass of a substance }}\)
= \(\frac{5.6 \mathrm{~g}}{60 \mathrm{~g} \mathrm{~mol}^{-1}}\)
= 0.09333 mol

[Calculation using log table:
\(\frac{5.6}{60}\)
= Antilog10 [log10 (5.6) – log10 (60)]
= Antilog10 [0.7482 – 1.7782]
= Antilog10 [latex]\overline{2} .9700[/latex]
= 0.09333]

Now,
Number of molecules of urea
= Number of moles × Avogadro’s constant
= 0.09333 mol × 6.022 × 1023 molecules/mol
= 0.5616 × 1023 molecules (by using log table)
= 5.616 × 1022 molecules
Ans: Number of moles of urea = 0.0933 mol
Number of molecules of urea = 5.616 × 1022 molecules

[Calculation using log table:
0.09333 × 6.022
= Antilog10 [log10 (0.09333) + log10 (6.022)]
= Antilog10 [\(\overline{2} .9698\) + 0.7797]
= Antilog10 [latex]\overline{1} .7495[/latex]
= 0.5616]

Question 59.
Calculate the number of atoms in each of the following:
i. 64 u of oxygen (O)
ii. 42 g of nitrogen (N)
Solution:
i. 64 u of oxygen (O) = x atoms
Atomic mass of oxygen (O) = 16 u
∴ Mass of one oxygen atom = 16 u
∴ x = \(\frac{64 \mathrm{u}}{16 \mathrm{u}}\) = 4 atoms

ii. 42 g of nitrogen (N)
Atomic mass of nitrogen = 14 u
∴ Molar mass of nitrogen = 14 g mol-1
Now,
Number of moles = \(\frac{\text { Mass of a substance }}{\text { Molar mass of a substance }}\)
= \(\frac{42 \mathrm{~g}}{14 \mathrm{~g} \mathrm{~mol}^{-1}}\) = 3 mol
Now,
Number of atoms = Number of moles × Avogadro’s constant
= 3 mol × 6.022 × 1023 atoms/mol
= 18.07 × 1023 atoms
= 1.807 × 1024 atoms
Ans: i. Number of oxygen atoms in 64 u = 4 atoms
ii. Number of nitrogen atoms in 42 g = 1.807 × 1024 atoms

Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry

Question 60.
Calculate the number of atoms in each of the following.
i. 52 moles of Argon (Ar)
ii. 52 u of Helium (He)
iii. 52 g of Helium (He)
Solution:
i. 52 moles of Argon
1 mole Argon atoms = 6.022 × 1023 atoms of Ar
∴ Number of atoms = 52 mol × 6.022 × 1023 atoms/mol
= 313.144 × 1023 atoms of Argon

ii. 52 g of He
Molar mass of He = mass of 1 atom of He = 4.0 u
4.0 u = 1 He
∴ 52 u = x
∴ x = 52 u × \(\frac{1 \text { atom of He }}{4.0 \mathrm{u}}\) = 13 atoms of He

iii. 52 g of He
Molar mass of He = 4.0 g mol-1
Number of moles = \(\frac{\text { Mass of a substance }}{\text { Molar mass of a substance }}\)
= \(\frac{52 \mathrm{~g}}{4.0 \mathrm{~g} \mathrm{~mol}^{-1}}\)
= 13 mol
Number of atoms of He = Number of moles × Avogadro’s constant
= 13 mol × 6.022 × 1023 atoms/mol
= 78.286 × 1023 atoms of He
Ans. i. Number of argon atoms in 52 moles = 313.144 × 1023 atoms of Argon
ii. Number of helium atoms in 52 u = 13 atoms of He
iii. Number of helium atoms in 52 g = 78.286 × 1023 atoms of He

Question 61.
Calculate the number of atoms of ‘C’, ‘H’ and ‘O’ in 72.5 g of isopropanol, C3H7OH (molar mass 60 g mol-1).
Solution:
Mass of isopropanol(C3H7OH) = 72.5 g
The number of atoms of C, H, O
Calculation: Molecular formula of isopropanol, is C3H7OH.
Molar mass of C3H7OH = 60 g mol-1
Number of moles = \(\frac{\text { Mass of a substance }}{\text { Molar mass of a substance }}\)
= \(\frac{72.5 \mathrm{~g}}{60 \mathrm{~g} \mathrm{~mol}^{-1}}\)
= 1.208 mol
∴ Moles of isopropanol = 1.21 mol
Number of atoms = Number of moles × Avogadro’s constant
Now, 1 molecule of isopropanol has total 12 atoms, out of which 8 atoms are of H, 3 of C and 1 of O.
∴ Number of C atoms in 72.5 g isopropanol = (3 × 1.208) mol × 6.022 × 1023 atoms/mol
= 2.182 × 1024 atoms of carbon
∴ Number of ‘H’ atoms in 72.5 g isopropanol = (8 × 1.208) mol × 6.022 × 1023 atoms/mol
= 5.819 × 1024 atoms of hydrogen
∴ Number of ‘O’ atoms in 72.5 g isopropanol = (1 × 1.208) mol × 6.022 × 1023 atoms/mol
= 7.274 × 1023 atoms of oxygen
Ans. 72.5g of isopropanol contain 2.182 ×1024 atoms of H and 7.274 × 1023 atoms of O.

Question 62.
Calculate the number of moles and molecules of ammonia (NH3) gas in a volume 67.2 dm3 of it measured at STP.
Solution:
Given: Volume of ammonia at STP = 67.2 dm3
To find: Number of moles and molecules of ammonia
Formulae: i. Number of moles of a gas (n) = \(\frac{\text { Volume of a gas at STP }}{\text { Molar volume of a gas }}\)
ii. Number of molecules = Number of moles × 6.022 × 1023 molecules mol-1
Calculation: Molar volume of a gas = 22.4 dm3 mol-1 at STP.
Number of moles (n) = \(\frac{\text { Volume of a gas at STP }}{\text { Molar volume of a gas }}\)
Number of moles of NH3 = \(\frac{67.2 \mathrm{dm}^{3}}{22.4 \mathrm{dm}^{3} \mathrm{~mol}^{-1}}\)
Number of molecules = Number of moles × 6.022 × 1023 molecules mol-1
3.0 mol × 6022 × 1023 molecules mol-1
= 18.066 × 1023 molecules
Ans: Number of moles of ammonia = 3.0 mol
Number of molecules of ammonia = 18.066 × 1023 molecules

Question 63.
3.40 g of ammonia at STP occupies volume of 4.48 dm3. Calculate molar mass of ammonia.
Solution:
Given: Mass of ammonia = 3.40 g
Volume at STP = 4.48 dm3
To Find: Molar mass of ammonia
Calculation: Let ‘x’ grams be the molar mass of NH3.
Molar volume of a gas = 22.4 dm3 mol-1 at STP.
Volume occupied by 3.40 g of NH3 at S.T.P = 4.48 dm3
Volume occupied by ‘x’ g of NH3 at S.T.P = 22.4 dm3
∴ x = \(\frac{22.4 \times 3.40}{4.48}\) = 17.0 g mol-1
Ans: Molar mass of ammonia is 17.0 g mol-1.

Question 64.
Veg puffs from a particular bakery have an average mass of 27.0 g, whereas egg puffs from the same bakery have an average mass of 40 g.
i. Suppose a person buys 1 kg of veg puff from the bakery. Calculate the number of veg puffs he receives.
ii. Determine the mass of egg puffs (in kg) that will contain the same number of eggs puffs as in one kilogram of veg puffs.
Solution:
i. Mass of a veg puff = 27.0 g = 0.027 kg
∴ Number of veg puffs in 1 kg = 1 / 0.027 = 37
ii. One kilogram of veg puffs contains 37 veg puffs.
Mass of 37 egg puffs = 37 × 0.040 = 1.48 kg
Ans: i. 37 veg puffs in 1 kg of puff.
ii. Mass of 37 egg puffs is 1.48 kg

Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry

Multiple Choice Questions:

1. The branch of chemistry which deals with carbon compounds is called ……………. chemistry.
(A) organic
(B) inorganic
(C) carbon
(D) bio
Answer:
(A) organic

2. A/an is a simple combination of two or more substances in which the constituent substances retain their separate identities.
(A) compound
(B) mixture
(C) element
(D) All of these
Answer:
(B) mixture

3. Which one of the following is NOT a mixture?
(A) Paint
(B) Gasoline
(C) Liquefied Petroleum Gas (LPG)
(D) Distilled water
Answer:
(D) Distilled water

4. The sum of the masses of reactants and products is equal in any physical or chemical reaction. This is in accordance with ………………
(A) law of multiple proportion
(B) law of definite composition
(C) law of conservation of mass
(D) law of reciprocal proportion
Answer:
(C) law of conservation of mass

5. A sample of calcium carbonate (CaCO3) has the following percentage composition: Ca = 40 %; C = 12 %; O = 48 %. If the law of definite proportions is true, then the weight of calcium in 4 g of a sample of calcium
carbonate from another source will be ……………..
(A) 0.016 g
(B) 0.16 g
(C) 1.6 g
(D) 16 g
Answer:
(C) 1.6 g

Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry

6. Two elements, A and B, combine to form two compounds in which ‘a’ g of A combines with ‘b1’ and ‘b2’g of B respectively. According to law of multiple proportion ………………
(A) b1 = b2
(B) b1 and b2 bear a simple whole number ratio
(C) a and b1 bear a whole number ratio
(D) no relation exists between b1 and b2
Answer:
(B) b1 and b2 bear a simple whole number ratio

7. At constant temperature and pressure, two litres of hydrogen gas react with one litre of oxygen gas to produce two litres of water vapour. This is in accordance with ……………….
(A) law of multiple proportion
(B) law of definite composition
(C) law of conservation of mass
(D) law of gaseous volumes
Answer:
(D) law of gaseous volumes

8. One mole of oxygen molecule weighs …………….
(A) 8 g
(B) 32 g
(C) 16 g
(D) 6.022 × 1023 g
Answer:
(B) 32 g

9. The mass of 0.002 mol of glucose (C6H12O6) is ………………
(A) 0.20 g
(B) 0.36 g
(C) 0.50 g
(D) 1.80 g
Answer:
(B) 0.36 g

10. Which of the following is CORRECT?
(A) 1 mole of oxygen atoms contains 6.0221367 × 1023 atoms of oxygen.
(B) 1 mole of water molecules contains 6.0221367 × 1023 molecules of water.
(C) 1 mole of sodium chloride contains 6.0221367 × 1023 formula units of NaCl.
(D) All of these
Answer:
(D) All of these

Maharashtra Board Class 11 Chemistry Important Questions Chapter 1 Some Basic Concepts of Chemistry

11. 180 g of glucose (C6H12O6) contains ……………. carbon atoms.
(A) 1.8 × 1023
(B) 1.8 × 1024
(C) 3.6 × 1023
(D) 3.6 × 1024
Answer:
(C) 3.6 × 1023

12. The number of molecules present in 8 g of oxygen gas is …………….
(A) 6.022 × 1023
(B) 3.011 × 1023
(C) 12.044 × 1023
(D) 1.505 × 1023
Answer:
(D) 1.505 × 1023

13. The number of molecules in 22.4 cm3of ozone gas at STP is ……………….
(A) 6.022 × 1020
(B) 6.022 × 1023
(C) 22.4 × 1020
(D) 22.4 × 1023
Answer:
(A) 6.022 × 1020

14. 11.2 cm3 of hydrogen gas at STP, contains …………….. moles.
(A) 0.0005
(B) 0.01
(C) 0.029
(D) 0.5
Answer:
(A) 0.0005

15. The mass of 224 mL of hydrogen gas at STP is
(A) 0.02 g
(B) 0.224 g
(C) 2.24 g
(D) 20.0 g
Answer:
(A) 0.02 g

16. 4.4 g of an unknown gas occupies 2.24 L of volume under STP conditions. The gas may be ………………
(A) CO2
(B) CO
(C) O2
(D) SO2
Answer:
(A) CO2

Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry

Balbharti Maharashtra State Board 11th Chemistry Textbook Solutions Chapter 14 Basic Principles of Organic Chemistry Textbook Exercise Questions and Answers.

Maharashtra State Board 11th Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry

1. Answer the following :

Question A.
Write condensed formulae and bond line formulae for the following structures.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 1
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 2

Question B.
Write dash formulae for the following bond line formulae.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 3
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 4

Question C.
Write bond-line formulae and condensed formulae for the following compounds
a. 3-methyloctane
b. hept-2-ene
c. 2, 2, 4, 4- tetramethylpentane
d. octa-1,4-diene
e. methoxy ethane
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 5

Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry

Question D.
Write the structural formulae for the following names and also write correct IUPAC names for them.
a. 5-ethyl-3-methylheptane
b. 2,4,5-trimethylthexane
c. 2,2,3-trimethylpentan-4-01
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 6

Question E.
Identify more favourable resonance structure from the following. Justify.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 7
Answer:
a.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 8
Structure (I) will be more favourable resonance structure as structure (II) involves separation of opposite charges and the electronegative oxygen atom has a positive charge.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 9
Both structures (I) and (II) involves separation of opposite charges, but structure (I) has a positive charge on the more electropositive ‘C’ and a negative charge on more electronegative ‘O’. Thus, structure (I) will be more favourable resonance structure.

Question F.
Find out all the functional groups present in the following polyfunctional compounds.
a. Dopamine a neurotransmitter that is deficient in Parkinson’s disease.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 10
b. Thyroxine the principal thyroid hormone.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 11
c. Penicillin G, a naturally occurring antibiotic
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 12
Answer:
i. Functional groups: Phenolic -OH group (Ar-OH) and primary amine (-NH2) group are present in dopamine.
ii. Functional groups: Phenolic -OH group (Ar-OH), halide (-I), ether (Ar-O-Ar), primary amine (-NH2) carboxylic acid (-COOH) groups are present in thyroxine.
iii. Functional groups: Secondary amide
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 13,
carboxylic acid (-COOH), tertiary amide
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 14,
thioether (R-S-R) groups are present in penicillin G.

Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry

Question G.
Find out the most stable species from the following. Justify.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 15
Answer:
a. The most stable species from the given species is \(\left(\mathrm{H}_{3} \mathrm{C}\right)_{3} \dot{\mathrm{C}}\) i.e., tert-butyl radical.
This is because it has greater number of alkyl groups attached to the C-atom having unpaired electron. More the number of the alkyl groups, the greater will be +1 inductive (electron releasing) effect, and thereby greater will be the stability of the free radical.

b. The most stable species from the given species is \(\mathrm{CBr}_{3}^{-}\).
This is because it contains 3 -Br atoms, which exhibits electron withdrawing inductive effect. Carbanions are stabilized by -I inductive (electron withdrawing) effect. Larger the number of -I groups attached to the negatively charged carbon atom, lower will be the electron density on the carbon atom and higher will be its stability.

c. The most stable species from the given species is \(\stackrel{+}{\mathbf{C}} \mathbf{H}_{3}\).
This because it does not contain Cl atom, which exhibits electron withdrawing inductive effect. Carbocations are destabilized by -I inductive (electron withdrawing) effect. When more number of-I groups are attached to the positively charged carbon atom, the positive charge on the carbon atom increases further, thus destabilizing the species. Hence, the species with no -I groups will be most stable.

Question H.
Identify the α-carbons in the following species and give the total number of α-hydrogen in each.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 16
Answer:
a.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 17
In structure (i), C-2 and C-4 are α-carbon atoms.
Hydrogen atoms(s) attached to α-C atoms is a α-H atom. Thus, structure (i) contains 4 α-H atoms.
b.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 18
In structure (ii), carbon atoms adjacent to C-2 are α-carbon atoms (as shown in the structure).
Thus, structure (ii) contains 6 α-H atoms.

c.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 19
C-3 carbon atom, that is, C-atom next to (H2C=CH-) is a α-C atom.
Thus, structure (iii) contains 2 α-H atoms.

Question I.
Identify primary, secondary, tertiary and quaternary carbon in the following compounds.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 20
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 21

2. Match the pairs

Column ‘A’Column ‘B’
i.Inductive effecta.Delocalization of π  electrons
ii.Hyperconjugationb.Displacement of π electrons
iii.Resonance effectc.Delocalization of σ electrons
d.Displacement of σ electrons

Answer:
i – d,
ii – c,
iii – a

Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry

3. What is meant by homologous series ? Write the first four members of homologous series that begins with
A. CH3CHO
B. H-C≡C-H
Also write down their general molecular formula.
Answer:
Homologous series: A series of compounds of the same family in which each member has the same type of carbon skeleton and functional group, and differs from the next member by a constant difference of one methylene group (-CH2-) in its molecular and structural formula is called as homologous series.
A. CH3CHO :
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 22
Comparing these molecular formulae and assigning the number of carbon atoms as ‘n’, the following general formula is deduced: CnH2nO/CnH2n-1CHO (where n = 1, 2, 3, …).

B. H-C≡C-H :
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 23
Comparing these molecular formulae and assigning the number of carbon atoms as ‘n’, the following general formula is deduced: CnH2n-2 (where n = 2, 3,4,….).

4. Write IUPAC names of the following
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 24
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 25

5. Find out the type of isomerism exhibited by the following pairs.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 26
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 27
Answer:
A. Metamerism
B. Functional group isomerism
C. Tautomerism
D. Tautomerism

Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry

6. Draw resonance srtuctures of the following :

A. Phenol
B. Benzaldehyde
C. Buta-1,3-diene
D. Acetate ion
Answer:
A. Resonance structures for phenol:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 28

B. Resonance structures of benzaldehyde:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 29

C. Resonance structures of Buta-1,3-diene:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 30

D. Resonance structures of acetate ion:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 31

7. Distinguish :

Question A.
Inductive effect and resonance effect
Answer:
Inductive effect:

  1. Presence of polar covalent bond is required.
  2. The polarity is induced in adjacent carbon- carbon single (covalent) bond due to a presence of influencing group (more electronegative atom than carbon).
  3. Depending on the nature of influencing group it is differentiated as +I effect and -I effect.
  4. The direction of the arrow head denotes the direction of the permanent electron displacement.

Resonance effect:

  1. Presence of conjugated n electron system or species having an atom carrying p orbital attached to a multiple bond is required.
  2. The polarity is produced in the molecule by the interaction of conjugated π bonds (or that between π bond and p orbital on the adjacent atom).
  3. Depending on the nature of influencing group it is differentiated as +R and -R effect.
  4. The delocalisation of n electrons is denoted by using curved arrows.

Question B.
Electrophile and nucleophile
Answer:
Electrophile:

  1. Electrophile is an electron deficient species.
  2. It is attracted towards negative charge (electron seeking).
  3. It attacks a nucleophilic centre in the substrate and brings about an electrophilic reaction
  4. It is an electron pair acceptor. (Lewis acid)
  5. It can be a positively charged ion or a neutral species having a vacant orbital.
    e.g. H+, Br , \(\mathrm{NO}_{2}^{+}\), BF3, AlCl3, etc.

Nucleophile:

  • Nucleophile is an electron rich species.
  • It is attracted towards positive charge (nucleus seeking).
  • It attacks the electrophilic centre in the substrate and brings about a nucleophilic reaction.
  • It is an electron pair donor. (Lewis base)
  • It can be negatively charged ion or neutral species having at least one lone pair of electrons.
    Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 32

C. Carbocation and carbanion
Answer:
Carbocation:

  • It is a species in which carbon carries a positive charge.
  • Positively charged carbon is sp2 hybridized.
  • It is electron-deficient.
  • e.g. tert-Butyl carbocation, (CH3)3C+

Carbanion:

  • It is a species in which carbon carries a negative charge.
  • Negatively charged carbon is sp3/sp2 hybridized.
  • It is electron-rich.
  • e.g.Methyl carbanion,
    Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 33

D. Homolysis and heterolysis
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 34

Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry

8. Write true or false. Correct the false stament
A. Homolytic fission involves unsymmetrical breaking of a covalent bond.
B. Heterolytic fission results in the formation of free radicals.
C. Free radicals are negatively charged species
D. Aniline is heterocyclic compound.
Answer:
A. False
Homolytic fission involves symmetrical breaking of a covalent bond.
B. False
Heterolytic fission results in the formation of charged ions like cation and anion.
C. False
Free radicals are electrically neutral/uncharged species.
D. False
Aniline is a homocyclic aromatic compound.

9. Phytane is naturally occuring alkane produced by the alga spirogyra and is a constituent of petroleum. The IUPAC name for phytane is 2, 6, 10, 14-tetramethyl hexadecane. Write zig-zag formula for phytane. How many primary, secondary, tertiary and quaternary carbons are present in this molecule.
Answer:
Zig-zag formula of phytane (2,6,10,14-tetramethyl hexadecane) is as follows:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 35
Dash formula to represent types of C-atom:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 36
In phytane, six 1° C-atoms, ten 2° C-atoms, four 3° C-atoms are present. Phytane does not contain any quaternary carbon atom in its structure.

10. Observe the following structures and answer the questions given below.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 37
a. What is the relation between (i) and (ii) ?
b. Write IUPAC name of (ii).
c. Draw the functional group isomer of (i).
Answer:
a. (a) and (b) are chain isomers of each other.
b. IUPAC name of structure (b) is 2-methylpropanal.
c. Functional group isomer of (a) is butanone.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 38

11. Observe the following and answer the questions given below
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 39
a. Name the reactive intermediae produced
b. Indicate the movement of electrons by suitable arrow to produce this intermediate
c. Comment on stability of this intermediate produced.
Answer:
i. The reactive intermediates produced are methyl free radicals:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 40
ii. Stability order of alkyl free radicals is: \(\dot{\mathrm{C}} \mathrm{H}_{3}\) < 1° <2° <3°
Hence, \(\dot{\mathrm{C}} \mathrm{H}_{3}\) produced in the above reaction is least stable and highly reactive.

Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry

12. An electronic displacement in a covalent bond is represented by following notation.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 41
A. Identify the effect
B. Is the displacement of electrons in a covalent bond temporary or permanent.
Answer:
A. The electronic displacement represented above is inductive effect (-I effect).
B. Inductive effect is a permanent electronic effect as it depends on the electronegativity of the atoms. In the given example, the displacement of electrons is permanent as Cl is more electronegative than C.

13. Draw all the no-bond resonance structures of isopropyl carbocation.
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 42

14. A covalent bond in tert-butyl bromide breaks in a suitable polat solvent to give ions.
A. Name the anion produced by this breaking of a covalent bond.
B. Indicate the type of bond breaking in this case.
C. Comment on geometry of the cation formed by such bond cleavage.
Answer:
A. The anion produced by breaking of the covalent C – Br bond is bromide
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 43
B. Heterolytic cleavage/fission takes place as charged ions are produced.
C. tert-Butyl carbocation formed in the given cleavage has trigonal planar geometry.

15. Choose correct options

A. Which of the following statements are true with respect to electronic displacement in covalent bond ?
a. Inductive effect operates through π bond
b. Resonance effect operates through σ bond
c. Inductive effect operates through σ bond
d. Resonance effect operates through π bond
i. a. and b
ii. a and c
iii. c and d
iv. b and c
Answer:
iii. c and d

B. Hyperconjugation involves overlap of …………. orbitals
a. σ – σ
b. σ – p
c. p – p
d. π – π
Answer:
b. σ – p

Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry

C. Which type of isomerism is possible in CH3CHCHCH3?
a. Position
b. Chain
c. Geometrical
d. Tautomerism
Answer:
a. Position

D. The correct IUPAC name of the compound
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 44
is ……………
a. hept-3-ene
b. 2-ethylpent-2-ene
c. hex-3-ene
d. 3-methylhex-3-ene
Answer:
d. 3-methylhex-3-ene

E. The geometry of a carbocation is …………
a. linear
b. planar
c. tetrahedral
d. octahedral
Answer:
b. planar

F. The homologous series of alcohols has general molecular formula ………..
a. CnH2n+1OH
b. CnH2n+2OH
c. CnH2n-2OH
d. CnH2nOH
Answer:
a. CnH2n+1OH

G. The delocaalization of electrons due to overlap between p-orbital and sigma bond is called …………….
a. Inductive effect
b. Electronic effect
c. Hyperconjugation
d. Resonance
Answer:
c. Hyperconjugation

11th Chemistry Digest Chapter 14 Basic Principles of Organic Chemistry Intext Questions and Answers

Can you recall? (Textbook Page No. 204)

Question i.
Which is the essential element in all organic compounds?
Answer:
Carbon is the essential element in all organic compounds.

Question ii.
What is the unique property of carbon that makes organic chemistry a separate branch of chemistry?
Answer:

  • All organic compounds contain carbon.
  • Carbon atoms show catenation property in which carbon atoms combine with other carbon atoms to form long chains and rings.
  • Carbon atom can also form multiple bonds with other carbon atoms and with atoms of other elements.
  • Due to this property of self-linking of carbon, a large number of organic compounds like proteins, DNA, sugar, oils, etc., are formed.

Thus, the unique property of catenation of carbon makes organic chemistry a separate branch of chemistry.

Question iii.
Which classes of organic compounds are often used in our daily diet?
Answer:
Carbohydrates (sugars), proteins (pulses), fats (edible plant and animal oil) and vitamins are the major classes of organic compounds often used in our daily diet.

Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry

Try this. (Textbook Page No. 204)

Question 1.
Find out the structures of glucose, vanillin, camphor and paracetamol using internet. Mark the carbon atoms present in them. Assign the hybridization state to each of the carbon and oxygen atom. Identify sigma (σ) and pi (π) bonds in these molecules.
Answer:
i. Structure of glucose:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 45
a. Hybridization of carbon: In glucose, only carbon at position C-1 is sp2 hybridized. On the other hand, carbons at C-2, C-3, C-4, C-5 and C-6 positions are sp3 hybridized.
b. Hybridization of oxygen: Oxygen atom attached to C-1 is sp2 hybridized, rest oxygen atoms attached to carbon at C-2, C-3, C-4, C-5 and C-6 are sp3 hybridized.
[Note: Here, the open chain structure of glucose is used to answer the given questions.]
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 46

ii. Structure of vanillin:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 47
a. Hybridization of carbon: In vanillin, carbon atoms C-1 to C-7 are sp2 hybridized. Only C-8 carbon is sp3 hybridized.
b. Hybridization of oxygen: Oxygen atom bonded to C-7 sp2 hybridized whereas oxygen atom bonded to C-4 and C-8 are sp3 hybridized.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 48

iii. Structure of camphor:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 49
a. Hybridization of carbon: In camphor, all the carbons are sp3 hybridized except the carbonyl carbon which is sp2 hybridized.
b. Hybridization of oxygen: The carbonyl oxygen is sp2 hybridized.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 50

iv. Structure of paracetamol:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 51
a. Hybridization of carbon: In paracetamol, carbons present in the ring and carbon at C-7 position are sp2 hybridized. Only C-8 carbon is sp3 hybridized.
b. Hybridization of oxygen: Oxygen atom attached to carbon at ,C-1 position is sp3 hybridized. Oxygen atom attached to carbon at C-7 position is sp2 hybridized.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 52

Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry

Question 2.
i. Draw the structural formula of ethane.
ii. Draw electron-dot structure of propane.
Ans:
i. Structural formula of ethane (C2H6) can be drawn as follows:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 53
ii. Electron-dot structure of propane is given as,
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 54
Where ‘•’ represents valence electrons of carbon and hydrogen.

Try this (Textbook Page No. 205)

Complete the table:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 55
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 56
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 57

Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry

Try this. (Textbook Page No. 206)

Question 1.
Draw two Newman projection formulae and two Sawhorse formulae for the propane molecule.
Answer:
Structural formula of propane is:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 58
Structural formula of propane:
i. Newman projection formulae for propane molecule can be given as:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 59
ii. Sawhorse formula for propane molecule can be given as:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 60

Can you tell? (Textbook Page No. 208)

Question 1.
Consider the following reaction:
2CH3 – CH2 – CH2 – OH + 2Na → 2CH3 – CH2 – CH2 – ONa + H2
Compare the structure of the substrate propanol with that of the product sodium propoxide. Which part of the substrate, the carbon skeleton or the OH group has undergone a change during the reaction?
Answer:
In above reaction, the -OH group of the substrate molecule has undergone a change. The H-atom of hydroxyl group (-OH) is replaced by sodium forming the product.

Activity: (Textbook Page No. 219)

Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 61
Observe the structural formulae (a) and (b).
i. Find out their molecular formulae.
ii. What is the difference between them?
iii. What is the relation between the two compounds represented by these structural formulae?
Answer:
i. Molecular formula of both (a) and (b) are same i.e., C3H6O.
ii. Compound (a), has a ketone (-CO-) functional group (i.e., acetone) and compound (b) has an aldehyde (-CHO) functional group (i.e., propionaldehyde). Both the compounds have different functional groups.
iii. Compound (a) and (b) are isomers of each other.
[Note: Aldehydes and ketones are the functional group isomers of each other.]

Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry

Can you tell? (Textbook Page No. 222)

Question 1.
Some bond fissions are described in the following table. For each of them, show the movement of electron/s using curved arrow notation. Classify them as homolysis or heterolysis and identify the intermediate species produced as carbocation, carbanion or free radical.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 62
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 63

Can you recall? (Textbook Page No. 223)

i. What is meant by ‘reagent’?
ii. Identify the ‘reagent’, ‘substrate’, ‘product’ and ‘byproduct’ in the following reaction.
CH3COCl + NH3 → CH3CONH2 + HCl
Answer:
i. The reactant which reacts with a substrate to form corresponding products is known reagent.
ii.
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 64

Can you recall? (Textbook Page No. 224)

i. How is covalent bond formed between two atoms?
ii. Consider two covalently bonded atoms Q and R where R is more electronegative than Q. Will these atoms share the electron pair equally between them?
iii. Represent the above polar covalent bond between Q and R using fractional charges δ+ and δ.
Answer:
i. A covalent bond is formed between two atoms by mutual sharing of electrons so as to complete their octets or duplets (in case of elements having only one shell).

ii. A covalent bond is formed between Q and R having different electronegativities, that is, R is more electronegative than Q. In such a case, the atom R with a higher value of electronegativity pulls the shared pair of electrons to a greater extent towards itself as compared to the atom Q with lower value of electronegativity. As a result of this, the shared pair of electrons will get shifted towards atom R. Thus, both the atoms Q and R will not share the electron pair equally between them.

iii. Polar covalent bond between Q and R can be represented as:
\(\mathrm{Q}^{\delta+}-\mathrm{R}^{\delta-}\)

Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry

Try this (Textbook Page No. 225)

i. Draw a bond line structure of benzene (C6H6).
ii. How many C – C and C = C bonds are there in this structure?
iii. Write down the expected values of the bond lengths of the carbon-carbon bonds in benzene (Refer chapter 5).
Answer:
i. Bond line structure of benzene:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 65
ii. In benzene, there are three alternating C – C single bonds and C = C double bonds.
[Note: In benzene, there are six C – C sigma bonds and three C – C pi bonds.]
iii. The expected values of carbon-carbon bond lengths in benzene are:

BondBond length
C – C154 pm
C = C133 pm

Can you recall? (Textbook Page No. 225)

i. Write down two Lewis structures for ozone. (Refer chapter 5)
ii. How are these two Lewis structures related to each other?
iii. What are these two Lewis structures called?
Answer:
i. Lewis structures of ozone can be shown as follows:
Maharashtra Board Class 11 Chemistry Solutions Chapter 14 Basic Principles of Organic Chemistry 66
ii. In these two Lewis structures, the position of the atoms is same but the position of pair of electrons (or formal charge) is different. These two Lewis structures are considered equivalent to each other.
iii. These two Lewis structures are called as resonating or contributing or canonical structures.

Internet my friend (Textbook Page No. 229)

i. Basic principles of organic chemistry:
https://authors.library.caltech.edu/25034
ii. Collect information about isomerism.
Answer:
i. Students are expected to refer to the book provided in the above link to collect additional information on the basic principles of organic chemistry.

ii. https://www.compoundchem.com/2014/05/22/typesofisomerism/
chemdictionary.org/structural-isomers/
https://en.wikipedia.org/wiki/Structural_isomer
[Note: Students can use the above links as a reference and collect additional information about isomerism on their own.]

Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity

Balbharti Maharashtra State Board 11th Chemistry Textbook Solutions Chapter 13 Nuclear Chemistry and Radioactivity Textbook Exercise Questions and Answers.

Maharashtra State Board 11th Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity

1. Choose the correct option.

Question A.
Identify nuclear fusion reaction
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 1
Answer:
Among the given options, reactions (i) and (ii) represent nuclear fusion reactions wherein lighter nuclei combine to form a heavy nucleus.

Question B.
The missing particle from the nuclear reaction is
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 2
Answer:
(A) \({ }_{15}^{30} \mathrm{P}\)

Question C.
\({ }_{27}^{60} \mathrm{CO}\) decays with half-life of 5.27 years to produce \({ }_{28}^{60} \mathrm{Ni}\). What is the decay constant for such radioactive disintegration ?
a. 0.132 y-1
b. 0.138
c. 29.6 y
d. 13.8%
Answer:
a. 0.132 y-1

Question D.
The radioactive isotope used in the treatment of Leukemia is
a. 60Co
b. 226Ra
c. 32P
d. 131I
Answer:
c. 32P

Question E.
The process by which nuclei having low masses are united to form nuclei with large masses is
a. chemical reaction
b. nuclear fission
c. nuclear fusion
d. chain reaction
Answer:
c. nuclear fusion

Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity

2. Explain

Question A.
On the basis of even-odd of protons and neutrons, what type of nuclides are most stable ?
Answer:

  • Nuclides with even number of protons (Z) and even number of neutrons (N) are most stable.
  • These nuclides tend to form proton-proton and neutron-neutron pairs.
  • This impart stability to the nucleus.

Question B.
Explain in brief, nuclear fission.
Answer:
i. Nuclear fission: It is a process which involves splitting of the heavy nucleus of an atom into two nearly equal fragments accompanied by release of the large amount of energy.
e.g. Nuclear fission of 235U

ii. When a uranium nucleus absorbs neutron, it breaks into two lighter fragments and releases energy (heat), more neutrons, and other radiation. This can be given as,
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 3

iii. Characteristics of nuclear fission reactions:

  • The mass of the fission products is less than the parent nucleus. A large amount of energy corresponding to the mass loss is released in each fission.
  • When one uranium 235 nucleus undergoes fission, three neutrons are emitted, which subsequently disintegrate three more uranium nuclei and thereby produce nine neutrons. Such a chain continues by itself.
  • In a very short time enormous amount of energy is liberated, which can be utilized for destructive or peaceful purposes.
  • Energy released per fission is approximately 200 MeV.

Note:

  • Each fission may lead to different products.
  • There is no unique way for fission of 235U that produces Ba and Kr. There are 400 ways for fission of 235U leading to 800 fission products.
  • Many of these fission products are radioactive which undergo spontaneous disintegrations giving rise to new elements in the periodic table.

Question C.
The nuclides with odd number of both protons and neutrons are the least stable. Why ?
Answer:

  • The nuclides with odd number of both protons and neutrons are the least stable because, odd number of protons and neutrons results in the presence of two unpaired nucleons.
  • These unpaired nucleons result in instability. Hence, such nuclides are the least stable.

Question D.
Referring the stabilty belt of stable nuclides, which nuclides are β and β+ emitters ? Why ?
Answer:

  • Beta decay occurs when an unstable nucleus emits a beta particle and energy. A beta particle is either an electron or a positron. An electron is a negatively charged particle, and a positron is a positively charged electron (or anti-electron).
  • When the beta particle is an electron, the decay is called beta-minus (β) decay. In beta-minus decay, a neutron breaks down to a proton and an electron, and the electron is emitted from the nucleus.
  • When the beta particle is a positron, the decay is called beta-plus (β+) decay. In beta-plus decay, a proton breaks down to a neutron and a positron, and the positron is emitted from the nucleus.
  • Thus, beta-minus decay occurs when a nucleus has too many neutrons relative to protons (i.e., N/Z > 1) and beta-plus decay occurs when a nucleus has too few neutrons relative to protons (i.e., N/Z < 1).
  • By referring the stability belt of stable nuclides, nuclides with N/Z > 1 are to the left of the stability zone. Such nuclides are beta-minus emitters as they become stable when a neutron converts to a proton.
  • Nuclides with N/Z < 1 are to the right of the stability zone. Such nuclides are beta-plus emitters as they become stable when a proton converts to a neutron.

Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity

Question E.
Explain with an example each nuclear transmutation and artifiacial radioactivity. What is the difference between them ?
Answer:
i. Nuclear transmutation: It involves transformation of a stable nucleus into another nucleus takes place which can be either stable or unstable.
ii. Artificial (induced) radioactivity: It is nuclear transmutation where the product nucleus is radioactive. The product nucleus decays spontaneously with emission of radiation and particles.
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 4
Step-I can be considered as nuclear transmutation as it produces a new nuclide \({ }_{7}^{13} \mathrm{~N}\).
However, the new nuclide is unstable (radioactive). Hence, step-I involves artificial (induced) radioactivity. Thus, in artificial transmutation, a stable element is collided with high speed particles to form another radioactive element.

Question F.
What is binding energy per nucleon ? Explain with the help of diagram how binding energy per nucleon affects nuclear stability ?
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 5
i. Binding energy per nucleon (\(\overline{\mathrm{B}}\)), for nucleus containing (A) nucleons with binding energy (B.E.) is given as,
\(\overline{\mathrm{B}}\) = B.E./A
ii. Mean binding energy per nucleon (\(\overline{\mathrm{B}}\)) for the most stable isotopes as a function of mass number is shown above. This plot leads to the following inferences:
a. Light nuclides: (A < 30)
The peaks with A values in multiples of 4. For example, \({ }_{2}^{4} \mathrm{He},{ }_{6}^{12} \mathrm{C},{ }_{8}^{16} \mathrm{O}\) are more stable.
b. Medium mass nuclides: (30 < A < 90)
\(\overline{\mathrm{B}}\) increases typically from 8 MeV for A = 16 to nearly 8.3 MeV for A between 28 and 32 and it remains nearly constant 8.5 MeV beyond this and shows a broad maximum. The nuclides falling on the maximum are most stable which turns possess high values. 56Fe with \(\overline{\mathrm{B}}\) value of 8.79 MeV is the most stable.
c. Heavy nuclides (A > 90)
\(\overline{\mathrm{B}}\) decreases from maximum 8.79 MeV to 7.7 MeV for A ≅ 210, 209Bi is the stable nuclide. Beyond this, all nuclides are radioactive (α-emitters).

Question G.
Explain with example α-decay.
Answer:
i. The emission of α-particle from the nuclei of an radioelement is called α-decay.
ii. The charge on an α-particle is +2 with a mass of 4 u.
It is identical with helium nucleus and hence an α-particle is designated as \({ }_{2}^{4} \mathrm{He}\).
iii. In the α-decay process, the parent nucleus \({ }_{\mathrm{z}}^{\mathrm{A}} \mathrm{X}\) emits an α-particle and produces daughter nucleus Y. The parent nucleus thus loses two protons (charge +2) and two neutrons. The total mass lost is 4 u. The daughter nucleus will therefore, have mass 4 units less and charge 2 units less than its parent.
iv. General equation for α-decay process can be given as:
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 6
In α-decay process of radium, radon (daughter nuclei) is formed with loses of two protons (charge +2) and two neutrons. The total mass lost is 4 u.
Thus, radon has a mass of 4 units less and charge 2 units less than its parent radium.

Question H.
Energy produced in nuclear fusion is much larger than that produced in nuclear fission. Why is it difficult to use fusion to produce energy ?
Answer:

  • Nuclear fusion involves the fusion of lighter nuclei to form a heavy nucleus which is accompanied by an enormous amount of energy (heat).
  • Fusion reaction requires extremely high temperature typically of the order of 108 K.

Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity

Question I.
How does N/Z ratio affect the nuclear stability ? Explain with a suitable diagram.
Answer:

  • When the graph of number of neutrons (N) against protons (Z) is drawn, and all the stable isotopes are plotted on it, there is quite a clear correlation between N and Z. This graph is shown in the adjacent figure.
  • A large number of elements have several stable isotopes and hence, the curve appears as a belt or zone called stability zone. All stable nuclides fall with this zone and the nuclei that are to the left or to the right of the stability zone are unstable and exhibit radioactivity. Below the belt, a straight line which represents the ratio N/Z to be nearly unity (i.e., N = Z) is shown.
  • For nuclei lighter than \({ }_{20}^{40} \mathrm{Ca}\), the straight line (N = Z) passes through the belt. The lighter nuclides are therefore stable (N/Z being 1).
  • The N/Z ratio for the stable nuclides heavier than calcium gives a curved appearance to the belt with gradual increase of N/Z (> 1). The heavier nuclides therefore, need more number of neutrons than protons to attain stability. The heavier nuclides with increasing number of protons render large coulombic repulsions. With increased number of neutrons, the protons within the nuclei get more separated, which renders them stable.
  • Thus, nuclear stability is linked to the number of nucleons (neutrons and protons). In general, the lighter stable nuclei have equal numbers of protons and neutrons while heavier stable nuclei have increasingly more neutrons than protons.

Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 7
[Note: Atoms with unstable nuclei are radioactive (exhibit radioactivity). To become more stable, the nuclei undergo radioactive decay.]

Question J.
You are given a very old sample of wood. How will you determine its age ?
Answer:
The age of the wood sample can be determined by radiocarbon dating as 14C becomes a part of a plant due to the photosynthesis reaction (i.e., absorption of [14CO2 + 12CO2]).
i. The activity (N) of given wood sample and that of fresh sample of live plant (N0) is measured, where, N0 denotes the activity of the given sample at the time of death.
ii. The age of the given wood sample. can be determined by applying following Formulae:
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 8
Note: The oldest rock found so far in Northern Canada is 3.96 billion years old.

3. Answer the following question

Question A.
Give example of mirror nuclei.
Answer:
Example of mirror nuclei: \({ }_{1}^{3} \mathrm{H}\) and \({ }_{2}^{3} \mathrm{He}\)

Question B.
Balance the nuclear reaction:
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 9
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 10

Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity

Question C.
Name the most stable nuclide known. Write two factors responsible for its stability.
Answer:
The most stable nuclide known is lead (\({ }_{82}^{208} \mathrm{~Pb}\)).
Two factors responsible for its stability are as follows:

  • It is a nuclide with even number of both protons (Z) and neutrons (N).
  • It has two magic numbers i.e., 82 (for protons) and 126 (for neutrons).

Question D.
Write relation between decay constant of a radioelement and its half life.
Answer:
Relation between decay constant of a radioelement and its half-life is given as, λ = \(\frac{0.693}{\mathrm{t}_{1 / 2}}\)
Where, λ = Decay constant, t1/2 = Half-life of a radioelement

Question E.
What is the difference between an α-particle and helium atom ?
Answer:

  • Helium atom is composed of 2 protons and 2 neutrons (or 1 neutron) along with 2 electrons in the outer shell.
  • On the other hand, α-particle constitutes 2 protons and 2 neutrons bound together to form a particle which is similar to helium (except presence of electrons).
  • Helium is one of the inert gas which is stable (duplet complete) whereas α-particle is unstable and highly reactive.

Question F.
Write one point that differentiates nuclear reations from chemical reactions.
Answer:
Chemical reactions:

  • Rearrangement of atoms by breaking and forming of chemical bonds.
  • Different isotopes of an element have same behaviour.

Nuclear reactions:

  • Elements or isotopes of one element are converted into another element in a nuclear reaction.
  • Isotopes of an element behave differently.

Question G.
Write pairs of isotones and one pair of mirror nuclei from the following :
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 11
Answer:
Isotones: i. \({ }_{5}^{10} \mathrm{~B} \text { and }{ }_{6}^{11} \mathrm{C}\)
ii. \({ }_{13}^{27} \mathrm{Al} \text { and }{ }_{14}^{28} \mathrm{~S}\)
Mirror nuclei: Since there are no isobars the given set of nuclides does not contain a pair of mirror nuclei.

Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity

Question H.
Derive the relationship between half life and decay constant of a radioelement.
Answer:
Equation for the decay constant is given as,
λ = \(\frac{2.303}{t} \log _{10} \frac{\mathrm{N}_{0}}{\mathrm{~N}}\) …(i)
Where, λ = Decay constant
N = Number of nuclei (atoms) present at time t
At t = 0, N = N0.
Hence, at t = t1/2, N = N0/2
Substitution of these values of N and t in equation (i) gives,
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 12

Question I.
Represent graphically log10 (activity /dps) versus t/s. What is its slope ?
Answer:
Equation for a decay constant (λ) is given as,
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 13
Hence, instead if log10N versus t, log10 \(\left(\frac{-\mathrm{d} \mathrm{N}}{\mathrm{dt}}\right)\) which is log10 (activity) is plotted.
The graph of log10 (activity/dps) versus t/s gives a straight line which can be represented as follows:
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 14

Question J.
Write two units of radioactivity. How are they interrelated ?
Answer:
The unit of radioactivity is curie (Ci).
1 Ci = 3.7 × 1010 dps
ii. Other unit of radioactivity is Becquerel (Bq).
1 Bq = 1 dps
Thus, 1 Ci = 3.7 × 1010 dps = 3.7 × 1010 Bq

Question K.
Half life of 24Na is 900 minutes. What is its decay constant?
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 15

Question L.
Decay constant of 197Hg is 0.017 h-1. What is its half life ?
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 16

Question M.
The total binding energy of 58Ni is 508 MeV. What is its binding energy per nucleon ?
Answer:
Given: B.E. of 58Ni = 508 MeV,
A = 58
To find: Binding energy per nucleon \(\bar{B}\)
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 17

Question N.
Atomic mass of \({ }_{16}^{32} \mathrm{~S}\) is 31.97 u. If masses of neutron and H atom are 1.0087 u and 1.0078 u respectively. What is the mass defect ?
Answer:
Given: m = 31.97 u, Z = 16, A = 32
mn = 1.0087 u
mH = 1.0078 u
To find: Δm
Formula: Δm = ZmH + (A – Z)mn – m
Calculation: Δm = ZmH + (A – Z)mn – m
= 16 × 1.0078 + (16 × 1.0087) – 31.97
= [16.1248 + 16.1392] – 31.97
= 0.294 u
Ans: The mass defect is 0.294 u.

Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity

Question O.
Write the fusion reactions occuring in the Sun and stars.
Answer:
Fusion reactions occurring in the Sun and stars are can be represented as,
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 18

Question P.
How many α and β – particles are emitted in the trasmutation
\({ }_{90}^{232} \mathrm{Th} \longrightarrow{ }_{82}^{208} \mathrm{~Pb}\)
Answer:
\({ }_{90}^{232} \mathrm{Th} \longrightarrow{ }_{82}^{208} \mathrm{~Pb}\)
The emission of one α-particle decreases the mass number by 4 whereas the emission of β-particles has no effect on mass number.
Net decrease in mass number = 232 – 208 = 24.
This decrease is only due to α-particles. Hence, number of α-particles emitted = \(\frac {24}{4}\) = 6
Now, the emission of one α-particle decrease the atomic number by 2 and one β-particle emission increases it by 1.
The net decrease in atomic number = 90 – 82 = 8
The emission of 6 α-particles causes decrease in atomic number by 12. However, the actual decrease is only 8. Thus, atomic number increases by 4. This increase is due to emission of 4 β-particles.
Thus, 6 α and 4 β-particles are emitted.

Question Q.
A produces B by α- emission. If B is in the group 16 of periodic table, what is the group of A ?
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 19
When α-emission occurs, atomic number decreases by 2 and atomic mass number by 4.
Thus, if ‘B’ belongs to group 16 of periodic table, that means outermost orbit will contain 6 electrons.
Thus, ‘A’ will have 8 electrons in its valence shell and it will belong to group 18 of the periodic table.

Question R.
Find the number of α and β- particles emitted in the process
\({ }_{86}^{222} \mathrm{Rn} \longrightarrow{ }_{84}^{214} \mathrm{PO}\)
Answer:
The emission of one α-particle decreases the mass number by 4 whereas the emission of β-particles has no effect on mass number.
Net decrease in mass number = 222 – 214 = 8. This decrease is only due to α-particle. Hence, number of α-particle emitted = 8/4 = 2
Now, the emission of one α-particle decreases the atomic number by 2 and one β-particle emission increases it by 1.
The net decrease in atomic number = 86 – 84 = 2
The emission of 2 α-particles causes decrease in atomic number by 4. However, the actual decrease is only 2. It means atomic number increases by 2. This increase is due to emission of 2 β-particles.
Thus, 2 α and 2 β-particles are emitted.

[Note: The above question is modified to include the final decay product so as to determine the number of α-particles and β-particles emitted in the process. Here, the final decay product is assumed to be Po-214.]

Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity

4. Solve the problems

Question A.
Half life of 18F is 110 minutes. What fraction of 18F sample decays in 20 minutes ?
Answer:
Given: t1/2 = 110 min
t = 20 min
To find: Fraction of 18F simple that decays
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 20
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 21
∴ Fraction of 18F sample that decays = 1 – 0.882 = 0.118
Ans: Fraction of 18F sample that decays in 20 minutes is 0.118.

Question B.
Half life of 35S is 87.8 d. What percentage of 35S sample remains after 180 d ?
Answer:
Given: t1/2 = 87.8 d,
N0 = 100,
t = 180 d
To find: % of 35S that remains after 180 days
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 22

Question C.
Half life 67Ga is 78 h. How long will it take to decay 12% of sample of Ga ?
Answer:
Given: t1/2 = 78 h,
N0 = 100,
N = 100 – 12 = 88
To find: t
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 23
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 24

Question D.
0.5 g Sample of 201Tl decays to 0.0788 g in 8 days. What is its half life ?
Answer:
Given: N0 = 0.5 g,
N = 0.0788 g,
t = 8 days
To find: t1/2
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 25

Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity

Question E.
65% of 111In sample decays in 4.2 d. What is its half life ?
Answer:
Given: N0 = 100,
N = 100 – 65 = 35,
t = 4.2d
To find: t1/2
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 26
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 27

Question F.
Calculate the binding energy per nucleon of \({ }_{36}^{84} \mathrm{Kr}\) whose atomic mass is 83.913 u. (Mass of neutron is 1.0087 u and that of H atom is 1.0078 u).
Answer:
Given: A = 84, Z = 36,
m = 83.913 u
mn = 1.0087 u
mH = 1.0078 u
To find: Binding energy per nucleon \((\bar{B})\)
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 28

Question G.
Calculate the energy in Mev released in the nuclear reaction
\({ }_{77}^{174} \mathrm{Ir} \longrightarrow{ }_{75}^{170} \mathrm{Re}+{ }_{2}^{4} \mathrm{He}\)
Atomic masses : Ir = 173.97 u,
Re = 169.96 u and
He = 4.0026 u
Answer:
Given: mIr= 173.97 u
mRe = 169.96 u
mHe = 4.0026 u
To find: Energy released
Formulae: i. Δm = (mass of 174Ir) – (mass of 170Re + mass of 4He)
ii. E = Δm × 931.4 MeV
Calculation:i. Δm = (mass of 174Ir) – (mass of 170Re + mass of 4He)
= 173.97 – (169.96 + 4.0026)
= 7.4 × 10-3 u
ii. E = Δm × 931.4
= 7.4 × 10-3 × 931.4
= 6.89236 MeV ≈ 6.892 MeV
Ans: The energy released in given nuclear reaction is 6.892 MeV.

Question H.
A 3/4 of the original amount of radioisotope decays in 60 minutes. What is its half life ?
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 29

Question I.
How many – particles are emitted by 0.1 g of 226Ra in one year?
Answer:
Given: t = 1 y,
Amount of sample = 0.1 g
To find: Number of particles emitted
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 30
Activity = \(\frac{-\mathrm{d} \mathrm{N}}{\mathrm{dt}}\) = λN
= 4.28 × 10-4 × 2.665 × 1020 atoms
= 1.141 × 1017 particles/year
Ans: Particles emitted by 0.1 g of 226Ra in one year = 1.141 × 1017 particles/year.
[Note: The half-life of radium is 1620 years. In order to apply appropriate textual concept, we have used this value in calculation.]

Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity

Question J.
A sample of 32P initially shows activity of one Curie. After 303 days the activity falls to 1.5× 104 dps. What is the half life of 32P ?
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 31

Question K.
Half life of radon is 3.82 d. By what time would 99.9 % of radon will be decayed.
Answer:
Given: t1/2 = 3.82 d,
N0 = 100
N = 100 – 99.9 = 0.1
To find: t
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 32

Question L.
It has been found that the Sun’s mass loss is 4.34 × 109 kg per second. How much energy per second would be radiated into space by the Sun ?
Answer:
Given: Sun’s mass loss = 4.34 × 109 kg per second
To find: Energy radiated per second into space by Sun
calculation: Δm = 4.34 × 109 kg per second
Now, 1.66 × 10-27 kg = 1u
∴ Δm = \(\frac{4.34 \times 10^{9}}{1.66 \times 10^{-27}}\) u per second
= 2.614 × 1036 u per second
Now, 1 u = 931.4 MeV
2.614 × 1036 u per second = 2.614 × 1036 × 931.4
= 2.435 × 1039 MeV/s
Now, 1 MeV = 1.6022 × 10-19 J and 1 eV = 1 × 10-6 MeV
1 MeV = 1.6022 × 10-13 J
= 1.6022 × 10-16 LJ
E = 2.435 × 1039 MeV/s × 1.6022 × 10-16 kJ/MeV
= 3.901 × 1023 kJ/s
Ans: Energy radiated per second into space by Sun is 3.901 × 1023 kJ/s.

Question M.
A sample of old wood shows 7.0 dps/g. If the fresh sample of tree shows 16.0 dps/g, How old is the given sample of wood ? Half life of 14C 5730 y.
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 33

Activity :

1. Discuss five applications of radioactivity for peaceful purpose.
Answer:

  • Development in earth sciences: Like to understand various geographical changes occurring on earth.
  • Development in space technology: To study nuclear reactions in stars which may lead to new discoveries.
  • Development in medical sciences: Diagnosis and treatment of various diseases.
  • Development in industries: As a potent source of electricity or a power generator.
  • Development in agriculture: To study or monitor changes in soil like uptake of nutrients from the soil etc.

[Note: Students can use above points are reference to discuss topic in class].

2. Organize a trip to Bhabha Atomic Reasearch Centre, Mumbai to learn about nuclear reactor. This will have to be organized through your college.
Answer:
Students are expected to visit the place to understand more about nuclear reactors.

Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity

11th Chemistry Digest Chapter 13 Nuclear Chemistry and Radioactivity Intext Questions and Answers

Do you know? (Textbook Page no. 190)

Question 1.
How small is the nucleus in comparison to the rest of the atom?
Answer:
The radius of nucleus is of the order of 10-15 m whereas that of the outer sphere is of the order of 10-10 m. The size of outer sphere, is 105 times larger than the nucleus i.e., if we consider the atom of size of football stadium then its nucleus will be the size of a pea.

(Textbook Page no. 191)

Question 1.
Identify the following nuclides as: isotopes, isobars and isotones.
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 34
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 35

(Textbook Page No. 194)

Question 1.
i. What do you understand by the term rate of decay and give its mathematical expression.
ii. Why is minus sign required in the expression of decay rate?
Answer:
i. Rate of decay of a radioelement denotes the number of nuclei of its atoms which decay in unit time. It is also called activity of radioelement.
Rate of decay at any time t can be expressed as follows:
Rate of decay (activity) = \(-\frac{\mathrm{d} \mathrm{N}}{\mathrm{dt}}\)
where, dN is the number of nuclei that decay within time interval dt.
ii. Minus sign in the expression indicates that the number of nuclei decreases with time. Therefore, dN is a negative quantity. But, the rate of decay is a positive quantity. The negative sign is introduced in the rate expression to make the rate positive.

Try this. (Textbook Page No. 194)

Question 1.
Prepare a chart of comparative properties of the above three types of radiations.
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 36

Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity

Just think (Textbook Page No. 195)

Question 1.
Does half-life increase, decrease or remain constant? Explain.
Answer:
Half-life of a particular radioelement remains constant at a given instant. A radioactive half-life refers to the amount of time it takes for half of the original isotope to decay. It is related to decay constant by the expression: t1/2 = 0.693 / λ

From the expression, it is evident that half-life of a radio isotope is dependent only on the decay constant and is independent of the initial amount of the radio isotope. Each successive half-life in which the amount of radio isotope decreases to its half value is the same.
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 37
Thus, half-life remains constant.

Try this (Textbook Page No. 198)

Question 1.
24Mg and 27Al, both undergo (α, n) reactions and the products are radioactive. These emit β particles having positive charge (called positrons). Write balanced nuclear reactions in both.
Answer:
Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity 38

Do you know? (Textbook Page No. 198)

Question 1.
What is the critical mass of 235U?
Answer:
i. The critical mass is the minimum mass of uranium-235 required to achieve a self-sustaining fission chain reaction under stated conditions.
ii. The chain reaction in fission of U-235 becomes self-sustaining when the critical mass of uranium-235 is about 50 kilograms.

Maharashtra Board Class 11 Chemistry Solutions Chapter 13 Nuclear Chemistry and Radioactivity

Activity (Textbook Page No. 200)

Question 1.
You have learnt in Std. 9th, medical, industrial and agricultural applications of radioisotopes. Write at least two applications each.
Answer:
i. The uses of radioactive isotopes in the field of medicine:
a. Polycythaemia: The red blood cell count increases in the disease polycythaemia. Phosphorus-32 is used in its treatment.
b. Bone cancer: Strontium-89, strontium-90, samarium-153 and radium-223 are used in the treatment of bone cancer.

ii. The uses of radioactive isotopes in the industrial field:
a. Luminescent paint and radioluminescence: The radioactive substances radium, promethium, tritium with some phosphorus are used to make certain objects visible in the dark.
e.g. Hands of a clock, krypton-85 is used in HID (High Intensity Discharge) lamps.
b. Use in ceramic articles:
1. Luminous colours are used to decorate ceramic tiles, utensils, plates, etc.
2. Uranium oxide was earlier used to colour ceramics.

iii. The uses of radioactive isotopes in the agriculture field:
a. The genes and chromosomes that give seeds its properties like fast growth, higher productivity, etc., can be modified by means of radiation.
b. Onions and potatoes are irradiated with gamma rays from cobalt-60 to prevent their sprouting.

Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium

Balbharti Maharashtra State Board 11th Chemistry Textbook Solutions Chapter 12 Chemical Equilibrium Textbook Exercise Questions and Answers.

Maharashtra State Board 11th Chemistry Solutions Chapter 12 Chemical Equilibrium

1. Choose the correct option

Question A.
The equilibrium, H2O(l) ⇌ H+(aq) + OH(aq) is
a. dynamic
b. static
c. physical
d. mechanical
Answer:
a. dynamic

Question B.
For the equilibrium, A ⇌ 2B + Heat, the number of ‘A’ molecules increases if
a. volume is increased
b. temperature is increased
c. catalyst is added
d. concentration of B is decreased
Answer:
b. temperature is increased

Question C.
For the equilibrium Cl2(g) + 2NO(g) ⇌ 2NOCl(g) the concentration of NOCl will increase if the equilibrium is disturbed by ………..
a. adding Cl2
b. removing NO
c. adding NOCl
d. removal of Cl2
Answer:
a. adding Cl2

Question D.
The relation between Kc and Kp for the reaction A(g) + B(g) ⇌ 2C(g) + D(g) is
a. Kc = Kp/RT
b. Kp = Kc2
c. Kc = \(\frac{1}{\sqrt{\mathrm{Kp}}}\)
d. Kp/Kc = 1
Answer:
a. Kc = Kp/RT

Question E.
When volume of the equilibrium reaction C(s) + H2O(g) ⇌ CO(g) + H2(g) is increased at constant temperature the equilibrium will
a. shift from left to right
b. shift from right to left
c. be unaltered
d. can not be predicted
Answer:
a. shift from left to right

Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium

2. Answer the following

Question A.
State Law of Mass action.
Answer:
Law of mass action: The law of mass action states that the rate of a chemical reaction at each instant is proportional to the product of concentrations of all the reactants.

Question B.
Write an expression for equilibrium constant with respect to concerntration.
Answer:
For a reversible chemical reaction at equilibrium, aA + bB ⇌ cD + dD
Equilibrium constant (Kc) = \(\frac{[C]^{\mathrm{c}}[\mathrm{D}]^{\mathrm{d}}}{[\mathrm{A}]^{\mathrm{a}}[\mathrm{B}]^{\mathrm{b}}}\)

Question C.
Derive mathematically value of Kp for A(g) + B(g) ⇌ C(g) + D(g).
Answer:
When the concentrations of reactants and products in gaseous reactions are expressed in terms of their partial pressure, then the equilibrium constant is represented as Kp.
∴ For the reaction,
A(g)+ B(g) ⇌ C(g) + D(g)
the equilibrium constant (KC) can be expressed using partial pressure as: Kp = \(\frac{P_{C} \times P_{D}}{P_{A} \times P_{B}}\)
Where PA, PB, PC and PD are equilibrium partial pressures of A, B, C and D respectively.

Question D.
Write expressions of KC for following chemical reactions
i. 2SO2(g) + O2(g) ⇌ 2SO3(g)
ii. N2O4(g) ⇌ 2NO2(g)
Answer:
i. 2SO2(g) + O2(g) ⇌ 2SO3(g)
Kc = \(\frac{\left[\mathrm{SO}_{3}\right]^{2}}{\left[\mathrm{SO}_{2}\right]^{2}\left[\mathrm{O}_{2}\right]}\)

ii. N2O4(g) ⇌ 2NO2(g)
Kc = \(\frac{\left[\mathrm{NO}_{2}\right]^{2}}{\left[\mathrm{~N}_{2} \mathrm{O}_{4}\right]}\)

Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium

Question E.
Mention various applications of equilibrium constant.
Answer:
Various applications of equilibrium constant:

  • Prediction of the direction of the reaction
  • To know the extent of the reaction
  • To calculate equilibrium concentrations
  • Link between chemical equilibrium and chemical kinetics

Question F.
How does the change of pressure affect the value of equilibrium constant ?
Answer:
The change of pressure does not affect the value of equilibrium constant.

Question J.
Differentiate irreversible and reversible reaction.
Answer:
Irreversible reaction:

  1. Products are not converted back to reactants.
  2. Reaction stops completely and almost goes to completion.
  3. It can be carried out in an open or closed vessel.
  4. It takes place only in one direction. It is represented by →
  5. e.g. C(s) + O2(g) → CO2(g)

Reversible reaction:

  1. Products arc converted back to reactants.
  2. Reaction appears to have stopped but does not undergo completion.
  3. It is generally carried out in a closed vessel.
  4. It takes place in both directions. It is represented by ⇌
  5. e.g. N2(g) + O2(g) ⇌ 2NO(g)

Question K.
Write suitable conditions of concentration, temperature and pressure used during manufacture of ammonia by Haber process.
Answer:
i. Concentration: Addition of H2 or N2 both favours forward reaction. This increases the yield of NH3.
ii. Temperature: The formation NH3 is exothermic. Hence, low temperature should favour the formation of NH3. However, at low temperatures, the rate of reaction is small. At high temperatures, the reaction occurs rapidly but decomposition of NH3 occurs. Hence, optimum temperature of about 773 K is used.
iii. Pressure: The forward reaction is favoured with high pressure as it proceeds with decrease in number of moles. At high pressure, the catalyst becomes inefficient. Therefore, optimum pressure needs to be used. The optimum pressure is about 250 atm.

Question L.
Relate the terms reversible reactions and dynamic equilibrium.
Answer:

  • Reversible reactions are the reactions which do not go to completion and occur in both the directions simultaneously.
  • If such a reaction is allowed to take place for a long time, so that the concentrations of the reactants and products do not vary with time, then the reaction will attain equilibrium.
  • Since, both the forward and backward reactions continue to take place in opposite directions in the same speed, the equilibrium achieved is dynamic in nature.

Thus, if the reaction is not reversible then it cannot attain dynamic equilibrium.

Question M.
For the equilibrium.
\(\mathrm{BaSO}_{4(\mathrm{~s})} \rightleftharpoons \mathrm{Ba}_{(\mathrm{aq})}^{2+}+\mathrm{SO}_{4(\mathrm{aq})}^{2-}\)
state the effect of
a. Addition of Ba2+ ion.
b. Removal of SO42- ion
c. Addition of BaSO4(s)
on the equilibrium.
Answer:
a. Addition of Ba2+ ion will favour the reverse reaction, (that is, equilibrium shifts from right to left). This increases the amount of BaSO4.
b. Removal of \(\mathrm{SO}_{4}^{2-}\) ion will favour the forward reaction, (that is, equilibrium shifts from left to right). This decreases the amount of BaSO4.
c. Addition of BaSO4(s) will not affect the equilibrium as the equilibrium constant expression does not include pure solids.

Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium

3. Explain :

Question A.
Dynamic nature of chemical equilibrium with suitable example.
Answer:
Dynamic nature of chemical equilibrium:
i. Consider a chemical reaction: A ⇌ B.
Kc = [B]/[A]
At equilibrium, the ratio of concentration of the product to that of the concentration of the reactant is constant and this is equal to Kc.

ii. At this stage reaction takes place in both the directions with same speed although the reaction appears to have stopped. Thus, the chemical equilibrium is dynamic in nature. Dynamic means moving and at a microscopic level, the system is in motion.

iii. For example, in the reaction between H2 and I2 to form HI, the colour of the reaction mixture becomes constant because the concentrations of H2, I2 and HI become constant at equilibrium.
H2 + I2 ⇌ 2HI
Thus, when equilibrium is reached, the reaction appears to have stopped. However, this is not the case. The reaction is still going on in the forward and backward direction but the rate of forward reaction is equal to the rate of backward reaction. Hence, chemical equilibrium is dynamic in nature and not static.

Question B.
Relation between Kc and Kp.
Answer:
Consider a general reversible reaction:
aA(g) + bB(g) ⇌ cC(g) + dD(g)
The equilibrium constant (Kp) in terms of partial pressure is given by equation:
Kp = \(\frac{\left(P_{C}\right)^{c}\left(P_{D}\right)^{d}}{\left(P_{A}\right)^{a}\left(P_{B}\right)^{b}}\) …………(1)
For a mixture of ideal gases, the partial pressure of each component is directly proportional to its concentration at constant temperature.
For component A,
PAV = nART
PA = \(\frac{\mathrm{n}_{\mathrm{A}}}{\mathrm{V}}\) × RT
\(\frac{\mathrm{n}_{\mathrm{A}}}{\mathrm{V}}\) is molar concentration of A in mol dm-3 V
∴ PA = [A]RT where, [A] = \(\frac{\mathrm{n}_{\mathrm{A}}}{\mathrm{V}}\)
Similarly, for other components, PB = [B]RT, PC = [C]RT, PD = [D]RT
Now substituting equations for PA, PB, PC, PD in equation (1), we get
Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium 1
where Δn = (number of moles of gaseous products) – (number of moles of gaseous reactants) in the balanced chemical equation.
R = 0.08206 L atm K-1 mol-1
[Note: While calculating the value of Kp, pressure should be expressed in bar, because standard state of pressure is 1 bar. 1 pascal (Pa) = 1 N m-2 and 1 bar = 105 Pa]

Question C.
State and explain Le Chatelier’s principle with reference to
1. change in temperature
2. change in concerntration.
Answer:
Statement: When a system at equilibrium is subjected to a change in any of the factors determining the equilibrium conditions of a system, system will respond in such a way as to minimize the effect of change.

1. Change in temperature:

  • Consider the equilibrium reaction,
    PCl5(g) ⇌ PCl3(g) + Cl2(g) + 92.5 kJ
  • The forward reaction is exothermic. According to Le Chatelier’s principle an increase in temperature shifts the position of equilibrium to the left.
  • The reverse reaction is endothermic. An endothermic reaction consumes heat. Therefore, the equilibrium must shift in the reverse direction to use up the added heat (heat energy converted to chemical energy).
  • Thus, an increase in temperature favours formation of PCl5 while a decrease in temperature favours decomposition of PCl5.

2. Change in concentration:

  • Consider reversible reaction representing production of ammonia (NH3).
    N2(g) + 3H2(g) ⇌ 2NH3(g) + Heat
  • According to Le Chatelier’s principle, when H2 or N2 is added to equilibrium, the effect of addition of H2 or N2 or is reduced by shifting the equilibrium from left to right so that the added N2 or H2 is consumed.
  • The forward reaction occurs to a large extent than the reverse reaction until the new equilibrium is established. As a result, the yield of NH3 is increases.
  • In general, if the concentration of one of the species in equilibrium mixture is increased, the position of equilibrium shifts in the opposite so as to reduce the concentration of this species. However, the equilibrium constant remains unchanged.

Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium

Question D.
a. Reversible reaction
b. Rate of reaction
Answer:
a. Reversible reaction:
i. Reactions which do not go to completion and occur in both the directions simultaneously are called reversible reactions.
ii. Reversible reactions proceed in both directions. The direction from reactants to products is the forward reaction, whereas the opposite reaction from products to reactants is called the reverse or backward reaction.
iii. A reversible reaction is denoted by drawing in between the reactants and product a double arrow, one pointing in the forward direction and other in the reverse direction (⇌ or ⇄).
ii. At high temperature in an open container, the CO2 gas formed will escape away. Therefore, it is not possible to obtain back
e.g. a. H2(g) + I2(g) ⇌ 2HI(g)
b. CH3COOH(aq) + H2O(l) ⇌ CH3COO(aq) + H3O+(aq)

b. Rate of reaction:
Rate of a chemical reaction:
i. The rate of a chemical reaction can be determined by measuring the extent to which the concentration of a reactant decreases in the given time interval, or extent to which the concentration of a product increases in the given time interval.
ii. Mathematically, the rate of reaction is expressed as:
Rate = \(-\frac{\mathrm{d}[\text { Reactant }]}{\mathrm{dT}}=\frac{\mathrm{d}[\text { Product }]}{\mathrm{dT}}\)
where, d[reactant] and d[product] are the small decrease or increase in concentration during the small time interval dT.

Question E.
What is the effect of adding chloride on the position of the equilibrium ?
AgCl(s) ⇌ Ag+(aq) + Cl(aq)
Answer:
Addition of Cl ion will favour the reverse reaction, (that is, equilibrium shift from right to left) This increases the amount of AgCl.

11th Chemistry Digest Chapter 12 Chemical Equilibrium Intext Questions and Answers

Can you recall? (Textbook Page No. 174)

Question 1.
What are the types of the following changes?
Natural waterfall, spreading of smoke from burning incense stick, diffusion of fragrance of flowers.
Answer: Natural waterfall, spreading of smoke from burning incense stick and diffusion of fragrance of flowers are irreversible physical changes.

Try this. (Textbook Page No. 174)

Question 1.
Dissolve 4 g cobalt chloride in 40 mL water. It forms a reddish pink solution. Add 60 mL concentrated HCl to this. It will turn blue. Take 5 mL of this solution in a test tube and place it in a beaker containing ice water mixture. The colour of solution will become pink. Place the same test tube in a beaker containing water at 90 °C. The colour of the solution turns blue.
Answer:
Inference: The colour change of the solution from pink to blue is caused by the chemical reaction. On changing the temperature, the direction of the reaction reverses. This indicates that the chemical reaction is reversible. This activity is an example of a reversible chemical reaction.
The reaction can be written as:
Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium 2
Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium 3

Can you tell? (Textbook Page No. 174)

Question 1.
What does violet colour of the solution in the activity mentioned in Q.2 indicate?
Answer:
In the reaction, the reactant \(\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}^{2+}\) is pink in colour and the product \(\mathrm{CoCl}_{4}^{2-}\) is blue in colour. When the solution contains both the reactant and product, the resulting solution will appear violet. This indicates that the reaction has attained equilibrium (that is, the reaction proceeds in both the direction with equal rates and is a reversible reaction).

Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium

(Textbook Page No. 174)

Question 1.
Calcium earbonate when heated strongly, decomposes to form calcium oxide and carbon dioxide.
i. If this reaction is carried out in a closed container, what will we observe?
ii. Consider this reaction occurring in an open system or container, what will happen? Can we obtain back calcium carbonate?
Answer:
At high temperature in a closed container, we will find that after certain time, some calcium carbonate is present. If we continue the experiment over a longer period of time at the same temperature, the concentrations of calcium carbonate, calcium oxide and carbon dioxide remain unchanged. The reaction thus appears to have stopped and the system has attained the equilibrium. Actually, the reaction does not stop but proceeds in both the directions with equal rates. In other words, calcium carbonate decomposes to give calcium oxide and carbon dioxide at a particular rate. Exactly at the same rate the calcium oxide and carbon dioxide recombine and form calcium carbonate. Thus, in closed container, reversible reaction occurs.
Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium 4
ii. At high temperature in an open container, the CO2 gas formed will escape away. Therefore, it is not possible to obtain back calcium carbonate. Thus, in an open container, irreversible reaction occurs.
\(\mathrm{CaCO}_{3(\mathrm{~s})} \stackrel{\text { Heat }}{\longrightarrow} \mathrm{CaO}_{(\mathrm{s})}+\mathrm{CO}_{2(\mathrm{~g})}\)

Internet my friend (Textbook Page No. 175)

Question 1.
i. Equilibrium existing in the formation of oxyhaemoglobin in human body
ii. Refrigeration system in equilibrium
Answer:
i. Equilibrium existing in the formation of oxyhaemoglobin in human body:
Oxygen is transported in the body with the assistance of red blood cells. The red blood cells contain a pigment called haemoglobin. Each haemoglobin molecule binds four oxygen molecules to form oxyhaemoglobin. Thus, the oxygen molecules are carried to individual cells in the body tissue where they are released.

The binding of oxygen to haemoglobin is a reversible reaction.
Hb + 4O2 ⇌ Hb.4O2
When the oxygen concentration is high (in the lungs), haemoglobin and oxygen combine to form oxyhaemoglobin and the reaction achieves equilibrium. But, when the oxygen concentration is low (in the body tissue), the reverse reaction occurs, that is, oxyhaemoglobin dissociates to haemoglobin and oxygen.
Thus, an equilibrium exists in the formation of oxyhaemoglobin in the human body.

ii. Refrigeration system in equilibrium:
a. Refrigeration system works on the principle of thermal equilibrium i.e., when a cold body comes in contact with a hot body then the heat flows from hot body to cold body until both the bodies attain the same temperature.
b. In the same way, a liquid (called as refrigerant) passes through the various compartments in the refrigerator and eventually lowers the temperature inside the refrigerator. This cycle is briefly described below:
Refrigerant flows through the compressor, which raises the pressure of the refrigerant. Next, the refrigerant flows through the condenser, where it condenses from vapor form to liquid form, giving off heat in the process. The heat given off is what j makes the condenser “hot to the touch.” After the condenser, the refrigerant goes through the expansion valve, where it experiences a pressure drop. Finally, the refrigerant goes to the evaporator. The refrigerant draws heat from the evaporator which causes the refrigerant to vaporize. The evaporator draws heat from the region that is to be cooled. The vaporized refrigerant goes back to the compressor to restart the cycle. In each of the heat transfer process, equilibrium is achieved (that is, heat given off is equivalent to the cooling achieved.)
Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium 5

[Note: Students are expected to collect additional information about equilibrium existing in the formation of oxyhaemoglobin in human body’ and ‘refrigeration system in equilibrium on their own.]

Try this. (Textbook Page No. 176)

Question 1.
i. Place some iodine crystals in a closed vessel. Observe the change in colour intensity in it.
ii. What do you see in the flask after some time?
Answer:
i. The vessel gets slowly filled up with violet coloured vapour of iodine. After a certain time, the intensity of violet colour becomes stable.
ii. After sometime, both solid iodine and iodine vapour are present in the closed vessel. Iodine crystals will be seen deposited near the mouth of the flask and violet coloured vapour will be filled in the entire flask. It means solid iodine sublimes to give iodine vapour and the iodine vapour condenses to form solid iodine. The stable intensity of the colour indicates a state of equilibrium between solid and vapour iodine.
Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium 6
Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium 7

Try this. (Textbook Page No. 176)

Question 1.
i. Dissolve a given amount of sugar in minimum amount of water at room temperature.
ii. Increase the temperature and dissolve more amount of sugar in the same amount of water to make a thick sugar syrup solution.
iii. Cool the syrup to the room temperature.
Answer:
Observation: Sugar crystals separate out.
Inference: The sugar syrup solution prepared is a saturated solution. Therefore, additional amount of sugar cannot be dissolved in it at room temperature.
In a saturated solution, there exists dynamic equilibrium between the solute molecules in the solid state and in dissolved state.
Sugar(aq) ⇌ Sugar(s)
The rate of dissolution of sugar = The rate of crystallization of sugar.
However, when it is heated, additional amount of sugar can be dissolved in it. But when such a thick sugar syrup is cooled again to room temperature, sugar crystals separate out.

Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium

Do you know? (Textbook Page No. 177)

Question 1.
What is a saturated solution?
Answer:
A saturated solution is the solution when additional solute cannot be dissolved in it at the given temperature. The concentration of solute in a saturated solution depends on temperature.

Observe and discuss. (Textbook Page No. 177)

Question 1.
Colourless N2O4 taken in a closed flask is converted to NO2 (a reddish brown gas).
Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium 8
Answer:
Observation: Initially, the colourless gas (N2O4) turns to reddish brown (NO2) gas. After sometime, the colour becomes lighter indicating the formation of N2O4 from NO2.
Inference: This indicates that the reaction is reversible. In such reaction, the reactants combine to form the products and the products combine to give the reactants. As soon as the forward reaction produces any NO2, the reverse reaction begins and NO2, starts combining back to N2O4. At equilibrium, the concentrations of N2O4 and NO2 remain unchanged and do not vary with time, because the rate of formation of NO2 is equal to the rate of formation of N2O4.
Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium 9

[Note: For any reversible reaction in a closed system whenever the opposing reactions (forward and reaction) are occurring at different rates, the forward reaction will gradually become slower and the reverse reaction will become faster. Finally, the rates become equal and equilibrium is established.]

Discuss (Textbook Page No. 177)

i. Consider the following dissociation reaction:
Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium 10
The reaction is carried out in a closed vessel starting with hydrogen iodide.
ii. Now, let us start with hydrogen and iodine vapour in a closed container at a certain temperature.
H2(g) + I2(g) ⇌ 2HI(g)
Answer:
i. Starting with hydrogen iodide:
Observations:
a. At first, there is an increase in the intensity of violet colour.
b. After certain time, the increase in the intensity of violet colour stops.
c. When contents in a closed vessel are analyzed at this stage, it is observed that reaction mixture contains the hydrogen iodide, hydrogen and iodine with their concentrations being constant over time.
Inference:
The rate of decomposition of HI becomes equal to the rate of combination of H2 and I2. At equilibrium, no net change is observed and both reactions continue to occur at equal rates.
Thus, the reaction represents chemical equilibrium.

ii. Starting with hydrogen and iodine:
Observations:
a. At first, there is a decrease in the intensity of violet colour.
b. After certain time, the decrease in the intensity of violet colour stops.
c. When contents in a closed vessel are analyzed at this stage, it is observed that reaction mixture contains hydrogen, iodine and hydrogen iodide with their concentrations being constant over time.
Inference:
The rate of combination of H2 and I2 becomes equal to the rate of decomposition of HI. The reaction attains chemical equilibrium.

Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium

Can you recall? (Textbook Page No. 180)

Question 1.
Write ideal gas equation with significance of each term involved in it.
Answer:
Ideal gas equation is PV = nRT.
where, P = Pressure of the gas
V = Volume of the gas
n = Number of moles of the gas
R = universal gas constant
T = Absolute temperature of the gas

Just think. (Textbook page no. 181)

Question 1.
Two processes, which are taking place in opposite directions are in equilibrium. How to write equilibrium constant expersions for heterogeneous equilibrium?
Answer:
Equilibrium in a system having more than one phase is called heterogeneous equilibrium.
If ethanol is placed in a conical flask, liquid-vapour equilibrium is established.
C2H5OH(l) ⇌ C2H5OH(g)
For a given temperature,
Kc = \(\frac{\left[\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}_{(g)}\right]}{\left[\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}_{(l)}\right]}\)
But [C2H5OH(l)] = 1
∴ Kc = [C2H5OH(g)]
Thus, at any given temperature, density is constant irrespective of the amount of liquid, and the term in the denominator is also constant.
ii. similarly, consider I2(g) ⇌ I2(g)
Kc = [I2(g)]
iii. Thus, the expression for equilibrium constant does not contain the concentration of pure solids and pure liquids. That is because for any pure liquid and solid, the concentration is simply its density and this will not change no matter how much solid or liquid is used. Hence, the expression for heterogeneous equilibrium only uses the concentration of gases and dissolved substances (aq.). Solids are pure substances with unchanging concentrations and thus equilibria including solids are simplified.

Can you tell? (Textbook Page No. 183)

Question 1.
Comment on the extent to which the forward reaction will proceed, from the magnitude of the equilibrium constant for the following reactions:
i. H2(g) + I2(g) ⇌ 2HI(g), Kc = 20 at 550 K
ii. H2(g) + Cl2(g) ⇌ 2HCl(g), Kc = 1018 at 550 K
Answer:
i. For the reaction, Kc = 20 at 550 K
If the value of Kc is the range of 10-3 to 103, the forward and reverse proceed to equal extents.
Hence, the given reaction will form appreciable concentrations of both reactants and the product at equilibrium.

ii. For the reaction, Kc = 1018 at 550 K
If the value of Kc >>> 103, forward reaction is favoured.
Hence, the given reaction will proceed in the forward direction and will nearly go to completion.

Use your brain power (Textbook Page No. 183)

Question 1.
The value of Kc for the dissociation reaction:
H2(g) ⇌ 2H(g) is 1.2 × 10-42 at 500 K.
Does the equilibrium mixture contain mainly hydrogen molecules or hydrogen atoms?
Answer:
When the value of Kc is very low (that is, Kc < 10-3), then at equilibrium, only a small fraction of the reactants is converted into products.
For the given reaction, Kc <<< 103 at 500 K.
Hence, the equilibrium mixture contains mainly hydrogen molecules.

Maharashtra Board Class 11 Chemistry Solutions Chapter 12 Chemical Equilibrium

Internet my friend (Textbook Page No. 183)

Question 1.
Collect information about chemical equilibrium.
Answer:
https://www.chemguide.co.uk/physical/equilibria/introduction.html
[Note: Students can use the above link as reference and collect information about chemical equilibrium.]

Can you tell? (Textbook Page No. 188)

i. If NH3 is added to the equilibrium system (Haber process), in which direction will the equilibrium shift to consume added NH3 to reduce the effect of stress?
ii. In this process, out of the reactions (reverse and forward reaction), which reaction will occur to a greater extent?
iii. What will be the effect on yield of NH3?
Answer:
i. If NH3 is added to the equilibrium system, the equilibrium will shift from right to left to consume added NH3 to reduce the effect of stress.
ii. If NH3 is added to the equilibrium system, then reverse reaction will occur to greater extent.
iii. If NH3 is added to the equilibrium system, the equilibrium will shift in reverse direction and the yield of NH3 will decrease.

Internet my friend (Textbook Page No. 188)

i. Collect information about Haber process in chemical equilibrium.
ii. Youtube.Freescienceslessons: The Haber process
Answer:
i. https://www.chemguide.co.uk/physical/equilibria/haber.html
[Note: Students can use the above link as reference and collect information about chemical equilibrium involved in Haber process.]
ii. Students are expected to refer ‘The Haber process ’ on YouTube channel ‘Freescienceslessons’

Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids

Balbharti Maharashtra State Board 11th Chemistry Textbook Solutions Chapter 11 Adsorption and Colloids Textbook Exercise Questions and Answers.

Maharashtra State Board 11th Chemistry Solutions Chapter 11 Adsorption and Colloids

1. Choose the correct option.

Question A.
The size of colloidal particles lies between
a. 10-10 m and 10-9 m
b. 10-9 m and 10-6 m
c. 10-6 m and 10-4 m
d. 10-5 m and 10-2 m
Answer:
b. 10-9 m and 10-6 m

Question B.
Gum in water is an example of
a. true solution
b. suspension
c. lyophilic sol
d. lyophobic sol
Answer:
c. lyophilic sol

Question C.
In Haber process of production of ammonia K2O is used as
a. catalyst
b. inhibitor
c. promotor
d. adsorbate
Answer:
c. promotor

Question D.
Fruit Jam is an example of-
a. sol
b. gel
c. emulsion
d. true solution
Answer:
b. gel

Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids

2. Answer in one sentence :

Question A.
Name type of adsorption in which van der Waals focres are present.
Answer:
Physical adsorption or physisorption.

Question B.
Name type of adsorption in which compound is formed.
Answer:
Chemical adsoiption or chemisorption.

Question C.
Write an equation for Freundlich adsorption isotherm.
Answer:
Freundlich proposed the following empirical equation for adsorption of a gas on solid.
\(\frac{x}{\mathrm{~m}}\) = k P1/n (n > 1) ……(i)
where,
x = Mass of the gas adsorbed
m = Mass of the adsorbent
\(\frac{x}{\mathrm{~m}}\) = Mass of gas adsorbed per unit mass of adsorbent
P = Equilibrium pressure
k and n are constants which depend on the nature of adsorbate, adsorbent and temperature.

Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids

3. Answer the following questions:

Question A.
Define the terms:
a. Inhibition
b. Electrophoresis
c. Catalysis.
Answer:
a. Inhibition:
The phenomenon in which the rate of chemical reaction is reduced by an inhibitor is called inhibition.

b. Electrophoresis:
The movement of colloidal particles under an applied electric potential is called electrophoresis.

c. Catalysis:
The phenomenon of increasing the rate of a chemical reaction with the help of a catalyst is known as catalysis.

Question B.
Define adsorption. Why students can read blackboard written by chalks?
Answer:

  • Adsorption is the phenomenon of accumulation of higher concentration of ‘one substance on the surface of another (in bulk) due to unbalanced/unsatisfied attractive forces on the surface.
  • When we write on blackboard using chalk, the chalk particles get adsorbed on the surface of the blackboard.

Hence, students can read blackboard written by chalks.

Question C.
Write characteristics of adsorption.
Answer:
Following are the characteristics of adsorption:

  • Adsorption is a surface phenomenon.
  • It depends upon the surface area of the adsorbent.
  • It involves physical forces (van der Waals forces) or chemical forces (chemical or covalent bonds).
  • Adsorbate is always present in higher concentration on the surface of an adsorbent than in the bulk.
  • Adsorption is dependent on temperature (of the surface) and pressure (of adsorbate gas).
  • It takes place with the evolution of heat (with some exceptions).

Question D.
Distinguish between Lyophobic and Lyophilic sols.
Answer:
Lyophobic sols (colloids):

  1. Lyophobic sols are formed only by special methods.
  2. They are irreversible.
  3. These are unstable and hence, require traces of stabilizers.
  4. Addition of small amount of electrolytes causes precipitation or coagulation of lyophobic sols.
  5. Viscosity of lyophobic sol is nearly the same as the dispersion medium.
  6. Surface tension of lyophobic sol is nearly the same as the dispersion medium.

Lyophilic sols (colloids):

  1. Lyophilic sols are formed easily by direct mixing.
  2. They are reversible.
  3. These are self-stabilized.
  4. Addition of large amount of electrolytes causes precipitation or coagulation of lyophilic sols.
  5. Viscosity of lyophilic sol is much higher than that of the dispersion medium.
  6. Surface tension of lyophilic sol is lower than that of dispersion medium.

Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids

Question E.
Identify dispersed phase and dispersion medium in the following colloidal dispersions.
a. milk
b. blood
c. printing ink
d. fog
Answer:

Colloidal dispersionDispersed phaseDispersion medium
MilkLiquidLiquid
BloodSolidLiquid
Printing inkSolidLiquid
FogLiquidGas

Question F.
Write notes on :
a. Tyndall effect
b. Brownian motion
c. Types of emulsion
d. Hardy-Schulze rule
Answer:
a. Tyndall effect:
i. Tyndall observed that when light passes through true solution, the path of light through it cannot be detected.
ii. However, if the light passes through a colloidal dispersion, the particles scatter some light in all directions and the path of the light through colloidal dispersion becomes visible to observer standing at right angles to its path.
iii. The phenomenon of scattering of light by colloidal particles and making path of light visible through the dispersion is referred as Tyndall effect and the bright cone of the light is called Tyndall cone.
iv. Tyndall effect is observed only when the following conditions are satisfied.

  • The diameter of the dispersed particles is not much smaller than the wavelength of light used.
  • The refractive indices of dispersed phase and dispersion medium differ largely.

v. Significance of Tyndall effect:

  • It is useful in determining number of particles in colloidal system and their particle size.
  • It is used to distinguish between colloidal dispersion and true solution.

Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids 1

b. Brownian motion:
i. The colloidal or microscopic particles undergo ceaseless random zig-zag motion in all directions in a fluid. This motion of dispersed phase particles is called Brownian motion.
ii. Cause of Brownian motion:

  • Particles of the dispersed phase constantly collide with the fast-moving molecules of dispersion medium (fluid).
  • Due to this, the dispersed phase particles acquire kinetic energy from the molecules of the dispersion medium.
  • This kinetic energy brings about Brownian motion.

c. Types of emulsion:
iii. There are two types of emulsions:
a. Emulsion of oil in water (o/w type): An emulsion in which dispersed phase is oil and dispersion medium is water is called emulsion of oil in water.
e.g. 1. Milk consists of particles of fat dispersed in water.
2. Other examples include vanishing cream, paint, etc.
b. Emulsion of water in oil (w/o type): An emulsion in which dispersed phase is water and dispersion medium is oil is called emulsion of water in oil.
e.g. 1. Cod liver oil consists of particles of water dispersed in oil.
2. Some other examples of this type include butter, cream, etc.

d. Hardy-Schulze rule:
i. Generally, greater the valency of the flocculating ion added, greater is its power to cause precipitation. This is known as Hardy-Schulze rule.
ii. In the coagulation of negative sol, the flocculating power follows the following order:
Al3+ > Ba2+ > Na+
iii. Similarly, in the coagulation of positive sol, the flocculating power is in the following order:
[Fe (CN)6]4- > PO43- > SO42- > Cl

Question G.
Explain Electrophoresis in brief with the help of diagram. What are its applications ?
Answer:
i. Electrophoresis: Electrophoresis set up is shown in the diagram below.
Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids 2

  • The diagram shows U tube set up in which two platinum electrodes are dipped in a colloidal solution.
  • When electric potential is applied across two electrodes, colloidal particles move towards one or other electrode.
  • The movement of colloidal particles under an applied electric potential is called electrophoresis.
  • Positively charged particles move towards cathode while negatively charged particles migrate towards anode and get deposited on the respective electrode.

ii. Applications of electrophoresis:

  • On the basis of direction of movement of the colloidal particles under the influence of electric field, it is possible to know the sign of charge on the particles.
  • It is also used to measure the rate of migration of sol particles.
  • Mixture of colloidal particles can be separated by electrophoresis, since different colloidal particles in mixture migrate with different rates.

Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids

Question H.
Explain why finely divided substance is more effective as adsorbent?
Answer:

  • Adsorption is a surface phenomenon and hence, the extent of adsorption depends upon surface area of the adsorbent.
  • Adsorption increases with increase in surface area of the adsorbent.
  • Finely divided powdered substances provide larger surface area for a given mass.

Hence, finely divided substance is more effective as adsorbent.

Question I.
What is the adsorption Isotherm?
Answer:
The relationship between the amount of a substance adsorbed per unit mass of adsorbent and the equilibrium pressure (in case of gas) or concentration (in case of solution) at a given constant temperature is called an adsorption isotherm.

Question J.
Aqueous solution of raw sugar, when passed over beds of animal charcoal, becomes colourless. Explain.
Answer:

  • When aqueous solution of raw sugar is passed over beds of animal charcoal, charcoal adsorbs the coloured particles from the raw sugar.
  • Thus, due to the adsorption of coloured particles, raw sugar becomes colourless when passed over beds of animal charcoal.

Question K.
What happens when a beam of light is passed through a colloidal sol?
Answer:
i. When a beam of light is passed through colloidal sol, it is observed that the colloidal particles scatter some of the incident light in all directions.
ii. Because of this scattering of light, the path of light through the colloidal dispersion becomes visible to observer standing at right angles to its path and the phenomenon is known as Tyndall effect.
iii.
Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids 3

Question L.
Mention factors affecting adsorption of gas on solids.
Answer:
Adsorption of gases on solids depends upon the following factors:

  • Nature of adsorbate (gas)
  • Nature of solid adsorbent
  • Surface area of adsorbent
  • Temperature of the surface
  • Pressure of the gas

Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids

Question M.
Give four uses of adsorption.
Answer:
i. Catalysis (Heterogeneous catalysis):

  • The solid catalysts are used in many industrial manufacturing processes.
  • For example, iron is used as a catalyst in manufacturing of ammonia, platinum in manufacturing of sulphuric acid, H2SO4 (by contact process) while finely divided nickel is employed as a catalyst in hydrogenation of oils.

ii. Gas masks:

  • It is a device which consists of activated charcoal or mixture of adsorbents.
  • It is used for breathing in coal mines to avoid inhaling of the poisonous gases.

iii. Control of humidity: Silica and alumina gels are good adsorbents of moisture.
iv. Production of high vacuum:

  • Lowering of temperature at a given pressure, increases the rate of adsorption of gases on charcoal powder. By using this principle, high vacuum can be attained by adsorption.
  • A vessel evacuated by vacuum pump is connected to another vessel containing coconut charcoal cooled by liquid air. The charcoal adsorbs the remaining traces of air or moisture to create a high vacuum.

Question N.
Explain Bredig’s arc method.
Answer:

  • Colloidal sols can be prepared by electrical disintegration using Bredig’s arc method.
  • This process involves vaporization as well as condensation.
  • Colloidal sols of metals such as gold, silver, platinum can be prepared by this method.
  • In this method, electric arc is struck between electrodes of metal immersed in the dispersion medium.
  • The intense heat produced vapourizes the metal which then condenses to form particles of colloidal sol.

Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids 4

Question O.
Explain the term emulsions and types of emulsions.
Answer:
i. A colloidal system in which one liquid is dispersed in another immiscible liquid is called an emulsion.
ii. There are liquid-liquid colloidal systems in which both liquids are either completely or partially immiscible.
iii. There are two types of emulsions:
a. Emulsion of oil in water (o/w type): An emulsion in which dispersed phase is oil and dispersion medium is water is called emulsion of oil in water.
e.g. 1. Milk consists of particles of fat dispersed in water.
2. Other examples include vanishing cream, paint, etc.
b. Emulsion of water in oil (w/o type): An emulsion in which dispersed phase is water and dispersion medium is oil is called emulsion of water in oil.
e.g. 1. Cod liver oil consists of particles of water dispersed in oil.
2. Some other examples of this type include butter, cream, etc.

Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids

4. Explain the following :

Question A.
A finely divided substance is more effective as adsorbent.
Answer:

  • Adsorption is a surface phenomenon and hence, the extent of adsorption depends upon the surface area of the adsorbent.
  • Adsorption increases with an increase in surface area of the adsorbent.
  • Finely divided powdered substances provide a larger surface area for a given mass. Hence, a finely divided substance is more effective as an adsorbent.

Question B.
Freundlich adsorption isotherm, with the help of a graph.
Answer:
Graphical representation of the Freundlich adsorption isotherm:
Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids 5
i. Freundlich proposed the following empirical equation for adsorption of a gas on solid.
\(\frac{x}{\mathrm{~m}}\) = k P1/n (n > 1) ………(i)
where,
x = Mass of the gas adsorbed
m = Mass of the adsorbent
\(\frac{x}{\mathrm{~m}}\) = Mass of gas adsorbed per unit mass of adsorbent
P = Equilibrium pressure
k and n are constants which depend on the nature of adsorbate, adsorbent and temperature.
ii. The graphical representation of Freundlich equation is as shown in the adjacent plot of x/m vs ‘P’.
iii. In case of solution, P in the equation (i) is replaced by the concentration (C) and thus,
\(\frac{x}{\mathrm{~m}}\) = k C1/n ………(ii)
iv. By taking logarithm on both sides of the equation (ii),
we get
log \(\frac{x}{\mathrm{~m}}\) = log k + \(\frac{1}{n}\) log C ……..(iii)
v. On plotting a graph of log \(\frac{x}{\mathrm{~m}}\) against log C or log P, a straight line is obtained as shown in the adjacent plot. The slope of the straight line is and intercept on Y-axis is log k.
vi. The factor \(\frac{1}{n}\) ranges from 0 to 1. Equation (iii) holds good over limited range of pressures.
a. When \(\frac{1}{n}\) → 0, \(\frac{x}{\mathrm{~m}}\) → constant, the adsorption is independent of pressure.
b. When \(\frac{1}{n}\) = 1, \(\frac{x}{\mathrm{~m}}\) = k P, i.e., \(\frac{x}{\mathrm{~m}}\) ∝ P, the adsorption varies directly with pressure.
c. The experimental isotherms tend to saturate at high pressure.
Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids 13

5. Distinguish between the following :

Question A.
Adsorption and absorption. Give one example.
Answer:
Adsorption:

  • Adsorption is a surface phenomenon as adsorbed matter is concentrated only at the surface and does not penetrate through the surface to the bulk of adsorbent.
  • Concentration of the adsorbate is high only at the surface of the adsorbent.
  • It is dependent on temperature and pressure.
  • It is accompanied by evolution of heat known as heat of adsorption.
  • It depends on surface area.
    e.g. Adsoiption of a gas or liquid like acetic acid by activated charcoal.

Absorption:

  • Absorption is a bulk phenomenon as absorbed matter is uniformly distributed inside as well as at the surface of the bulk of substance.
  • Concentration of the absorbate is uniform throughout the bulk of the absorbent.
  • It is independent of temperature and pressure.
  • It may or may not be accompanied by any evolution or absorption of heat.
  • It is independent of surface area.
    e.g. Absorption of water by cotton, absorption of ink by blotting paper.

Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids

Question B.
Physisorption and chemisorption. Give one example.
Answer:
Physisorption:

  1. In physisorption, the forces operating are weak van der Waals forces.
  2. It is not specific in nature as all gases adsorb on all solids. For example, all gases adsorb on charcoal.
  3. The heat of adsorption is low and lies in the range 20-40 kJ mol-1.
  4. It occurs at low temperature and decreases with an increase of temperature.
  5. It is reversible.
  6. Physisorbed layer may be multimolecular layer of adsorbed particles under high pressure.
    e.g. At low temperature N2 gas is physically adsorbed on iron.

Chemisorption:

  1. In chemisorption, the forces operating are of chemical nature (covalent or ionic bonds).
  2. It is highly specific and occurs only when chemical bond formation is possible between adsorbent and adsorbate. For example, adsorption of oxygen on tungsten, hydrogen on nickel, etc.
  3. The heat of adsorption is high and lies in the range 40-200 kJ mol-1.
  4. It is favoured at high temperature, however, the extent of chemical adsorption is lowered at very high temperature due to bond breaking.
  5. It is irreversible.
  6. Chemisorption forms monomolecular layer of adsorbed particles.
    e.g. N2 gas chemically adsorbed on iron at high temperature forms a layer of iron nitride, which desorbs at very high temperature.

6. Adsorption is surface phenomenon. Explain.
Answer:
Consider a surface of a liquid or a solid.

  • The molecular forces at the surface of a liquid are unbalanced or in unsaturation state.
  • In solids, the ions or molecules at the surface of a crystal do not have their forces satisfied by the close contact with other particles.
  • Because of the unsaturation, solid and liquid surfaces tend to attract gases or dissolved substances with which they come in close contact. Thus, the substance accumulates on the surface of solid or liquid i.e., the substance gets adsorbed on the surface.

Hence, adsorption is a surface phenomenon.
Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids 6

7. Explain how the adsorption of gas on solid varies with
a. nature of adsorbate and adsorbent
b. surface area of adsorbent
Answer:
i. a. Nature of adsorbate:
1. All solids adsorb gases to some extent. It is observed that gases having high critical temperature liquify easily and can be readily adsorbed.
2. The gases such as SO2, Cl2, NH3 which are easily liquefiable are adsorbed to a larger extent as compared to gases such as N2, O2, H2, etc. which are difficult to liquify.
3. Thus, the amount of gas adsorbed by a solid depends on the nature of the adsorbate gas i.e., whether it is easily liquefiable or not.

b. Nature of adsorbent: Substances which provide large surface area for a given mass are effective as adsorbents and adsorb appreciable volumes of gases.
e.g. Silica gel and charcoal are effective adsorbents due to their porous nature.

ii. Surface area of the adsorbent:

  • Adsorption is a surface phenomenon. Hence, the extent of adsorption increases with increase in surface area of the adsorbent.
  • Finely divided substances, rough surfaces, colloidal substances are good adsorbents as they provide larger surface area for a given mass.

Note: Critical temperature of some gases and volume adsorbed.
Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids 7

8. Explain two applications of adsorption.
Answer:
i. Catalysis (Heterogeneous catalysis):

  • The solid catalysts are used in many industrial manufacturing processes.
  • For example, iron is used as a catalyst in manufacturing of ammonia, platinum in manufacturing of sulphuric acid, H2SO4 (by contact process) while finely divided nickel is employed as a catalyst in hydrogenation of oils.

ii. Gas masks:

  • It is a device which consists of activated charcoal or mixture of adsorbents.
  • It is used for breathing in coal mines to avoid inhaling of the poisonous gases.

Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids

9. Explain micelle formation in soap solution.
Answer:

  • Soap molecule has a long hydrophobic hydrocarbon chain called tail which is attached to hydrophilic ionic carboxylate group, called head.
  • In water, the soap molecules arrange themselves to form spherical particles that are called micelles.
  • In each micelle, the hydrophobic tails of soap molecules point to the centre and the hydrophilic heads lie on the surface of the sphere.
  • As a result of this, soap dispersion in water is stable.

Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids 8

10. Draw labelled diagrams of the following :
a. Tyndall effect
b. Dialysis
c. Bredig’s arc method
d. Soap micelle
Answer:
a. Tyndall effect:
Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids 9

b. Dialysis:
Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids 10

c. Bredig’s arc method:
Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids 11

d. Soap micelle:
Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids 12

Activity :
Collect the information about methods to study surface chemistry.
Answer:
Following are the few methods that are employed to study surface chemistry.
i. X-ray photoelectron spectroscopy:
It is a surface-sensitive spectroscopic technique which is used to measure elemental composition of the surface, to determine elements that are present as contaminants on the surface, etc.

ii. Auger electron spectroscopy:
It is a common analytical technique which is used to study surfaces of materials.

iii. Temperature programmed desorption (TPD):
Adsorbed molecules get desorbed when the surface temperature is increased. TPD technique is used to observe these desorbed molecules and helps in providing information about binding energy between the adsorbate and adsorbent.

iv. Scanning Electron Microscopy:
In this technique, a scanning electron microscope is used to focus electron beam over the surface of the sample to be examined. The electron beam interacts with the sample and an image is obtained. This image provides information about surface structure and composition of the sample.

[Note: Students are expected to collect additional information about surface chemistry on their own.]

Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids

11th Chemistry Digest Chapter 11 Adsorption and Colloids Intext Questions and Answers

Can you tell? (Textbook Page No. 160)

Question 1.
What is adsorption?
Answer:
Adsorption is the phenomenon of accumulation of higher concentration of one substance on the surface of another (in bulk) due to unbalanced/unsatisfied attractive forces on the surface.

Try this. (Textbook Page No. 161)

Question 1.
Dip a chalk in ink. What do you observe?
Answer:
When a chalk is dipped in ink, it is observed that the ink molecules are adsorbed at the surface of chalk and the surface becomes coloured, while the solvent of the ink goes deeper into the chalk due to absorption.

Internet my friend. (Textbook Page No. 172)

Question i.
Brownian motion
Answer:
Students can search relevant videos on YouTube to visualize Brownian motion.

Question ii.
Collect information about Brownian motion.
Answer:
i. The colloidal or microscopic particles undergo ceaseless random zig-zag motion in all directions in a fluid. This motion of dispersed phase particles is called Brownian motion.
ii. Cause of Brownian motion:

  • Particles of the dispersed phase constantly collide with the fast-moving molecules of dispersion medium (fluid).
  • Due to this, the dispersed phase particles acquire kinetic energy from the molecules of the dispersion medium.
  • This kinetic energy brings about Brownian motion.

Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids

Internet my friend. (Textbook Page No. 172)

Question 1.
Collect information about surface chemistry.
Answer:

  • Surface or interface represents the boundary which separates two bulk phases.
    e.g. Boundary between water and its vapour is a liquid-gas interface.
  • Certain properties of substances, particularly of solids and liquids, depend upon the nature of the surface.
  • An interface usually has a thickness of a few molecules. However, its area depends on the size of the bulk phase particles.
  • Commonly considered bulk phases may be pure compounds or solutions.
  • A number of important phenomena, namely, dissolution, crystallization, heterogeneous catalysis, electrode processes and corrosion take place at an interface.
  • Thus, study of chemistry of surfaces is critical to many applications in industry, analytical investigations and day-to-day activities such as cleaning and softening of water.
  • The branch of chemistry which deals with the nature of surfaces and changes occurring on the surfaces is called surface chemistry.
  • Study of surfaces requires a rigorously clean surface. An ultra-clean metal surface can be obtained under very high vacuum, of the order of 10-8 to 10-9 pascal.
  • Adsorption, catalysis and colloids (such as emulsions and gels) are some of the important aspects of surface chemistry.

[Note: Students are expected to collect additional information about surface chemistry on their own.]

Activity. (Textbook Page No. 172)

Question 1.
Calculate surface area to volume ratio of spherical particle. See how the ratio increases with the reduction of radius of the particle. Plot the ratio against the radius.
Answer:
The graph below shows that as the radius of the spherical particle decreases, the surface-to-volume ratio increases steadily.
Maharashtra Board Class 11 Chemistry Solutions Chapter 11 Adsorption and Colloids 14